1-decyl-3-methyl-1H-imidazol-3-ium iodide | 654077-64-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-decyl-3-methyl-1H-imidazol-3-ium iodide
• 英文别名: decyl-ImI；1-Decyl-3-methylimidazol-3-ium;iodide；1-decyl-3-methylimidazol-3-ium;iodide
• CAS: 654077-64-2
• 化学式: C₁₄H₂₇N₂*I
• 分子量: 350.286
• InChiKey: QPOGOGMIYOLCBD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.46
• 重原子数：
  17
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  8.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-碘全氟癸烷 、 1-decyl-3-methyl-1H-imidazol-3-ium iodide 反应 0.25h， 生成
  参考文献：
  名称：

  基于超分子卤键阴离子的超氟化离子液晶

  摘要：

  报道了非常规离子液晶，其中液晶性是通过卤素键合的超分子阴离子 [C n F 2 n +1 ‐I⋅⋅⋅I⋅⋅⋅I-C n F 2 n +1 ] −实现的。该材料系统在许多方面都是独一无二的，首次证明了1）离子、卤素键合液晶，以及2）咪唑基离子液晶，其中液晶性的发生不是由阳离子的烷基链驱动的。

  DOI：

  10.1002/anie.201601278
• 作为产物：
  描述：

  N-甲基咪唑 、 1-碘癸烷 生成 1-decyl-3-methyl-1H-imidazol-3-ium iodide
  参考文献：
  名称：

  流体镶嵌模型，稳态粘度适应和离子液体：通过旁链不饱和度急剧降低熔点

  摘要：

  违背传统常识：具有长且不饱和烷基附件的离子液体（IL）（参见顶部结构）无视已建立的趋势，这些趋势将长离子束缚的烷基与更高的熔点联系在一起。在相同温度下，新的离子液体的粘度也比饱和标准液（参见底部结构）低。这些特征与某些生物体内顺应性适应的特征平行，并间接支持类似流体马赛克的纳米级特征。

  DOI：

  10.1002/anie.200906169

文献信息

• Method for isolating cells
  申请人：Merck Patent GmbH

  公开号：EP2853587A1

  公开（公告）日：2015-04-01

  The present invention relates to a method and kit for the isolation of cells from a sample. The sample is treated with an extraction solution that comprises at least MgCl2 and/or an ionic liquid resulting in the isolation of preferably viable cells.

  本发明涉及一种从样品中分离细胞的方法和试剂盒。样品用提取液处理，提取液至少包括氯化镁和/或离子液体，从而最好能分离出有活力的细胞。
• Synthesis of a novel alkylimidazolium iodide containing an amide group for electrolyte of dye-sensitized solar cells
  作者：Seung-Hwan Jeon、A.R. Sathiya Priya、Eun-Ji Kang、Kang-Jin Kim

  DOI：10.1016/j.electacta.2010.04.103

  日期：2010.8

  A novel alkylimidazolium iodide containing an amide group, 1-(2-hexanamidoethyl)-3-methylimidazol-3-ium iodide (amido-ImI), was synthesized to act as the quasi-solid-state electrolyte of dye-sensitized solar cells (DSSCs). The DSSC with the amido-ImI electrolyte exhibited short-circuit photocurrent density (J(sc)) and overall energy conversion efficiency (eta) that were improved by 7.2% and 10.2%, respectively, compared to those obtained with the cell containing 1-hexyl-2,3-dimethylimidazolium iodide, a commonly used liquid electrolyte, at 100 mW cm(-2). Furthermore, the stability of the DSSC was enhanced by the presence of amido-ImI. (C) 2010 Elsevier Ltd. All rights reserved.
• METHOD FOR ISOLATING CELLS
  申请人：Merck Patent GmbH

  公开号：EP2443226A1

  公开（公告）日：2012-04-25
• METHOD FOR ISOLATING VIRUSES
  申请人：Merck Patent GmbH

  公开号：EP2467471A2

  公开（公告）日：2012-06-27
• FREESTANDING ION GEL AND METHOD FOR PREPARING THE SAME
  申请人：Research & Business Foundation Sungkyunkwan University

  公开号：US20210054127A1

  公开（公告）日：2021-02-25

  Disclosed is preparation of a freestanding ion gel having high stability and high ionic conductivity based on surface-activity ionic liquids. Further, disclosed is a solid electrolyte using the ion gel. A method for preparing the freestanding ion gel include mixing a surface-activity ionic liquid having an alkyl group having 8 or greater carbon atoms, a crosslinking agent, water and oil with each other to form a bicontinuous microemulsion mixture; ii) adding an initiator to the mixture; and iii) curing the mixture using ultraviolet (UV) or thermal energy to form a freestanding ion gel.