2-Bromo-3-(decyloxy)-5-(hydroxymethyl)phenol | 820958-28-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-Bromo-3-(decyloxy)-5-(hydroxymethyl)phenol
• 英文别名: 2-bromo-3-decoxy-5-(hydroxymethyl)phenol
• CAS: 820958-28-9
• 化学式: C₁₇H₂₇BrO₃
• 分子量: 359.304
• InChiKey: SDHJNSGKFWBYFC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  21
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-Bromo-3-(decyloxy)-5-(hydroxymethyl)phenol 在 18-冠醚-6 、 potassium carbonate 、 pyridinium chlorochromate 、 sodium iodide 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 反应 40.0h， 生成 tert-butyl 2-(2-bromo-3-decoxy-5-formylphenoxy)acetate
  参考文献：
  名称：

  Dendrimers with Both Polar and Apolar Nanocontainer Characteristics

  摘要：

  Amphiphilic dendrimers with a custom-designed biaryl repeat unit have been synthesized. These dendrimers afford hydrophobic nanocontainers in polar solvents and hydrophilic nanocontainers in apolar solvents. These container properties were investigated using dye incorporation studies. The aggregation states of these dendrimers are also reported using DLS studies.

  DOI：

  10.1021/ja0449628
• 作为产物：
  描述：

  1-碘癸烷 在 18-冠醚-6 、 dimethyl sulfide borane 、 potassium carbonate 作用下， 以 四氢呋喃 、 丙酮 为溶剂， 反应 46.0h， 生成 2-Bromo-3-(decyloxy)-5-(hydroxymethyl)phenol
  参考文献：
  名称：

  Dendrimers with Both Polar and Apolar Nanocontainer Characteristics

  摘要：

  Amphiphilic dendrimers with a custom-designed biaryl repeat unit have been synthesized. These dendrimers afford hydrophobic nanocontainers in polar solvents and hydrophilic nanocontainers in apolar solvents. These container properties were investigated using dye incorporation studies. The aggregation states of these dendrimers are also reported using DLS studies.

  DOI：

  10.1021/ja0449628

文献信息

• Dendrimers with Both Polar and Apolar Nanocontainer Characteristics
  作者：Dharma Rao Vutukuri、Subhadeep Basu、S. Thayumanavan

  DOI：10.1021/ja0449628

  日期：2004.12.1

  Amphiphilic dendrimers with a custom-designed biaryl repeat unit have been synthesized. These dendrimers afford hydrophobic nanocontainers in polar solvents and hydrophilic nanocontainers in apolar solvents. These container properties were investigated using dye incorporation studies. The aggregation states of these dendrimers are also reported using DLS studies.