2-甲基-2-丙烯酸-1,10-癸二酯 | 6701-13-9

• 物质功能分类: 医药中间体 - 原料药中间体
• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 2-甲基-2-丙烯酸-1,10-癸二酯
• 中文别名: 1,10-癸二醇二甲基丙烯酸酯；2-甲基-2-丙烯酸-1,1-癸二酯
• 英文名称: decanediol dimethacrylate
• 英文别名: 1,10-decanediol di(meth)acrylate；D₃MA；1,10-decamethylene glycol dimethacrylate；1,10-Decanediol dimethacrylate；10-(2-methylprop-2-enoyloxy)decyl 2-methylprop-2-enoate
• CAS: 6701-13-9
• 化学式: C₁₈H₃₀O₄
• mdl: MFCD00080452
• 分子量: 310.434
• InChiKey: LRZPQLZONWIQOJ-UHFFFAOYSA-N

物化性质

• 熔点：
  170℃/2mm
• 沸点：
  170℃/2mm
• 密度：
  0.962
• LogP：
  6.5 at 25℃
• 物理描述：
  Liquid

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  22
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.666
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 危险类别码：
  R36/37/38
• 海关编码：
  2916190090
• WGK Germany：
  3
• 危险标志：
  GHS07
• 危险性描述：
  H315,H319,H335
• 危险性防范说明：
  P305 + P351 + P338
• 储存条件：
  2-8°C

反应信息

• 作为产物：
  描述：

  1,10-癸二醇 、 甲基丙烯酸 在 硫酸 、 苯 作用下， 生成 2-甲基-2-丙烯酸-1,10-癸二酯
  参考文献：
  名称：

  Cross-linked Polymers. I. Factors Influencing the Efficiency of Cross-linking in Copolymers of Methyl Methacrylate and Glycol Dimethacrylates¹

  摘要：

  DOI：

  10.1021/ja01110a068

文献信息

• Polymer Materials With Unsaturated Transfer Reagents
  申请人：Ivoclar Vivadent AG

  公开号：US20200087241A1

  公开（公告）日：2020-03-19

  Radically polymerizable composition which contains at least one vinyl ether according to general formula I: in which the variables have the following meanings: A is H, CN, a cycloaliphatic, linear or branched aliphatic C 1 -C 30 hydrocarbon residue, an aromatic C 6 -C 30 hydrocarbon residue or a combination thereof; X is —COO—, —CON(R 3 )— or is dispensed with; B is H, CN, a cycloaliphatic, linear or branched aliphatic C 1 -C 30 hydrocarbon residue, an aromatic C 6 -C 30 hydrocarbon residue or a combination thereof; Y is —COO—, —CON(R 3 )— or is dispensed with; R 1-3 in each case independently of one another are hydrogen, a cycloaliphatic, linear or branched aliphatic C 1 -C 10 hydrocarbon residue or an aromatic C 6 -C 10 hydrocarbon residue; m is an integer from 1 to 6; n is an integer from 1 to 6; p is an integer from 1 to 6; wherein m and p cannot be greater than 1 at the same time and wherein if m=1, p=n, and if p=1, m=n.

  包含至少一种根据通式I的乙烯醚的根本聚合组合物：其中变量具有以下含义：A为H、CN、环脂肪、线性或支链脂肪C1-C30烃残基、芳香族C6-C30烃残基或它们的组合；X为—COO—、—CON(R3)—或省略；B为H、CN、环脂肪、线性或支链脂肪C1-C30烃残基、芳香族C6-C30烃残基或它们的组合；Y为—COO—、—CON(R3)—或省略；R1-3分别独立地为氢、环脂肪、线性或支链脂肪C1-C10烃残基或芳香族C6-C10烃残基；m为1到6的整数；n为1到6的整数；p为1到6的整数；其中m和p不能同时大于1，如果m=1，则p=n，如果p=1，则m=n。
• POLYMER HAVING BIS(DIPHENYLPHOSPHINO)BINAPHTHYL GROUPS
  申请人：Shimada Toyoshi

  公开号：US20100022800A1

  公开（公告）日：2010-01-28

  A polymer having bis(diphenylphosphino)binaphthyl groups that can be used as a catalyst for an addition reaction, especially an asymmetric 1,4-addition reaction, or a reduction reaction, especially an asymmetric reduction reaction, and that can be easily recovered and recycled. The polymer having the bis(diphenylphosphino)binaphthyl groups is one resulting from repetition of a racemic or optically active 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl compound substituted at 5-position thereof with an unsaturated terminal of one (meth)acryloyl group of a compound having multiple (meth)acryloyl groups, that another 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl compound of a next unit is substituted at 5′-position thereof with an unsaturated terminal of another (meth)acryloyl group of the compound having multiple (meth)acryloyl groups so as to have a molecular weight of 1500 to 10000. The reduction catalyst comprises this polymer and a transition metal.

  具有双(二苯基膦)联萘基团的聚合物可用作催化剂，特别是用于加成反应，尤其是不对称的1,4-加成反应，或还原反应，特别是不对称还原反应，并且可以轻松回收和循环利用。具有双(二苯基膦)联萘基团的聚合物是由重复使用在其5位取代有一种具有多个(甲基)丙烯酰基团的化合物的不对称或光学活性2,2′-双(二苯基膦)-1,1′-联萘化合物所得，下一个单元的另一种2,2′-双(二苯基膦)-1,1′-联萘化合物在其5′位取代有另一种具有多个(甲基)丙烯酰基团的化合物的不饱和末端，以使其分子量为1500至10000。还原催化剂包括该聚合物和过渡金属。
• [EN] (METH)ACRYLOXY-CONTAINING TRISILOXANE, SILOXANE-CONTAINING POLYMERS AND BIOMEDICAL DEVICES THEREFROM<br/>[FR] TRISILOXANE CONTENANT UN (MÉTH)ACRYLOXY, POLYMÈRES CONTENANT UN SILOXANE ET DISPOSITIFS BIOMÉDICAUX LES CONTENANT
  申请人：MOMENTIVE PERFORMANCE MAT INC

  公开号：WO2014123956A1

  公开（公告）日：2014-08-14

  There is provided a trisiloxane having a 3-(meth)acryloxy-substituted (hydroxylcyclohexyl)ethyl group, useful in making water absorbing silicone-hydrogel films for biomedical devices, such as contact lens, and a process for producing these monomers. This invention also provides for copolymers made from the trisiloxane having a 3-(meth)acryloxy-substituted (hydroxylcyclohexyl)ethyl group described herein.

  提供了一种三硅氧烷，其具有3-(甲基)丙烯氧基取代的(羟基环己基)乙基基团，可用于制备用于生物医疗器械（如隐形眼镜）的吸水硅烷凝胶膜，并提供了制备这些单体的方法。本发明还提供了由所述具有3-(甲基)丙烯氧基取代的(羟基环己基)乙基基团的三硅氧烷制成的共聚物。
• Dental Materials Based On Cyclopolymerizable Crosslinkers
  申请人：Ivoclar Vivadent AG

  公开号：US20210236388A1

  公开（公告）日：2021-08-05

  Dental material which comprises at least one compound of formula I, in which R 1 is a linear, branched or cyclic aliphatic C 1 -C 30 hydrocarbon radical or an aromatic C 6 -C 30 hydrocarbon radical, wherein the aliphatic or aromatic hydrocarbon radical can be substituted or unsubstituted and wherein aliphatic hydrocarbon radicals can be interrupted by one or more urethane groups, ester groups, oxygen atoms and/or sulfur atoms; X, Y, Z independently of each other in each case are -COOR 2 —, -CON(R 3 R 4 )—, an aromatic C 6 -C 10 hydrocarbon radical or CN, wherein R 2 , R 3 , R 4 in each case independently of each other is hydrogen, a linear, branched or cyclic aliphatic C 1 -C 30 hydrocarbon radical or an aromatic C 6 -C 30 hydrocarbon radical, wherein the aliphatic or aromatic hydrocarbon radical can be substituted or unsubstituted and wherein aliphatic hydrocarbon radicals can be interrupted by one or more oxygen atoms, and m is 2 or 3.

  牙科材料，其中至少包含一种符合以下式I的化合物，其中R1是线性、支链或环状脂肪族C1-C30碳氢化合物基团或芳香族C6-C30碳氢化合物基团，其中脂肪族或芳香族碳氢基团可以是取代的或未取代的，脂肪族碳氢基团可以被一个或多个脲基团、酯基团、氧原子和/或硫原子中断；X、Y、Z分别独立地分别为-COOR2—、-CON(R3R4)—、芳香族C6-C10碳氢化合物基团或CN，其中R2、R3、R4分别独立地为氢、线性、支链或环状脂肪族C1-C30碳氢化合物基团或芳香族C6-C30碳氢化合物基团，其中脂肪族或芳香族碳氢基团可以是取代的或未取代的，脂肪族碳氢基团可以被一个或多个氧原子中断，m为2或3。
• COLORED COMPOSITION
  申请人：WAKO PURE CHEMICAL INDUSTRIES, LTD.

  公开号：US20160040013A1

  公开（公告）日：2016-02-11

  The present invention is to provide a colored composition having higher heat resistance compared with conventional colored compositions. The present invention further relates to: “a polymer having a monomer unit derived from a monomer which has (i) a cationic rhodamine derivative having, as an counter anion, an anion including an aryl group having an electron-withdrawing substituent and an anion group and (ii) an ethylenically unsaturated bond”, “a monomer which has (i) a cationic rhodamine derivative having, as an counter anion, an anion including an aryl group having an electron-withdrawing substituent and an anion group and (ii) an ethylenically unsaturated bond”, “a colored composition comprising the above-described polymer or the monomer”, and “a colored composition for a color filter comprising the above-described polymer or the monomer”.

  本发明提供了一种具有比传统彩色组合更高耐热性的彩色组合。本发明还涉及：“具有源自具有（i）带有阴离子的阳离子罗丹明衍生物，所述阴离子包括具有电子吸引取代基的芳基和阴离子基团以及（ii）烯丙基不饱和键的单体单体单元的聚合物”，“具有（i）带有阴离子的阳离子罗丹明衍生物，所述阴离子包括具有电子吸引取代基的芳基和阴离子基团以及（ii）烯丙基不饱和键的单体单体单元的单体”，“包括上述聚合物或单体的彩色组合”，以及“用于彩色滤光片的彩色组合，包括上述聚合物或单体”。