(1-methylpentyl)succinic acid | 334709-95-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (1-methylpentyl)succinic acid
• 英文别名: 2-Hexan-2-ylbutanedioic acid
• CAS: 334709-95-4
• 化学式: C₁₀H₁₈O₄
• 分子量: 202.251
• InChiKey: XPNNLTDPULSKGP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-己醇 在 盐酸 、 sodium hydride 、 三乙胺 作用下， 以 四氢呋喃 、 乙二醇二甲醚 、 二氯甲烷 、 水 、 mineral oil 为溶剂， 反应 105.5h， 生成 (1-methylpentyl)succinic acid
  参考文献：
  名称：

  立体化学研究揭示了无氧正构烷烃细菌活化的机理

  摘要：

  的厌氧生长的细菌菌株与HxN1 Ñ己烷，得到（2几乎相等量的[R，1' - [R ）-和（2小号，1' - [R ）- （1-甲基戊基）琥珀酸酯，其通过自由基加成的形成将碳氢化合物富马酸盐化（参见方案）。上亲高选择性攻击小号氢原子的的C2 ñ -己烷与在C2上的构型的反转相关联的结合针对一个C富马酸盐和展品同位素歧视期间 2 H键。

  DOI：

  10.1002/anie.201106055

文献信息

• Biological anaerobic treatment of BTEX contamination
  申请人：Southern Illinois University

  公开号：US20040014196A1

  公开（公告）日：2004-01-22

  The present invention concerns methods for isolating microorganisms that can anaerobically degrade aromatic hydrocarbons. The present invention also concerns methods of anaerobic biodegradation of aromatic hydrocarbons.

  本发明涉及分离可厌氧降解芳香烃的微生物的方法。本发明还涉及芳香烃的厌氧生物降解方法。
• Fuel compositions with mono- or di- butyl succinate and method of use thereof
  申请人：Berglund Kris A.

  公开号：US20090090048A1

  公开（公告）日：2009-04-09

  Fuel compositions comprising primarily a mono- or di-butyl succinate as an oxygenation additive are described. The fuels can be diesel fuels which generate carbon based particulates in diesel engines. The result is reduced emissions of particulates from the diesel engines.
• ANALYSIS AND ENHANCEMENT OF METABOLIC PATHWAYS FOR METHANOGENESIS
  申请人：Havemen Shelley

  公开号：US20100035309A1

  公开（公告）日：2010-02-11

  Processes for biogenic production of a hydrogen-carbon-containing fluid from a hydrocarbon containing formation are described. The processes may include providing in the formation an anaerobic microorganism consortium containing one or more enzymes to activate a starting hydrocarbon by an addition of a chemical group to the hydrocarbon. The processes may further include converting the activated hydrocarbon into the hydrogen-carbon-containing fluid through one or more intermediate hydrocarbons, and recovering the hydrogen-carbon-containing fluid from the formation.
• BIOCONVERSION OF SHORT-CHAIN HYDROCARBONS TO FUELS AND CHEMICALS
  申请人：Gonzales Ramon

  公开号：US20180355394A1

  公开（公告）日：2018-12-13

  An engineered microorganism(s) with novel pathways for the conversion of short-chain hydrocarbons to fuels and chemicals (e.g. carboxylic acids, alcohols, hydrocarbons, and their alpha-, beta-, and omega-functionalized derivatives) is described. Key to this approach is the use of hydrocarbon activation enzymes able to overcome the high stability and low reactivity of hydrocarbon compounds through the cleavage of an inert C—H bond. Oxygen-dependent or oxygen-independent activation enzymes can be exploited for this purpose, which when combined with appropriate pathways for the conversion of activated hydrocarbons to key metabolic intermediates, enables the generation of product precursors that can subsequently be converted to desired compounds through established pathways. These novel engineered microorganism(s) provide a route for the production of fuels and chemicals from short chain hydrocarbons such as methane, ethane, propane, butane, and pentane.
• Bioconversion of Short-Chain Hydrocarbons to Fuels and Chemicals
  申请人：Gonzalez Ramon

  公开号：US20200347423A1

  公开（公告）日：2020-11-05

  An engineered microorganism(s) with novel pathways for the conversion of short-chain hydrocarbons to fuels and chemicals (e.g. carboxylic acids, alcohols, hydrocarbons, and their alpha-, beta-, and omega-functionalized derivatives) is described. Key to this approach is the use of hydrocarbon activation enzymes able to overcome the high stability and low reactivity of hydrocarbon compounds through the cleavage of an inert C—H bond. Oxygen-dependent or oxygen-independent activation enzymes can be exploited for this purpose, which when combined with appropriate pathways for the conversion of activated hydrocarbons to key metabolic intermediates, enables the generation of product precursors that can subsequently be converted to desired compounds through established pathways. These novel engineered microorganism(s) provide a route for the production of fuels and chemicals from short chain hydrocarbons such as methane, ethane, propane, butane, and pentane.