2-{[(8-Bromooctyl)oxy]methyl}oxirane | 99932-67-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: 2-{[(8-Bromooctyl)oxy]methyl}oxirane
• 英文别名: 2-(8-bromooctoxymethyl)oxirane
• CAS: 99932-67-9
• 化学式: C₁₁H₂₁BrO₂
• 分子量: 265.19
• InChiKey: DDMQFOIBDLYYCC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  14
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  21.8
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Halogen-substituted Glycidyl ether compound and preparation process thereof
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0150842A2

  公开（公告）日：1985-08-07

  This invention relates to a halogen-substituted glycidyl ether compound represented by the following general formula 1 ): wherein R1 means a hydrogen atom or methyl group, R2 denotes an alkylene group represented by the general formula ( CH2 ) m, m standing for an integer of 4 - 20, or a xylylene group, and X Is a halogen atom, as well as to a process for preparing the glycidyl ether compound by reacting in an aprotic polar solvent and in the presence of a strong basic substance a hydroxyl-substituted compound, represented by the following general formula (2): wherein R1 has the same meaning as defined above, with a dihalogen-substituted compound represented by the following general formula (3): wherein R2 and X have the same meanings as defined above.

  本发明涉及一种卤素取代的缩水甘油醚化合物，由以下通式 1 )表示：其中 R1 指氢原子或甲基，R2 表示由通式 ( CH2 ) m 表示的亚烷基，m 代表 4 - 20 的整数或二甲苯基团，X 是卤素原子；本发明还涉及一种制备缩水甘油醚化合物的工艺，该工艺是将由以下通式(2)表示的羟基取代的化合物（其中 R1 的含义与上述定义相同）与由以下通式(3)表示的二卤素取代的化合物进行反应：其中 R2 和 X 的含义与上述定义相同。