nonatriacontanol | 1138242-67-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: nonatriacontanol
• 英文别名: 1-Nonatriacontanol；nonatriacontan-1-ol
• CAS: 1138242-67-7
• 化学式: C₃₉H₈₀O
• 分子量: 565.064
• InChiKey: ZOQKDKHGOGZNLC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  19.8
• 重原子数：
  40
• 可旋转键数：
  37
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  nonatriacontanol 、 3-叔丁基-2,5-二羟基苯甲醛 在 [4-(2,4,4,6,6,8,8,10,10,12,12,14,14,16,16,18,18,20,20,22,22,24,24,26,26,28,28,30,30,32,32,34,34,36,36,38,38,40,40,42,42,44,44,46,46-Pentatetracontamethylheptatetracontoxy)phenyl]-diphenylphosphane 、 偶氮二甲酸二乙酯 、 对甲苯磺酸 、 三乙胺 作用下， 以 甲苯 、 水 为溶剂， 反应 15.0h， 以90%的产率得到
  参考文献：
  名称：

  Polyisobutylene-Supported Phosphines as Recyclable and Regenerable Catalysts and Reagents

  摘要：

  Phosphines are important as catalysts or reagents in synthesis but must be separated from products after a reaction. This report shows that polyisobutylene (PIB)-bound alkyldiaryl- and triarylphosphines are useful as catalysts in addition and allylic amination reactions or as reagents in aza-Wittig and Mitsunobu reactions. Heptane solutions of such phosphines and their oxidized byproducts can be easily separated from polar solutions of organic products, and PIB-phosphine oxides formed during a reaction can readily be reduced to PIB-phosphines for reuse.

  DOI：

  10.1021/jo201097x

文献信息

• [EN] ORTHO-TERPHENYLS FOR THE PREPARATION OF GRAPHENE NANORIBBONS<br/>[FR] ORTHO-TERPHENYLES POUR LA PREPARATION DE NANORUBANS DE GRAPHENE
  申请人：BASF SE

  公开号：WO2015173215A1

  公开（公告）日：2015-11-19

  The present invention concerns ortho-Terphenyls of general formula (I); wherein R1, R2, R3 and R4 are independently selected from the group consisting of H; CN; NO2; and saturated, unsaturated or aromatic C1-C40 hydrocarbon residues, which can be substituted 1 - to 5- fold with F, CI, OH, NH2, CN and/or NO2, and wherein one or more -CH2-groups can be replaced by -O-, -NH-, -S-, -C(=O)O-, -OC(=O)- and/or -C(=O)-; and X and Y are the same or different, and selected from the group consisting of F, CI, Br, I, and OTf (trifluoromethanesulfonate); and their use for the preparation of graphene nanoribbons as well as a process for the preparation of graphene nanoribbons from said ortho-Terphenyls.

  本发明涉及一般式(I)的邻二联苯；其中R1、R2、R3和R4分别选自H；CN；NO2；以及饱和、不饱和或芳香族C1-C40烃基，该烃基可用F、Cl、OH、NH2、CN和/或NO2取代1至5次，并且一个或多个-CH2基团可被-O-、-NH-、-S-、-C(=O)O-、-OC(=O)-和/或-C(=O)-取代；X和Y相同或不同，选自F、Cl、Br、I和OTf（三氟甲磺酸盐）；以及它们用于制备石墨烯纳米带，以及从所述邻二联苯制备石墨烯纳米带的方法。
• ORTHO-TERPHENYLS FOR THE PREPARATION OF GRAPHENE NANORIBBONS
  申请人：BASF SE

  公开号：EP3142994A1

  公开（公告）日：2017-03-22
• SYNTHESIS OF TRI-COMPONENT RESINS
  申请人：BIRAU Maria

  公开号：US20120077953A1

  公开（公告）日：2012-03-29

  A resinous compound of the formulas or a salt thereof, wherein G 1 is —X 1 C(O)OR 1 ,—X 2 OC(O)R 2 , or —X 2 OH; G 2 is R 4 , R 12 , —C(O)R 2 , —C(O)X 1 C(O)OR 1 , or —C(O)X 2 OC(O)R 2 ; R 1 is an alkyl having from 10 to 80 carbon atoms; R 2 is an alkyl having from 2 to 40 carbon atoms; each R 3 and R 4 is independently hydrogen, alkyl, arylalkyl or alkylaryl; each R 5 and each R 6 is independently hydrogen or alkyl; X 1 and X 2 are both a straight or branched alkylene group; t1 is 1 to 20; t2 and t3 is independently 0 to 20; u1 is 1 to 30; u2 and u3 is independently 0 to 30; each R 7 and each R 8 is independently hydrogen, alkyl, or alkoxyl; each R 9 and each R 10 is independently hydrogen, alkyl, or alkoxyl; Ar is a substituted or unsubstituted aromatic moiety; p is 1 to 5; q is 1 to 12; A circle around (⊖)} is selected from the group consisting of Cl − , Br − , I − , HSO 4 − , HSO 3 − , CH 3 SO 3 − , NO 3 − , HCOO − , CH 3 COO − , H 2 PO 4 − , SCN − , BF 4 − , ClO 4 − , SSO 3 − , PF 6 − , and SbCl 6 − ; and J is alkyl, arylalkyl, or alkylaryl.
• US4288296A
  申请人：——

  公开号：US4288296A

  公开（公告）日：1981-09-08
• US8329854B2
  申请人：——

  公开号：US8329854B2

  公开（公告）日：2012-12-11