3,6-bis(dibenzothiophen-4-yl)-9-phenyl-9H-carbazole | 1364890-79-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3,6-bis(dibenzothiophen-4-yl)-9-phenyl-9H-carbazole
• 英文别名: 3,6-di-(dibenzothiophen-4-yl)-9-phenyl-9H-carbazole；3,6-di(dibenzothiophen-4-yl)-9-phenylcarbazole
• CAS: 1364890-79-8
• 化学式: C₄₂H₂₅NS₂
• 分子量: 607.799
• InChiKey: MNGHUUSEERRBBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13
• 重原子数：
  45
• 可旋转键数：
  3
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  61.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  二苯并噻吩-4-硼酸 、 3,6-二溴-9-苯基咔唑 在 palladium diacetate 、 potassium carbonate 、 三(邻甲基苯基)磷 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 6.0h， 以47%的产率得到3,6-bis(dibenzothiophen-4-yl)-9-phenyl-9H-carbazole
  参考文献：
  名称：

  TWI565701

  摘要：

  公开号：

文献信息

• Carbazole Compound, Material for Light-Emitting Element, Organic Semiconductor Material, Light-Emitting Element
  申请人：Osaka Harue

  公开号：US20120091887A1

  公开（公告）日：2012-04-19

  To provide a novel carbazole compound that has an excellent carrier-transport property and can be used for a transport layer or as a host material in a light-emitting element. Further, to provide an organic semiconductor material and a material for a light-emitting element using the carbazole compound. A carbazole compound in which the 4-position of a dibenzothiophene skeleton or a dibenzofuran skeleton is substituted with the 2- or 3-position of a carbazole skeleton directly or via an arylene group can be synthesized. The carbazole compound is found to have a suitable carrier-transport property, a good film quality, and be used suitably as a material of a light-emitting element and an organic semicondcutor material. Note that nitrogen of the carbazole skeleton is substituted with any of a phenyl group, a biphenyl group, and a naphthyl group.

  提供一种具有优异载流子传输性能的新型咔唑化合物，可用于光电元件中的传输层或作为主体材料。此外，提供使用该咔唑化合物的有机半导体材料和光电元件材料。可以合成一种咔唑化合物，其中二苯并噻吩骨架或二苯并呋喃骨架的4位被咔唑骨架的2位或3位直接或通过芳基基团取代。发现该咔唑化合物具有适当的载流子传输性能、良好的膜质量，并适用于光电元件材料和有机半导体材料。请注意，咔唑骨架的氮原子可被苯基、联苯基和萘基中的任何一个取代。
• Light-Emitting Element, Light-Emitting Device, Electronic Device, Lighting Device, and Organometallic Complex
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20180062084A1

  公开（公告）日：2018-03-01

  In a light-emitting element, a layer including an organic compound includes a light-emitting layer; the light-emitting layer includes a tris iridium complex; and on the assumption that there is a rectangle which covers the iridium complex and in which at least one atom of the iridium complex is located over each of four sides when the iridium complex is two-dimensionally seen from a direction of a C3 symmetry axis of the iridium complex, A×B/C 2 is greater than or equal to 2.5, where A represents a maximum length of a long side of the rectangle, B represents a length of a short side of the rectangle when the length of the long side of the rectangle is A, and C represents a width in the direction of the C3 symmetry axis when the iridium complex is two-dimensionally seen from a normal direction of the C3 symmetry axis.

  在发光元件中，包括有机化合物的层包括一个发光层；发光层包括一个三核铱配合物；假设存在一个矩形，覆盖铱配合物，在该矩形中，当从铱配合物的C3对称轴方向二维观察时，铱配合物的至少一个原子位于四条边的每一边上，当矩形的长边最大长度为A时，A×B/C2大于或等于2.5，其中A代表矩形的长边的最大长度，B代表矩形的短边长度，当矩形的长边长度为A时，C代表铱配合物从C3对称轴的正常方向二维观察时在C3对称轴方向的宽度。
• Light-Emitting Element and Electronic Device
  申请人：Seo Satoshi

  公开号：US20120074390A1

  公开（公告）日：2012-03-29

  An object is to provide a light-emitting element with high emission efficiency which includes a novel carbazole derivative that has a wide energy gap and can be used for a transport layer or a host material in a light-emitting element. A carbazole derivative in which the 4-position of dibenzothiophene or dibenzofuran is bonded to the 2- or 3-position of carbazole has been able to be provided by use of the carbazole derivative. Further, a light-emitting element having high emission efficiency has been able to be provided by use of the carbazole derivative.

  本发明旨在提供一种具有高发射效率的发光元件，其包括一种具有宽能隙的新型咔唑衍生物，可以用作发光元件中的传输层或主体材料。通过使用咔唑衍生物，可以提供一种在二苯并噻吩或二苯并呋喃的4位与咔唑的2位或3位结合的咔唑衍生物。此外，通过使用咔唑衍生物，还可以提供具有高发射效率的发光元件。
• Light-emitting element and electronic device
  申请人：Seo Satoshi

  公开号：US08673459B2

  公开（公告）日：2014-03-18

  An object is to provide a light-emitting element with high emission efficiency which includes a novel carbazole derivative that has a wide energy gap and can be used for a transport layer or a host material in a light-emitting element. A carbazole derivative in which the 4-position of dibenzothiophene or dibenzofuran is bonded to the 2- or 3-position of carbazole has been able to be provided by use of the carbazole derivative. Further, a light-emitting element having high emission efficiency has been able to be provided by use of the carbazole derivative.

  本发明旨在提供一种具有高发射效率的发光元件，其中包括一种具有宽能隙并可用于发光元件中的传输层或宿主材料的新型咔唑衍生物。通过使用咔唑衍生物，可以提供一种将二苯并噻吩或二苯并呋喃的4位与咔唑的2位或3位键合的咔唑衍生物。此外，通过使用该咔唑衍生物，可以提供具有高发射效率的发光元件。
• Carbazole compound, material for light-emitting element, organic semiconductor material, light-emitting element
  申请人：Osaka Harue

  公开号：US09133173B2

  公开（公告）日：2015-09-15

  To provide a novel carbazole compound that has an excellent carrier-transport property and can be used for a transport layer or as a host material in a light-emitting element. Further, to provide an organic semiconductor material and a material for a light-emitting element using the carbazole compound. A carbazole compound in which the 4-position of a dibenzothiophene skeleton or a dibenzofuran skeleton is substituted with the 2- or 3-position of a carbazole skeleton directly or via an arylene group can be synthesized. The carbazole compound is found to have a suitable carrier-transport property, a good film quality, and be used suitably as a material of a light-emitting element and an organic semicondcutor material. Note that nitrogen of the carbazole skeleton is substituted with any of a phenyl group, a biphenyl group, and a naphthyl group.

  提供一种新型的咔唑化合物，具有出色的载流子传输性能，可用作输运层或发光元件中的主体材料。此外，提供使用该咔唑化合物的有机半导体材料和发光元件材料。可以合成一种咔唑化合物，其二苯并噻吩骨架或二苯并呋喃骨架的4位被直接或通过芳基烃基取代为咔唑骨架的2位或3位。发现该咔唑化合物具有适当的载流子传输性能、良好的薄膜质量，并适用于发光元件材料和有机半导体材料。请注意，咔唑骨架的氮原子被苯基、联苯基和萘基中的任何一种取代。