2-甲基-1,4-苯二基二(4-[4-[(1-氧代-2-丙烯基)氧基]丁氧基]苯甲酸酯) | 132900-75-5

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 中文名称: 2-甲基-1,4-苯二基二(4-[4-[(1-氧代-2-丙烯基)氧基]丁氧基]苯甲酸酯)
• 英文名称: 2-methyl-1,4-phenylene bis(4-(4-(acryloyloxy)butoxy)-benzoate)
• 英文别名: 2,5-bis (4-(4-acryloyloxybutoxy)benzoyloxy)toluene；2-Methyl-1,4-phenylene bis(4-(4-(acryloyloxy)butoxy)benzoate)；[3-methyl-4-[4-(4-prop-2-enoyloxybutoxy)benzoyl]oxyphenyl] 4-(4-prop-2-enoyloxybutoxy)benzoate
• CAS: 132900-75-5
• 化学式: C₃₅H₃₆O₁₀
• 分子量: 616.665
• InChiKey: NLGINBDFXRCWQW-UHFFFAOYSA-N

物化性质

• 沸点：
  748.5±60.0 °C(Predicted)
• 密度：
  1.195±0.06 g/cm3(Predicted)
• LogP：
  5.1 at 25℃ and pH7

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  45
• 可旋转键数：
  22
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  124
• 氢给体数：
  0
• 氢受体数：
  10

安全信息

• 危险性防范说明：
  P261,P280,P301+P312,P302+P352,P305+P351+P338
• 危险性描述：
  H302,H315,H319,H335

反应信息

• 作为产物：
  描述：

  4-(4-(丙烯酰氧基)丁氧基)苯甲酸 在 N-甲基咪唑 、 氯化亚砜 、 2,3-dibutyl-6-methylphenol 、 三乙胺 作用下， 以 四氢呋喃 、 乙酸乙酯 、 N,N-二甲基甲酰胺 为溶剂， 反应 5.0h， 生成 2-甲基-1,4-苯二基二(4-[4-[(1-氧代-2-丙烯基)氧基]丁氧基]苯甲酸酯)
  参考文献：
  名称：

  JP5728313

  摘要：

  公开号：

文献信息

• [EN] POLYMERIZABLE COMPOUND AND OPTICALLY ANISOTROPIC BODY<br/>[FR] COMPOSÉ POLYMÉRISABLE ET CORPS OPTIQUEMENT ANISOTROPE
  申请人：DAINIPPON INK & CHEMICALS

  公开号：WO2017079867A1

  公开（公告）日：2017-05-18

  There is provided a polymerizable composition, by which discoloration or alignment defects are less likely to occur when a filmy polymer, which is obtained by adding a polymerizable compound to the polymerizable composition and polymerizing this composition, is irradiated with ultraviolet light. There are also provided a polymer obtained by polymerizing the polymerizable composition, and an optically anisotropic body using the polymer. The present invention provides a polymerizable low-wavelength dispersive or polymerizable reverse-wavelength dispersive compound having a partial structure represented by Formula (Z-0). Further, the present invention provides a composition containing the compound; a polymer obtained by polymerizing the composition; and an optically anisotropic body obtained by using the polymer.

  提供一种可聚合的组合物，通过该组合物得到的薄膜聚合物在紫外光照射时，不太容易发生变色或排列缺陷。还提供了通过聚合该聚合物组合物得到的聚合物，以及使用该聚合物的光学各向异性体。本发明提供了一种具有由式（Z-0）表示的部分结构的可聚合低波长色散或可聚合反波长色散化合物。此外，本发明提供了一种含有该化合物的组合物；通过聚合该组合物得到的聚合物；以及通过使用该聚合物得到的光学各向异性体。
• COMPOUND, COMPOSITION, CURED PRODUCT, OPTICALLY ANISOTROPIC BODY, AND REFLECTIVE FILM
  申请人：FUJIFILM Corporation

  公开号：US20210198230A1

  公开（公告）日：2021-07-01

  The present invention provides a compound having an excellent rate of change in HTP due to exposure. The present invention further provides a composition formed of the compound, a cured product, an optically anisotropic body, and a reflective film. The compound of the present invention is a compound represented by General Formula (1).

  本发明提供了一种由于暴露而具有优异的高温性能变化率的化合物。本发明还提供了由该化合物形成的组合物、固化产品、光学各向异性体和反射膜。本发明的化合物是由一般式（1）表示的化合物。
• POLYMERIZABLE LIQUID CRYSTAL COMPOUND, COMPOSITION, LIQUID CRYSTAL POLYMERIZATION FILM-KIND THEREOF AND USE THEREOF
  申请人：JNC CORPORATION

  公开号：US20170174992A1

  公开（公告）日：2017-06-22

  An object is to provide a polymerizable liquid crystal compound, a polymerizable liquid crystal composition containing the compound and liquid crystal polymerization film-kind capable of controlling chromatic dispersion characteristics and having low positive chromatic dispersion characteristics. An aspect can be exemplified in which the polymerizable liquid crystal compound is represented by formula (1): in which, in formula (1), G is a group composed of a quinoline skeleton, an isoquinoline skeleton, a quinoxaline skeleton or a quinazoline skeleton, A 1 is 1,4-phenylene or 1,4-cyclohexylene, Z 1 is a connecting group, m is an integer from 0 to 3, and R 1 is a group containing a polymerizable group.

  提供一种可聚合的液晶化合物，包含该化合物的可聚合液晶组合物以及能够控制色散特性并具有低正色散特性的液晶聚合膜。一种例子是该可聚合液晶化合物由式(1)表示：其中，在式(1)中，G是由喹啉骨架、异喹啉骨架、喹啉骨架或喹嗪骨架组成的基团，A1为1,4-苯基或1,4-环己基，Z1为连接基，m为0至3的整数，R1为含有可聚合基团的基团。
• POLYMERIZABLE LIQUID CRYSTAL COMPOUND, POLYMERIZABLE LIQUID CRYSTAL COMPOSITION, AND LIQUID CRYSTAL POLYMERIZED FILMS
  申请人：JNC CORPORATION

  公开号：US20180119014A1

  公开（公告）日：2018-05-03

  To provide a polymerizable liquid crystal compound in order to produce a retardation film having excellent front contrast. A polymerizable liquid crystal composition including a compound represented by Formula (1). In Formula (1), for example, W 1 is an alkoxycarbonyl group having 1 to 10 carbon atoms, an alkanoyl group having 1 to 10 carbon atoms, or a polymerizable functional group, A 1 is independently 1,4-phenylene or naphthalene-2,6-diyl, Z 1 is a linking group, m and n are independently an integer of 0 to 7, and satisfy 3≤m+n≤8, and P 1 is a polymerizable functional group.

  为了生产具有优异前对比度的减速膜，提供一种可聚合液晶化合物。包括由式（1）表示的化合物的可聚合液晶组合物。在式（1）中，例如，W1是具有1至10个碳原子的烷氧羰基、具有1至10个碳原子的烷酰基或可聚合官能团，A1独立地为1,4-苯撑或萘-2,6-二基，Z1为连接基，m和n独立地为0至7的整数，并满足3≤m+n≤8，P1为可聚合官能团。
• Liquid crystal composition, method for manufacturing the same, and film
  申请人：FUJIFILM Corporation

  公开号：US09464228B2

  公开（公告）日：2016-10-11

  A method for manufacturing a liquid crystal composition, the method including concurrently obtaining a liquid crystal compound represented by the formula (I) and a liquid crystal compound represented by the formula (II), by allowing a compound represented by the formula (III) to react with a carboxylic acid represented by the formula (IV) and a carboxylic acid represented by the formula (V), wherein P1 represents a polymerizable group; Sp1 represents a C3-12 divalent aliphatic group, etc; T1 represents a 1,4-phenylene group; T2 represents a divalent group having a single bond or cyclic structure; A1 represents —COO—, etc; A2 and A3 represents —OCO—, etc; X represents a hydrogen atom, C1-12 alkyl group, etc; Y1 and Y2 represents O, NR1 or S; R1 represents a hydrogen atom or methyl group; Formula (I) P1-Sp1-T1-A1-B-A2-T1-Sp1-P1; Formula (II) P1-Sp1-T1-A1-B-A3-T2-X; Formula (III) being HY1—B—Y2H; Formula (IV) P1-Sp1-T1-COOH; Formula (V) X-T2-COOH.

  一种制备液晶组分的方法，该方法包括同时获得由公式（I）表示的液晶化合物和由公式（II）表示的液晶化合物，通过让由公式（III）表示的化合物与由公式（IV）表示的羧酸和由公式（V）表示的羧酸反应得到，其中P1表示可聚合基团；Sp1表示C3-12二价脂肪族基团等；T1表示1,4-苯基基团；T2表示具有单键或环状结构的二价基团；A1表示—COO—等；A2和A3表示—OCO—等；X表示氢原子、C1-12烷基等；Y1和Y2表示O、NR1或S；R1表示氢原子或甲基基团；公式（I）为P1-Sp1-T1-A1-B-A2-T1-Sp1-P1；公式（II）为P1-Sp1-T1-A1-B-A3-T2-X；公式（III）为HY1—B—Y2H；公式（IV）为P1-Sp1-T1-COOH；公式（V）为X-T2-COOH。