3-Bromo-1,2,5-triaminobenzene | 17625-82-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-Bromo-1,2,5-triaminobenzene
• 英文别名: 6-bromo-1,2,4-triamino-benzene；6-Bromobenzene-1,2,4-triamine
• CAS: 17625-82-0
• 化学式: C₆H₈BrN₃
• 分子量: 202.054
• InChiKey: ZHJDHKSKSXCPFL-UHFFFAOYSA-N

物化性质

• 沸点：
  367.6±37.0 °C(Predicted)
• 密度：
  1.796±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  78.1
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-溴-4,6-二硝基苯胺 在 镍 作用下， 以 水 、 溶剂黄146 为溶剂， 生成 3-Bromo-1,2,5-triaminobenzene
  参考文献：
  名称：

  Process for the preparation of triamino benzenes by catalytic

  摘要：

  通过在含有至少一个摩尔等量的单酸或二酸的水中对2,4-二硝基苯胺进行催化氢化，可以高产高纯度地得到1,2,4-三氨基苯。这些产物被认为是染料和生物杀菌剂的中间体，具有重要的用途。

  公开号：

  US04141917A1

文献信息

• Chemical- and Sediment-Mediated Reduction of the Azo Dye Disperse Blue 79
  作者：Eric J. Weber、Rebecca L. Adams

  DOI：10.1021/es00005a005

  日期：1995.5.1

  Disperse Blue 79, a large volume disperse azo dye, and 2-bromo-4,6-dinitroaniline (BDNA), an important intermediate in the preparation of Disperse Blue 79, were readily reduced chemically and in three anoxic sediment-water systems studied; half-lives were on the order of minutes to hours. No reduction of Disperse Blue 79 or BDNA was observed however in a sediment-water system containing sediment with low organic carbon. The reaction kinetics of Disperse Blue 79 in the reducing Sediments are biphasic, that is, the initial rapid loss of dye is followed by a much slower rate of transformation. The reaction pathways for the chemical and sediment-mediated reduction of Disperse Blue 79 were quite similar, suggesting that the chemical reduction of such complex chemicals can provide valuable insight into their reaction pathways in environmental systems. For Disperse Blue 79, a number of reaction products resulting from the reduction of both the azo linkage and aromatic nitro groups were formed. The sediment-mediated reduction of BDNA was regioselective resulting in the formation of a 3-bromo-5-nitro-1,2-diaminobenzene, which was further reduced at a much slower rate to B-bromo-1,2,4-triaminobenzene. These results suggest that Disperse Blue 79 and BDNA may undergo reduction in some natural anoxic sediments, resulting in the subsequent release of potentially hazardous aromatic amines to the water column.
• US4141917A
  申请人：——

  公开号：US4141917A

  公开（公告）日：1979-02-27
• Process for the preparation of triamino benzenes by catalytic
  申请人：Hoechst Aktiengesellschaft

  公开号：US04141917A1

  公开（公告）日：1979-02-27

  1,2,4-TRIAMINO BENZENES ARE OBTAINED IN HIGH YIELD AND PURITY BY CATALYTIC HYDROGENATION OF 2,4-DINITRO ANILINES IN WATER CONTAINING AT LEAST ONE MOLAR EQUIVALENT OF A MONO- OR DI-CARBOXYLIC ACID. The products are known and useful as intermediates for dyes and biocides.

  通过在含有至少一个摩尔等量的单酸或二酸的水中对2,4-二硝基苯胺进行催化氢化，可以高产高纯度地得到1,2,4-三氨基苯。这些产物被认为是染料和生物杀菌剂的中间体，具有重要的用途。