9-(10-Iododecyl)-9H-carbazole | 139377-81-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-(10-Iododecyl)-9H-carbazole
• 英文别名: 9-(10-iododecyl)carbazole
• CAS: 139377-81-4
• 化学式: C₂₂H₂₈IN
• 分子量: 433.376
• InChiKey: IRMIFGNMMOOUHM-UHFFFAOYSA-N

物化性质

• 沸点：
  516.7±32.0 °C(Predicted)
• 密度：
  1.31±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  24
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  9-(10-Iododecyl)-9H-carbazole 、 1-{3-[4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-phenoxy]-propyl}-[4,4']bipyridinyl-1-ium; bromide 以 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Light-induced electron transfer of porphyrin triad for photoelectric conversion

  摘要：

  Two new triad model compounds of porphyrin-viologen-carbazole (1a and 1b) with different chain length were synthesized to mimic photosynthesis. The absorption and fluorescence spectra in solution, in micelle solution as well as in binary solvent, were investigated; especially, the effects of aggregation on the photophysical properties were investigated. A mechanism including photoinduced electron transfer and two-step charge separation was suggested. These triad compounds were easily formed LB films. Rather high photodriven voltages and currents were obtained with only one monolayer of LB film on the surface of SnO2 conductive glass.

  DOI：

  10.1021/j100186a020
• 作为产物：
  描述：

  1,10-二碘癸烷 、 咔唑 在 氢氧化钾 作用下， 以 四氢呋喃 为溶剂， 生成 9-(10-Iododecyl)-9H-carbazole
  参考文献：
  名称：

  Light-induced electron transfer of porphyrin triad for photoelectric conversion

  摘要：

  Two new triad model compounds of porphyrin-viologen-carbazole (1a and 1b) with different chain length were synthesized to mimic photosynthesis. The absorption and fluorescence spectra in solution, in micelle solution as well as in binary solvent, were investigated; especially, the effects of aggregation on the photophysical properties were investigated. A mechanism including photoinduced electron transfer and two-step charge separation was suggested. These triad compounds were easily formed LB films. Rather high photodriven voltages and currents were obtained with only one monolayer of LB film on the surface of SnO2 conductive glass.

  DOI：

  10.1021/j100186a020

文献信息

• Light-induced electron transfer of porphyrin triad for photoelectric conversion
  作者：Xiang Dong Wang、Bao Wen Zhang、Jian Wei Bai、Yi Cao、Xu Rui Xiao、Jing Mei Xu

  DOI：10.1021/j100186a020

  日期：1992.4

  Two new triad model compounds of porphyrin-viologen-carbazole (1a and 1b) with different chain length were synthesized to mimic photosynthesis. The absorption and fluorescence spectra in solution, in micelle solution as well as in binary solvent, were investigated; especially, the effects of aggregation on the photophysical properties were investigated. A mechanism including photoinduced electron transfer and two-step charge separation was suggested. These triad compounds were easily formed LB films. Rather high photodriven voltages and currents were obtained with only one monolayer of LB film on the surface of SnO2 conductive glass.