bisphenanthro[9',10':4,5]imidazo[2,1-a:2',1'-a']phenanthro[2,1,10-def:7,8,9-d'e'f']diisoquinoline-10,15-dione | 91708-84-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: bisphenanthro[9',10':4,5]imidazo[2,1-a:2',1'-a']phenanthro[2,1,10-def:7,8,9-d'e'f']diisoquinoline-10,15-dione
• 英文别名: 7,22,33,48-Tetrazapentadecacyclo[29.21.2.22,5.03,27.04,24.06,22.08,21.09,14.015,20.028,53.033,49.034,47.035,40.041,46.050,54]hexapentaconta-1(53),2,4,6,8(21),9,11,13,15,17,19,24,26,28,30,34(47),35,37,39,41,43,45,48,50(54),51,55-hexacosaene-23,32-dione
• CAS: 91708-84-8
• 化学式: C₅₂H₂₄N₄O₂
• 分子量: 736.788
• InChiKey: NTYDXKVGFXNVJJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.3
• 重原子数：
  58
• 可旋转键数：
  0
• 环数：
  15.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  69.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  9,10-二氨基菲 、 3,4,9,10-苝四羧酸二酐 在 zinc diacetate 作用下， 反应 3.0h， 生成 bisphenanthro[9',10':4,5]imidazo[2,1-a:2',1'-a']anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-14,29-dione 、 bisphenanthro[9',10':4,5]imidazo[2,1-a:2',1'-a']phenanthro[2,1,10-def:7,8,9-d'e'f']diisoquinoline-10,15-dione
  参考文献：
  名称：

  绿色合成多环苯并咪唑衍生物和有机半导体

  摘要：

  多环苯并咪唑衍生物是有机电子产品和光伏产品中的一类重要化合物，是使用无溶剂的“绿色”工艺制备的，该工艺基于在固态乙酸锌存在下加热羧酸酐和亚芳基二胺的方法。产物的分离和纯化是通过将粗反应混合物直接升华进行的。使用各种羧酸酐优化反应条件。还描述了这些材料的光学和电化学性质。

  DOI：

  10.1021/ol201973w

文献信息

• LYOTROPIC CHROMONIC LIQUID CRYSTAL COMPOSITION, METHOD FOR MANUFACTURE OF LYOTROPIC CHROMONIC LIQUID CRYSTAL COATING FILM, AND LYOTROPIC CHROMONIC LIQUID CRYSTAL COATING FILM MANUFACTURED THEREBY
  申请人：Shin Seung Han

  公开号：US20110272629A1

  公开（公告）日：2011-11-10

  The present invention relates to a lyotropic chromonic liquid crystal composition, a method for manufacturing a lyotropic chromonic liquid crystal coating film and a lyotropic chromonic liquid crystal coating film manufactured thereby. The lyotropic chromonic liquid crystal composition of the present invention includes chromonic liquid crystal compounds and monomers each having opposing acid-base properties. Use of the lyotropic chromonic liquid crystal composition in the formation of optical films leads to improvements in electrical and optical properties such as mechanical strength, an insulating characteristic and a refractive index.
• ELECTRO-POLARIZABLE COMPOUND AND CAPACITOR
  申请人：Capacitor Sciences Incorporated

  公开号：US20170301477A1

  公开（公告）日：2017-10-19

  A composite oligomeric material includes one or more repeating backbone units; one or more polarizable units incorporated into or connected to one or more of the one or more repeating backbone units; and one or more resistive tails connected to one or more of the repeating backbone units or to the one or more polarizable units as a side chain on the polarizable unit, on a handle linking a polarizable unit to a backbone unit, or directly attached to a backbone unit. The composite oligomer material may be polymerized to form a metadielectric, which may be sandwiched between to electrodes to form a metacapacitor.
• US8580143B2
  申请人：——

  公开号：US8580143B2

  公开（公告）日：2013-11-12
• Green Synthesis of Polycyclic Benzimidazole Derivatives and Organic Semiconductors
  作者：Masashi Mamada、César Pérez-Bolívar、Pavel Anzenbacher

  DOI：10.1021/ol201973w

  日期：2011.9.16

  Polycyclic benzimidazole derivatives, an important class of compounds in organic electronics and photovoltaics, were prepared using a solvent-free “green” process based on heating carboxylic acid anhydrides and arylene diamines in the presence of zinc acetate in the solid state. Products were isolated and purified directly by train sublimation of the crude reaction mixtures. The reaction conditions

  多环苯并咪唑衍生物是有机电子产品和光伏产品中的一类重要化合物，是使用无溶剂的“绿色”工艺制备的，该工艺基于在固态乙酸锌存在下加热羧酸酐和亚芳基二胺的方法。产物的分离和纯化是通过将粗反应混合物直接升华进行的。使用各种羧酸酐优化反应条件。还描述了这些材料的光学和电化学性质。