methacrylic acid 2-[(triphenylsilyl)oxy]ethyl ester | 112145-58-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methacrylic acid 2-[(triphenylsilyl)oxy]ethyl ester
• 英文别名: 2-Triphenylsilyloxyethyl 2-methylprop-2-enoate
• CAS: 112145-58-1
• 化学式: C₂₄H₂₄O₃Si
• 分子量: 388.538
• InChiKey: HVTYOZDTKOGQDY-UHFFFAOYSA-N

物化性质

• 沸点：
  443.6±28.0 °C(Predicted)
• 密度：
  1.11±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.79
• 重原子数：
  28
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  甲基丙烯酸羟乙酯 、 三苯基氯硅烷 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以35%的产率得到methacrylic acid 2-[(triphenylsilyl)oxy]ethyl ester
  参考文献：
  名称：

  Synthesis and characterization of some organosilicon derivatives of poly 2-hydroxyethyl methacrylate with cubane as a cross-linking agent

  摘要：

  Some silyl ether derivatives of 2-hydroxyethyl methacrylate (HEMA) were prepared. The Et3Si, Ph3Si and Me3Si groups together with cubane-1,4-dicarboxylic acid (CDA) were covalently linked with HEMA. The silyl-linked HEMA are abbreviated as TETMA, TPhMA and TMEMA, respectively. CDA linked to two HEMA groups is the cross-linking agent (CA). Free radical copolymerization and cross-linking copolymerization of the resulting monomers with 2-hydroxyethyl methacrylate (HEMA) with the various ratios of CA as cross-linking agent, were carried Out using AIBN as initiator at the temperature ranges 60-70 degrees C. The cross-linking copolymers were identified by FT-IR spectroscopy. The glass transition temperature (T-g) of the network polymers was determined calorimetrically. The T, of network polymers increases with increase of cross-linking degree. All monomers and polymers were identified by spectroscopic methods. These silyl derivatives modified methacrylate polymer properties. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.07.068

文献信息

• Synthesis and characterization of some organosilicon derivatives of poly 2-hydroxyethyl methacrylate with cubane as a cross-linking agent
  作者：Mohammad G. Assadi、Mehrdad Mahkam、Zohreh Tajrezaiy

  DOI：10.1016/j.jorganchem.2005.07.068

  日期：2005.11

  Some silyl ether derivatives of 2-hydroxyethyl methacrylate (HEMA) were prepared. The Et3Si, Ph3Si and Me3Si groups together with cubane-1,4-dicarboxylic acid (CDA) were covalently linked with HEMA. The silyl-linked HEMA are abbreviated as TETMA, TPhMA and TMEMA, respectively. CDA linked to two HEMA groups is the cross-linking agent (CA). Free radical copolymerization and cross-linking copolymerization of the resulting monomers with 2-hydroxyethyl methacrylate (HEMA) with the various ratios of CA as cross-linking agent, were carried Out using AIBN as initiator at the temperature ranges 60-70 degrees C. The cross-linking copolymers were identified by FT-IR spectroscopy. The glass transition temperature (T-g) of the network polymers was determined calorimetrically. The T, of network polymers increases with increase of cross-linking degree. All monomers and polymers were identified by spectroscopic methods. These silyl derivatives modified methacrylate polymer properties. (c) 2005 Elsevier B.V. All rights reserved.