4,4-dichloro-but-3-enal | 15447-69-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4,4-dichloro-but-3-enal
• 英文别名: 4,4-Dichlor-buten-(3)-al；4,4-Dichlorobut-3-enal；4,4-dichlorobut-3-enal
• CAS: 15447-69-5
• 化学式: C₄H₄Cl₂O
• 分子量: 138.981
• InChiKey: IHUPEUXCUPHNHI-UHFFFAOYSA-N

物化性质

• 沸点：
  10-20 °C(Press: 1 Torr)
• 密度：
  1.286±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  7
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4,4-dichloro-but-3-enal 在 chromium(VI) oxide 作用下， 生成 4,4-dichloro-but-3-enoic acid
  参考文献：
  名称：

  Le Coq,A.; Levas,E., Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1967, vol. 264, p. 1200 - 1203

  摘要：

  DOI：
• 作为产物：
  描述：

  dichloro-4,4 epoxy-1,2 butene-3 在 三氟化硼乙醚 作用下， 生成 4,4-dichloro-but-3-enal
  参考文献：
  名称：

  Le Coq,A.; Levas,E., Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1967, vol. 264, p. 1200 - 1203

  摘要：

  DOI：

文献信息

• N-biphenylamides and fungicidal compositions containing the same
  申请人：Sakaguchi Hiroshi

  公开号：US20050192359A1

  公开（公告）日：2005-09-01

  A N-biphenylamide compound of the formula (1): wherein R 1 , R 2 , R 3 , R 4 and R 5 independently represent a hydrogen atom, halogen atom or the like, R 6 represents C1-C6 alkyl and the like, R 7 represents a hydrogen atom or C1-C3 alkyl, R 8 represents a hydrogen atom or C1-C3 alkyl, R 9 and R 10 independently represents a halogen atom, C1-C6 alkyl, C1-C6 alkoxy or the like, R 11 , R 12 and R 13 independently represent a hydrogen atom, halogen atom or the like, R 14 , R 15 , R 16 and R 17 independently is a hydrogen atom, halogen atom or the like, X 1 represents an oxygen atom or sulfur atom, X 2 represents an oxygen atom or sulfur atom; has excellent effect aginst plant diseases.

  化合物的结构式（1）为N-联苯酰胺，其中R1，R2，R3，R4和R5独立地表示氢原子，卤素原子或类似物，R6表示C1-C6烷基或类似物，R7表示氢原子或C1-C3烷基，R8表示氢原子或C1-C3烷基，R9和R10独立地表示卤素原子，C1-C6烷基，C1-C6烷氧基或类似物，R11，R12和R13独立地表示氢原子，卤素原子或类似物，R14，R15，R16和R17独立地为氢原子，卤素原子或类似物，X1表示氧原子或硫原子，X2表示氧原子或硫原子；具有优异的植物病害防治效果。
• AMIDE DERIVATIVE, PEST CONTROL AGENT CONTAINING THE AMIDE DERIVATIVE, AND USE OF THE AMIDE DERIVATIVE
  申请人：Kobayashi Yumi

  公开号：US20110201687A1

  公开（公告）日：2011-08-18

  An amide derivative represented by the following Formula (1) is provided as an amide derivative showing a significantly excellent effect for a pest control action. In the following Formula (1), A represents a carbon atom, a nitrogen atom, or the like, and K represents a non-metal atomic group necessary for forming a cyclic linking group derived from benzene or a heterocyclie. X represents a halogen atom or the like; n represents an integer of from 0 to 4 . R 1 and R 2 represent hydrogen atoms, alkyl groups, or the like. T represents —C(=G 1 )-Q 1 or —C(=G 1 )-G 2 Q 2 , and G 1 to G 3 each represent oxygen atoms or the like. Q 1 and Q 2 each represent a hydrogen atom, an alkyl group, an aryl group, or the like. Y 1 and Y 5 each represent a halogen atom or the like, Y 2 and Y 4 each represent a hydrogen atom or the like, and Y 3 represents a C2-C5 haloalkyl group.

  提供以下式子（1）表示的酰胺衍生物，作为一种表现出显著杀虫作用的酰胺衍生物。在下面的式子（1）中，A代表碳原子、氮原子或类似物，K代表必要的非金属原子团，用于形成从苯或杂环中得到的环链连接基。X代表卤素原子或类似物；n代表0至4的整数。R1和R2代表氢原子、烷基或类似物。T代表- C（= G1）- Q1或- C（= G1）- G2Q2，G1到G3每个代表氧原子或类似物。Q1和Q2每个代表氢原子、烷基、芳基或类似物。Y1和Y5每个代表卤素原子或类似物，Y2和Y4每个代表氢原子或类似物，Y3代表C2-C5卤代烷基。
• N-BIPHENYLAMIDES AND FUNGICIDAL COMPOSITIONS CONTAINING THE SAME
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1486483A1

  公开（公告）日：2004-12-15

  A N-biphenylamide compound of the formula (1): wherein R1, R2, R3, R4 and R5 independently represent a hydrogen atom, halogen atom or the like, R6 represents C1-C6 alkyl and the like, R7 represents a hydrogen atom or C1-C3 alkyl, R8 represents a hydrogen atom or C1-C3 alkyl, R9 and R10 independently represents a halogen atom, C1-C6 alkyl, C1-C6 alkoxy or the like, R11, R12 and R13 independently represent a hydrogen atom, halogen atom or the like, R14, R15, R16 and R17 independently is a hydrogen atom, halogen atom or the like, X1 represents an oxygen atom or sulfur atom, X2 represents an oxygen atom or sulfur atom; has excellent effect aginst plant diseases.

  一种式（1）的 N-联苯酰胺化合物： 其中 R1、R2、R3、R4 和 R5 独立地代表氢原子、卤素原子或类似物，R6 代表 C1-C6 烷基或类似物，R7 代表氢原子或 C1-C3 烷基、 R8 代表氢原子或 C1-C3 烷基、 R9 和 R10 分别代表卤素原子、C1-C6 烷基、C1-C6 烷氧基或类似物、 R11、R12 和 R13 独立地代表氢原子、卤素原子或类似物，R14、R15、R16 和 R17 独立地代表氢原子、卤素原子或类似物，X1 代表氧原子或硫原子，X2 代表氧原子或硫原子； 对植物病害有很好的防治效果。
• AMIDE DERIVATIVE, PEST CONTROL AGENT CONTAINING THE AMIDE DERIVATIVE AND USE OF THE PEST CONTROL AGENT
  申请人：Mitsui Chemicals Agro, Inc.

  公开号：EP2319830A1

  公开（公告）日：2011-05-11

  An amide derivative represented by the following Formula (1) is provided as an amide derivative showing a significantly excellent effect for a pest control action. In the following Formula (1), A represents a carbon atom, a nitrogen atom, or the like, and K represents a non-metal atomic group necessary for forming a cyclic linking group derived from benzene or a heterocyclie. X represents a halogen atom or the like; n represents an integer of from 0 to 4. R1 and R2 represent hydrogen atoms, alkyl groups, or the like. T represents -C(=G1)-Q1 or -C(=G1)-G2Q2, and G1 to G3 each represent oxygen atoms or the like. Q1 and Q2 each represent a hydrogen atom, an alkyl group, an aryl group, or the like. Y1 and Y5 each represent a halogen atom or the like, Y2 and Y4 each represent a hydrogen atom or the like, and Y3 represents a C2-C5 haloalkyl group.

  下式(1)代表的酰胺衍生物作为一种酰胺衍生物，在害虫防治方面具有显著的优异效果。 在下式（1）中，A 代表碳原子、氮原子或类似物，K 代表形成源自苯或杂环的环状连接基团所必需的非金属原子团。X 代表卤素原子或类似物；n 代表 0 至 4 的整数。R1 和 R2 代表氢原子、烷基或类似物。T 代表 -C(=G1)-Q1 或 -C(=G1)-G2Q2，G1 至 G3 各自代表氧原子或类似物。Q1 和 Q2 各自代表氢原子、烷基、芳基或类似物。Y1 和 Y5 分别代表卤原子或类似物，Y2 和 Y4 分别代表氢原子或类似物，Y3 代表 C2-C5 卤代烷基。
• PEST CONTROL AGENT CONTAINING AN AMIDE DERIVATIVE AND USE OF THE PEST CONTROL AGENT
  申请人：Mitsui Chemicals Agro, Inc.

  公开号：EP3081552A1

  公开（公告）日：2016-10-19

  An amide derivative represented by the following Formula (1) is provided as an amide derivative showing a significantly excellent effect for a pest control action. In the following Formula (1), A represents a carbon atom, a nitrogen atom, or the like, and K represents a non-metal atomic group necessary for forming a cyclic linking group derived from benzene or a heterocyclie. X represents a halogen atom or the like; n represents an integer of from 0 to 4. R1 and R2 represent hydrogen atoms, alkyl groups, or the like. T represents -C(=G1)-Q1 or -C(=G1)-G2Q2, and G1 to G3 each represent oxygen atoms or the like. Q1 and Q2 each represent a hydrogen atom, an alkyl group, an aryl group, or the like. Y1 and Y5 each represent a halogen atom or the like, Y2 and Y4 each represent a hydrogen atom or the like, and Y3 represents a C2-C5 haloalkyl group.

  下式(1)代表的酰胺衍生物作为一种酰胺衍生物，在害虫防治方面具有显著的优异效果。 在下式（1）中，A 代表碳原子、氮原子或类似物，K 代表形成源自苯或杂环的环状连接基团所必需的非金属原子团。X 代表卤素原子或类似物；n 代表 0 至 4 的整数。R1 和 R2 代表氢原子、烷基或类似物。T 代表 -C(=G1)-Q1 或 -C(=G1)-G2Q2，G1 至 G3 各自代表氧原子或类似物。Q1 和 Q2 各自代表氢原子、烷基、芳基或类似物。Y1 和 Y5 分别代表卤原子或类似物，Y2 和 Y4 分别代表氢原子或类似物，Y3 代表 C2-C5 卤代烷基。