1-amino-4,5-diphenyl-1,2,3-triazole | 40788-61-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-amino-4,5-diphenyl-1,2,3-triazole
• 英文别名: 1-amino-4,5-diphenyl-v-triazole；4,5-diphenyl-[1,2,3]triazol-1-ylamine；4,5-Diphenyl-[1,2,3]triazol-1-ylamin；1-Amino-4,5-diphenyl-1,2,3-triazol；1-Amino-4,5-diphenyl-1,2,4-triazol；4,5-Diphenyl-1-amino-1,2,3-triazol；4,5-Diphenyl-1H-1,2,3-triazol-1-amine；4,5-diphenyltriazol-1-amine
• CAS: 40788-61-2
• 化学式: C₁₄H₁₂N₄
• 分子量: 236.276
• InChiKey: UKKDZCUPSSYZKY-UHFFFAOYSA-N

物化性质

• 熔点：
  126-128 °C
• 沸点：
  425.2±48.0 °C(Predicted)
• 密度：
  1.24±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  56.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-amino-4,5-diphenyl-1,2,3-triazole 生成 4,5-Diphenyl-1H-[1,2,3]triazole
  参考文献：
  名称：

  Mueller; Disselhoff, Justus Liebigs Annalen der Chemie, 1934, vol. 512, p. 250,252, 259

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 盐酸 作用下， 生成 1-amino-4,5-diphenyl-1,2,3-triazole
  参考文献：
  名称：

  Stolle, Journal fur praktische Chemie (Leipzig 1954), 1908, vol. <2>78, p. 546

  摘要：

  DOI：

文献信息

• The lead tetraacetate oxidation of bisacetylhydrazones of α-dicarbonyl compounds
  作者：Constantina P. Hadjiantoniou-Maroulis、Anastasia Vantsiouri、Apostolos J. Maroulis

  DOI：10.1002/jhet.5570330359

  日期：1996.5

  The oxidative cyclization of the title compounds results in generally two different kinds of products. The first, 1-(N,N-bisacetylamino)-1,2,3-triazole 7 (R3 = CH3) is the primary product, while the second, 1-N-acetylamino-1,2,3-triazole 8 (R3 = CH3), when observed, is obtained via hydrolysis from the former during work-up and separation of the reaction mixture. The primary products are considered

  标题化合物的氧化环化通常产生两种不同类型的产物。第一个1-（N，N-双乙酰氨基）-1,2,3-三唑7（R 3 = CH 3）是主要产物，而第二个1 - N-乙酰氨基-1,2,3-三唑当观察到时，通过后处理和反应混合物的分离中的前者通过水解获得8（R 3＝ CH 3）。初级产物被认为是由于两性离子中间体5（R 3 = CH 3），由Ñ所述两可的Ñ的-acetylimine部位5。
• PROCESS FOR PRODUCING ARYL CARBAMATES
  申请人：UBE INDUSTRIES LIMITED

  公开号：EP0902014A1

  公开（公告）日：1999-03-17

  A process for producing an aryl carbamate of a high purity at a high yield by reacting a diaryl carbonate with an amine compound having one or more hydrogen atoms bonded to the N position in the presence of carboxylic acid(s) of the following general formulae (I): R1-COOH and/or (II): R2-COOH (wherein R1 represents an alkyl or cycloalkyl group having a carbon atom at the α-position, which is bonded to only one hydrogen atom, and R2 represents an alkyl group having a carbon atom at the α-position, which is not bonded to a hydrogen atom).

  一种高纯度、高收率的氨基甲酸芳基酯的生产工艺，该工艺是在下列通式(I)的羧酸存在下，使碳酸二芳基酯与一个或多个氢原子键合在 N 位上的胺化合物反应：R1-COOH 和/或 (II)：R2-COOH（其中 R1 代表烷基或环烷基，在 α 位有一个碳原子，只与一个氢原子键合；R2 代表烷基，在 α 位有一个碳原子，不与氢原子键合）。
• Addition curable self-adhesive silicone rubber composition
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2746345A1

  公开（公告）日：2014-06-25

  An addition curable self-adhesive silicone rubber composition is provided. This silicone rubber composition comprises (A) 100 parts by weight of an organopolysiloxane containing at least 2 alkenyl groups bonded to silicon atoms per molecule, (B) 0.05 to 10 parts by weight of an organosilicon compound containing 1 to 100 silicon atoms which has at least 1 phenylene skeleton per molecule, and which has at least 1 hydrogen atom bonded to a silicon atom, (C) 0 to 30 parts by weight of an organohydrogenpolysiloxane containing at least 2 hydrogen atoms bonded to silicon atoms per molecule, and containing no phenylene skeleton in the molecule, (D) 0.001 to 0.1 part by weight of a triazole compound, and (E) a catalytic amount of a platinum catalyst. This silicone rubber composition is capable of forming a cured article having good adhesion to various organic resins.

  提供了一种可加成固化的自粘硅橡胶组合物。这种硅橡胶组合物包括：(A) 100 重量份的有机聚硅氧烷，其中每个分子至少含有 2 个与硅原子键合的烯基；(B) 0.05 至 10 份(重量)的有机硅化合物，该有机硅化合物含有 1 至 100 个硅原子，每个分子至少有 1 个亚苯基骨架，并且至少有 1 个氢原子键合到硅原子上；(C) 0 至 30 份(重量)的有机氢聚硅氧烷，该有机氢聚硅氧烷每个分子至少含有 2 个氢原子键合到硅原子上，并且分子中不含有亚苯基骨架；(D) 0.001 至 0.1 重量份的三唑化合物，以及 (E) 催化量的铂催化剂。这种硅橡胶组合物能够形成与各种有机树脂具有良好粘合力的固化物。
• ADDITION-CURABLE SILICONE RUBBER COMPOSITION
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP3219762A1

  公开（公告）日：2017-09-20

  Provided is an addition-curable silicone rubber composition in which a flame retardant has been added to a silicone rubber composition to improve the flame retardancy and, despite this, the physical properties of the silicone rubber serving as the base are unchanged. The addition-curable silicone rubber composition comprises (A) 100 parts by mass of an alkenyl-containing organopolysiloxane having at least two silicon-atom-bonded alkenyl groups in the molecule, (B) 0.2-20 parts by mass, per 100 parts by mass of component (A), of an organohydrogenpolysiloxane having at least two silicon-atom-bonded hydrogen atoms in the molecule, (C) 5-80 parts by mass, per 100 parts by mass of the sum of components (A) and (B), of a fine reinforcing silica powder having a specific surface area, as determined by the BET method, of 50 m2/g or greater, (D) 0.001-1 part by mass of a triazole-based compound, (E) 0.001-5 parts by mass of a phosphoric ester compound, and (F) a catalytic amount of a platinum catalyst.

  本发明提供了一种添加固化型硅橡胶组合物，其中在硅橡胶组合物中添加了阻燃剂，以提高阻燃性，尽管如此，作为基体的硅橡胶的物理性质保持不变。该添加固化型硅橡胶组合物包括：(A) 100 份（按重量计）分子中至少有两个硅原子键合烯基的含烯基有机聚硅氧烷；(B) 0.以每 100 份组分(A)的质量计，含有 2-20 份有机氢聚硅氧烷，其分子中至少有两个硅原子键合的氢原子；(C) 以每 100 份组分(A)和(B)的质量计，含有 5-80 份细小的强化二氧化硅粉末，其比表面积经 BET 方法测定为 50 m2/g 或以上；(D) 0.001-1份质量的三唑基化合物，(E) 0.001-5份质量的磷酸酯化合物，以及(F) 催化量的铂催化剂。
• Controlling cure rate with wetted filler
  申请人：PRC-DeSoto International, Inc.

  公开号：US11214666B2

  公开（公告）日：2022-01-04

  Compositions include a polythiol and a wetted filler. The composition comprises from 0.1 wt % to 10 wt % water based on the total weight of the composition. The compositions exhibit an extended working time and a rapid onset of cure. The compositions can be used as sealants.

  组合物包括聚硫醇和润湿填料。根据组合物的总重量，组合物中含有 0.1% 至 10% 的水。该组合物具有工作时间长、固化速度快的特点。该组合物可用作密封剂。