N,N'-bis(1,1-dimethyl-2-oxopropyl)diazine | 88842-48-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: N,N'-bis(1,1-dimethyl-2-oxopropyl)diazine
• 英文别名: 3,3'-[(E)-Diazenediyl]bis(3-methylbutan-2-one)；3-methyl-3-[(2-methyl-3-oxobutan-2-yl)diazenyl]butan-2-one
• CAS: 88842-48-2
• 化学式: C₁₀H₁₈N₂O₂
• 分子量: 198.265
• InChiKey: NFGAGPCVQFOEQO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  58.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-amino-3-methyl-2-butanone hydrochloride hydrate 在 吡啶 、 iodine pentafluoride 作用下， 以 二氯甲烷 为溶剂， 以55%的产率得到N,N'-bis(1,1-dimethyl-2-oxopropyl)diazine
  参考文献：
  名称：

  Synthesis and crystallography of 2,3,3,5,6,6-hexamethyl-3,6-dihydropyrazine hexahydrate and 3-amino-3-methyl-2-butanone hydrochloride

  摘要：

  DOI：

  10.1021/jo00181a013

文献信息

• VERFAHREN ZUR HERSTELLUNG VON NITRILKAUTSCHUKEN IN ORGANISCHEN LÖSUNGSMITTELN
  申请人：ARLANXEO Deutschland GmbH

  公开号：EP2611837B1

  公开（公告）日：2017-03-15
• Process for the Preparation of the Alkoxyamine 2-Methyl-2-[N-(Diethoxyphosphoryl-2,2-Dimethylpropyl)-Aminoxy] Propionic Acid
  申请人：Couturier Jean-Luc

  公开号：US20080221354A1

  公开（公告）日：2008-09-11

  The present invention relates to a process for the preparation of the alkoxyamine 2-methyl-2-[N-(diethoxy-phosphoryl-2,2-dimethylpropyl)aminoxy]propionic acid or of its salts comprising a stage of saponification of an azo compound in the presence of a base, a stage of photolysis of the salt resulting from the saponification stage in the presence of N-(tert-butyl)-1-diethylphosphono-2,2-dimethylpropyl nitroxide and optionally a stage of acidification of the salt of the alkoxyamine obtained on conclusion of the photolysis stage. The alkoxyamine or its salts can be used as radical polymerization initiators.
• NUCLEIC ACID AMPLIFICATION
  申请人：LIFE TECHNOLOGIES CORPORATION

  公开号：US20140147852A1

  公开（公告）日：2014-05-29

  In some embodiments, the present teachings provide methods for nucleic acid amplification, comprising forming a reaction mixture, and subjecting the reaction mixture to conditions suitable for nucleic acid amplification. In some embodiments, methods for nucleic acid amplification include subjecting the nucleic acid to be amplified to partially denaturing conditions. In some embodiments, methods for nucleic acid amplification include amplifying without fully denaturing the nucleic acid that is amplified. In some embodiments, the methods for nucleic acid amplification employ an enzyme that catalyzes homologous recombination and a polymerase. In some embodiments, methods for nucleic acid amplification can be conducted in a single reaction vessel. In some embodiments, methods for nucleic acid amplification can be conducted in a single continuous liquid phase of a reaction mixture, without need for compartmentalization of the reaction mixture or immobilization of reaction components. In some embodiments, methods for nucleic acid amplification comprise a amplifying at least one polynucleotide onto a surface under isothermal amplification conditions, optionally in the presence of a polymer. The polymer can include a sieving agent and/or a diffusion-reducing agent.
• EXFOLIATED GRAPHITE-RESIN COMPOSITE MATERIAL AND METHOD FOR PRODUCING THE SAME
  申请人：SEKISUI CHEMICAL CO., LTD.

  公开号：US20150175778A1

  公开（公告）日：2015-06-25

  There is provided an exfoliated graphite-resin composite material that has high dispersibility in resins and the like and is easily handled. An exfoliated graphite-resin composite material in which exfoliated graphite and a resin form a composite. When an amount of methylene blue adsorbed per g of the exfoliated graphite-resin composite material (μmol/g) is y, the amount of methylene blue adsorbed as measured based on a difference between an absorbance of a methanol solution of methylene blue at a concentration of 10 mg/L and an absorbance of a supernatant liquid obtained by introducing the exfoliated graphite-resin composite material into the methanol solution of methylene blue and performing centrifugation, and a BET specific surface area (m 2 /g) of the exfoliated graphite-resin composite material is x, a ratio y/x is 0.15 or more, and the BET specific surface area is 25 m 2 /g or more.
• US9683091B2
  申请人：——

  公开号：US9683091B2

  公开（公告）日：2017-06-20