Bis(2-(2,2,2-Trifluoroethoxy)ethyl)ether | 80054-74-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Bis(2-(2,2,2-Trifluoroethoxy)ethyl)ether
• 英文别名: 1,1,1-trifluoro-2-[2-[2-(2,2,2-trifluoroethoxy)ethoxy]ethoxy]ethane
• CAS: 80054-74-6
• 化学式: C₈H₁₂F₆O₃
• 分子量: 270.172
• InChiKey: UHIKTEOLOIVDKF-UHFFFAOYSA-N

物化性质

• 沸点：
  207.7±35.0 °C(Predicted)
• 密度：
  1.271±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  2-重氮基-1,1,1-三氟乙烷 、 二乙二醇 在 tetrafluoroboric acid 作用下， 以 氘代氯仿 为溶剂， 以100%的产率得到Bis(2-(2,2,2-Trifluoroethoxy)ethyl)ether
  参考文献：
  名称：

  Acid-catalyzed reactions of 2,2,2-trifluorodiazoethane for analysis of functional groups by fluorine-19 nuclear magnetic resonance spectrometry

  摘要：

  DOI：

  10.1021/ac00240a040

文献信息

• Nonaqueous electrolyte solution and nonaqueous electrolyte secondary battery
  申请人：ADEKA CORPORATION

  公开号：US10734684B2

  公开（公告）日：2020-08-04

  Disclosed is a nonaqueous secondary battery having a nonaqueous electrolyte containing a lithium salt dissolved in an organic solvent, in which the positive electrode active material is preferably a manganese-containing, lithium transition metal oxide salt. The nonaqueous electrolyte contains at least one compound of general formula (1), preferably at least one compound of general formula (1′). The content of the compound of formula (1) or (1′) in the nonaqueous electrolyte is preferably 0.001 to 10 mass %. The symbols in formulae (1) and (1′) are as defined in the description.

  揭示了一种非水性二次电池，其非水性电解质中含有溶解在有机溶剂中的锂盐，其中正极活性材料最好是含锰的锂过渡金属氧化物盐。非水性电解质至少包含一个一般式（1）的化合物，最好至少包含一个一般式（1′）的化合物。在非水性电解质中，化合物的一般式（1）或（1′）的含量最好为0.001至10质量%。式（1）和（1′）中的符号如描述中所定义。
• Nonaqueous electrolytic solution and nonaqueous secondary battery
  申请人：DENSO CORPORATION

  公开号：EP1202373A2

  公开（公告）日：2002-05-02

  A nonaqueous electrolytic solution having an electrolyte salt dissolved in an organic solvent, which contains a silicon compound having an unsaturated bond which is represented by formula (I): wherein R1, R2, R3, R4, R5, and R6 each represent an alkyl group, an alkoxy group, an alkenyl group, an alkenyloxy group, an alkynyl group, an alkynyloxy group, an aryl group or an aryloxy group, each of which may have an ether bond in the chain thereof; n represents a number of from 0 to 5; when n is 1 to 5, X represents a single bond, an oxygen atom, an alkylene group, an alkylenedioxy group, an alkenylene group, an alkenylenedioxy group, an alkynylene group, an alkynylenedioxy group, an arylene group or an arylenedioxy group; provided that at least one of R1, R2, R3, R4, R5, R6, and X represents a group containing an unsaturated bond, an organotin compound or an organogermanium compound and a nonaqueous secondary battery having the same.

  一种非水电解溶液，其电解质盐溶解在有机溶剂中，其中含有一种具有不饱和键的硅化合物，该硅化合物由式(I)表示： 其中 R1、R2、R3、R4、R5 和 R6 各代表一个烷基、一个烷氧基、一个烯基、一个烯氧基、一个炔基、一个炔氧基、一个芳基或一个芳氧基，其中每个基团的链中都可以有一个醚键；n 代表 0 至 5 的数字；当 n 为 1 至 5 时，X 代表单键、氧原子、亚烷基、亚烷基二氧基、亚烯基、亚烯基二氧基、亚炔基、亚炔基二氧基、芳基或芳基二氧基；条件是 R1、R2、R3、R4、R5、R6 和 X 中至少有一个代表含有不饱和键的基团、 有机锡化合物或有机锗化合物以及具有相同性质的非水二次电池。
• NON-AQUEOUS ELECTROLYTE SOLUTION AND NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY
  申请人：Adeka Corporation

  公开号：EP3352281B1

  公开（公告）日：2021-08-11
• NONAQUEOUS ELECTROLYTE SOLUTION AND NONAQUEOUS ELECTROPLYTE SECONDARY BATTERY
  申请人：ADEKA CORPORATION

  公开号：US20180226683A1

  公开（公告）日：2018-08-09

  Disclosed is a nonaqueous secondary battery having a nonaqueous electrolyte containing a lithium salt dissolved in an organic solvent, in which the positive electrode active material is preferably a manganese-containing, lithium transition metal oxide salt. The nonaqueous electrolyte contains at least one compound of general formula (1), preferably at least one compound of general formula (1′). The content of the compound of formula (1) or (1′) in the nonaqueous electrolyte is preferably 0.001 to 10 mass %. The symbols in formulae (1) and (1′) are as defined in the description.