2-hydroxy-3-[(2S)-2-hydroxypropoxy]benzaldehyde | 916811-84-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-hydroxy-3-[(2S)-2-hydroxypropoxy]benzaldehyde
• CAS: 916811-84-2
• 化学式: C₁₀H₁₂O₄
• 分子量: 196.203
• InChiKey: XYDWFFFHKOFAGK-ZETCQYMHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  66.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-hydroxy-3-[(2S)-2-hydroxypropoxy]benzaldehyde 以 乙醇 为溶剂， 反应 1.0h， 生成
  参考文献：
  名称：

  Chiral single-stranded metallohelix: metal-mediated folding of linear oligooxime ligand

  摘要：

  A linear tetraoxime ligand H4L bearing chiral (S)-2-hydroxylpropyl groups at both ends was synthesized. Complexation between H4L with Zn2+ and Mn+ (=Ca2+, Y3+, La3+) afforded helical trinuclear complex [LZn2M](n+). The helical sense was the most effectively induced when Ca2+ was used as the central metal Mn+. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2006.09.125
• 作为产物：
  描述：

  2-allyloxy-3-[2-(tetrahydro-pyran-2-yloxy)-propoxy]-benzaldehyde 在 palladium on activated charcoal 高氯酸 作用下， 以 甲醇 为溶剂， 以91%的产率得到2-hydroxy-3-[(2S)-2-hydroxypropoxy]benzaldehyde
  参考文献：
  名称：

  Chiral single-stranded metallohelix: metal-mediated folding of linear oligooxime ligand

  摘要：

  A linear tetraoxime ligand H4L bearing chiral (S)-2-hydroxylpropyl groups at both ends was synthesized. Complexation between H4L with Zn2+ and Mn+ (=Ca2+, Y3+, La3+) afforded helical trinuclear complex [LZn2M](n+). The helical sense was the most effectively induced when Ca2+ was used as the central metal Mn+. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2006.09.125

文献信息

• Chiral single-stranded metallohelix: metal-mediated folding of linear oligooxime ligand
  作者：Shigehisa Akine、Takanori Taniguchi、Tatsuya Nabeshima

  DOI：10.1016/j.tetlet.2006.09.125

  日期：2006.11

  A linear tetraoxime ligand H4L bearing chiral (S)-2-hydroxylpropyl groups at both ends was synthesized. Complexation between H4L with Zn2+ and Mn+ (=Ca2+, Y3+, La3+) afforded helical trinuclear complex [LZn2M](n+). The helical sense was the most effectively induced when Ca2+ was used as the central metal Mn+. (c) 2006 Elsevier Ltd. All rights reserved.