2-甲基-3-(2-甲基丙-2-烯酰氧基)丙酸 | 73850-50-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2-甲基-3-(2-甲基丙-2-烯酰氧基)丙酸
• 中文别名: N-[3-(二甲氨基)丙基]-1,1,2,2,3,3,4,4,5,5,6,6,6-十三氟-N-{2-[2-(2-羟基乙氧基)乙氧基]乙基}己烷-1-磺酰胺
• 英文名称: β-methacryloylhydroxyisobutyric acid
• 英文别名: 3-methacryloxy-2-methylpropionic acid；2-carboxypropyl methacrylic acid；2-Carboxypropyl methacrylate；2-methyl-3-(2-methylprop-2-enoyloxy)propanoic acid
• CAS: 73850-50-7
• 化学式: C₈H₁₂O₄
• 分子量: 172.181
• InChiKey: JPVKGOUOYQMHDD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  甲基丙烯酸 在 吩噻嗪 、 硫酸 作用下， 反应 25.0h， 生成 2-甲基-2-羟基丙酸 、 2-甲基-3-(2-甲基丙-2-烯酰氧基)丙酸
  参考文献：
  名称：

  Obmelyukhina, T. N.; Zil'berman, E. N.; Shmuilovich, S. M., Journal of applied chemistry of the USSR, 1980, vol. 53, # 2, p. 358 - 362

  摘要：

  DOI：

文献信息

• Method for Producing Carboxyl Group-Containing Water-Soluble Polymer
  申请人：Kobayashi Shinji

  公开号：US20070225522A1

  公开（公告）日：2007-09-27

  A first object of the present invention is to provide a method for producing a carboxyl group-containing water-soluble polymer capable of giving neutralized viscous solutions excellent in thickening effect even when the aqueous solutions of the carboxyl group-containing water-soluble polymer have a low concentration. A second object of the invention is to provide a method for producing a carboxyl group-containing water-soluble polymer capable of giving neutralized viscous solutions excellent in thickening effect at low concentration levels and, at the same time, capable of being dispersed and dissolved in water at high concentrations with ease. The prevent invention is a method for producing a carboxyl group-containing water-soluble polymer by reacting an α,β-unsaturated carboxylic acid and a compound having two or more ethylenically unsaturated groups in the presence of a radical polymerization initiator, which method is characterized in that the reaction is carried out in the presence of a (meth)acrylic acid derivative represented by the general formula (1): (in the formula, R 1 and R 2 each independently represents a hydrogen atom or a methyl group and n represents 1 or 2).

  本发明的第一目的是提供一种生产含羧基水溶性聚合物的方法，即使羧基水溶性聚合物的水溶液浓度较低，也能产生优良的增稠效果。本发明的第二目的是提供一种生产含羧基水溶性聚合物的方法，该方法能够在低浓度下产生优良的增稠效果，并且同时能够在高浓度下轻松分散和溶解于水中。 该方法是通过在自由基聚合引发剂存在下，使α，β-不饱和羧酸和具有两个或更多乙烯基不饱和基团的化合物反应而生产含羧基水溶性聚合物的方法。该方法的特征在于，在一般式（1）所表示的（甲）丙烯酸衍生物的存在下进行反应： （在该式中，R1和R2分别独立表示氢原子或甲基，n表示1或2）。
• MONOMER, POLYMER, RESIST COMPOSITION, AND PATTERNING PROCESS
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20140045123A1

  公开（公告）日：2014-02-13

  A polymer comprising recurring units derived from a (meth)acrylate monomer of tertiary ester type having branched alkyl on alicycle is used to form a resist composition. When subjected to exposure, PEB and organic solvent development, the resist composition is improved in dissolution contrast.

  一种聚合物，包括由具有支链烷基的萜酸酯单体衍生的重复单元，用于形成抗蚀组合物。在经过曝光、PEB和有机溶剂显影处理后，抗蚀组合物在溶解对比度方面得到改善。
• Processes for producing (meth)acrylic acid compound
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20040267045A1

  公开（公告）日：2004-12-30

  A first and second aspect of the invention relate to a process for producing a (meth)acrylic acid compound and a process for producing a (meth)acrylic ester, respectively. In particular, the second aspect of the invention relates to a process for (meth)acrylic ester production which includes a step in which by-products of a (meth)acrylic ester-yielding reaction are decomposed to recover a (meth)acrylic ester. A third aspect of the invention relates to a method of decomposing by-products of (meth)acrylic ester production in order to recover (meth)acrylic acid, a (meth)acrylic ester, and an alcohol through the decomposition of the by-products of (meth)acrylic ester production. A fourth and fifth aspect of the invention relate to a method of decomposing by-products of (meth)acrylic acid compound production in order to recover (meth)acrylic acid, a (meth)acrylic ester, and an alcohol through the decomposition of by-products of (meth)acrylic acid production and by-products of (meth)acrylic ester production.

  本发明的第一和第二方面涉及分别生产（甲基）丙烯酸化合物和生产（甲基）丙烯酸酯的过程。特别是，本发明的第二方面涉及一种（甲基）丙烯酸酯生产过程，其中包括一步骤，通过该步骤，（甲基）丙烯酸酯产生反应的副产物被分解以回收（甲基）丙烯酸酯。本发明的第三方面涉及一种分解（甲基）丙烯酸酯生产的副产物以回收（甲基）丙烯酸、（甲基）丙烯酸酯和醇的方法，通过分解（甲基）丙烯酸酯生产的副产物来实现。本发明的第四和第五方面涉及一种分解（甲基）丙烯酸化合物生产的副产物以回收（甲基）丙烯酸、（甲基）丙烯酸酯和醇的方法，通过分解（甲基）丙烯酸和（甲基）丙烯酸酯生产的副产物来实现。
• Processes for producing (meth)acrylic acid
  申请人：Yada Shuhei

  公开号：US20050004396A1

  公开（公告）日：2005-01-06

  In the purification and distillation step of acrylic acid (including (meth)acrylic acid), stable continuous operation for a long period is enabled by inhibiting the undesirable polymerization reaction of acrylic acid thereby to prevent the device from a trouble such as clogging. A process for producing acrylic acid which comprises purifying crude acrylic acid prepared by vapor-phase catalytic oxidation by distillation, wherein the concentration of β-acryloxypropionic acid in the feed stream to a distillation column mainly for the separation of water from acrylic acid is controlled to be at most one-fiftieth of the concentration of acrylic acid; the concentration of β-acryloxypropionic acid in the feed stream to a distillation column mainly for the separation of acetic acid from acrylic acid is controlled to be at most one-fortieth of the concentration of acrylic acid; and the concentration of β-acryloxypropionic acid in the feed stream to a distillation column mainly for the separation of acrylic acid from water, acetic acid and a solvent is controlled to be at most one-fiftieth of the concentration of acrylic acid.

  在丙烯酸（包括（甲）丙烯酸）的纯化和蒸馏步骤中，通过抑制丙烯酸的不良聚合反应，从而防止设备堵塞等问题，实现了长时间稳定的连续操作。制备丙烯酸的方法包括通过蒸馏纯化由气相催化氧化制备的原始丙烯酸，其中，控制在主要用于从丙烯酸中分离水的蒸馏柱的进料流中β-丙烯酰氧基丙酸的浓度最多为丙烯酸浓度的五十分之一；控制在主要用于从丙烯酸中分离乙酸的蒸馏柱的进料流中β-丙烯酰氧基丙酸的浓度最多为丙烯酸浓度的四十分之一；以及控制在主要用于从水、乙酸和溶剂中分离丙烯酸的蒸馏柱的进料流中β-丙烯酰氧基丙酸的浓度最多为丙烯酸浓度的五十分之一。
• Method of decomposing by-product during the production of (meth)acrylic ester
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20040225149A1

  公开（公告）日：2004-11-11

  A problem of the invention is to provide a method of decomposing a Michael addition reaction product formed as a by-product in the production step of a (meth)acrylic ester and recovering (meth)acrylic acid, a (meth)acrylic ester and an alcohol, in which the formation of an olefin as a by-product can be suppressed. The invention relates to a method of thermally decomposing a by-product at the time of production of a (meth)acrylic ester using an alcohol bearing a branched chain and having 3 or more carbon atoms, wherein the decomposition reaction is carried out in the absence of a catalyst.

  发明的问题是提供一种分解在生产（甲基）丙烯酸酯的过程中形成的副产物的迈克尔加成反应产物的方法，并回收（甲基）丙烯酸、（甲基）丙烯酸酯和醇，其中可以抑制副产物烯烃的生成。该发明涉及一种在使用具有3个或更多碳原子的支链醇在生产（甲基）丙烯酸酯的过程中热分解副产物的方法，其中分解反应在缺乏催化剂的情况下进行。