10-Imidazol-1-yldecoxy(triphenyl)silane | 1234388-35-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 10-Imidazol-1-yldecoxy(triphenyl)silane
• 英文别名: 10-imidazol-1-yldecoxy(triphenyl)silane
• CAS: 1234388-35-2
• 化学式: C₃₁H₃₈N₂OSi
• 分子量: 482.741
• InChiKey: DULADYNVXNESQH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.69
• 重原子数：
  35
• 可旋转键数：
  15
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  27
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  三苯基氯硅烷 、 1-(10-羟基癸)咪唑 在 吡啶 作用下， 以 乙腈 为溶剂， 以45%的产率得到10-Imidazol-1-yldecoxy(triphenyl)silane
  参考文献：
  名称：

  Synthesis and characterization of imidazole–triphenylsilane complexes

  摘要：

  Three imidazole-based triphenylsilane complexes were synthesized as preliminary model complexes to those that have been proposed as intermediates during the enzymatic biomineralization of silica by certain sponges. The active site of the enzyme includes histidine-serine moieties that appear to be vital to functionality. The model compounds include ligands that are bound to the silicon via a Si-O-C linkage and have a potentially chelating imidazole ring. Synthesis of these compounds was achieved by reaction of triphenylchlorosilane with two equivalents of ligand, one equivalent acting as a base for the HCl generated during the reaction. The compounds are highly reactive toward hydrolysis and were characterized by NMR, MS, elemental analysis, and X-ray crystallography. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.03.005