11,11'-disulfanediyldiundecanoic acid | 29265-73-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 11,11'-disulfanediyldiundecanoic acid
• 英文别名: ω,ω'-Thio-diundecansaeure；Thiodiundecansaeure；10-Carboxydecanyl sulfide；11-(10-carboxydecylsulfanyl)undecanoic acid
• CAS: 29265-73-4
• 化学式: C₂₂H₄₂O₄S
• 分子量: 402.639
• InChiKey: OHJZLOXJZJHLON-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  27
• 可旋转键数：
  22
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  99.9
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  11,11'-disulfanediyldiundecanoic acid 、 3-氨基苯硼酸 在 1-羟基苯并三唑 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 、 N,N-二异丙基乙胺 作用下， 以 四氢呋喃 、 乙腈 为溶剂， 以82%的产率得到(((11,11'-disulfanediylbis(undecanoyl))bis(azanediyl))bis(3,1-phenylene))diboronic acid
  参考文献：
  名称：

  纳米粒子聚集体的动态共价组装和拆卸

  摘要：

  报道了一种新型的动态共价纳米粒子（NP）构建块，它在NP结合的硼酸酯单层中表现出快速的结构适应性，并形成共价连接的NP组装体，尽管它们通过共价键连接，但仍可在其上完全分解化学刺激的应用。

  DOI：

  10.1039/c6cc00135a
• 作为产物：
  描述：

  11-巯基十一烷酸 在 磺酰氯 作用下， 以 二氯甲烷 为溶剂， 反应 0.1h， 以99%的产率得到11,11'-disulfanediyldiundecanoic acid
  参考文献：
  名称：

  纳米粒子聚集体的动态共价组装和拆卸

  摘要：

  报道了一种新型的动态共价纳米粒子（NP）构建块，它在NP结合的硼酸酯单层中表现出快速的结构适应性，并形成共价连接的NP组装体，尽管它们通过共价键连接，但仍可在其上完全分解化学刺激的应用。

  DOI：

  10.1039/c6cc00135a

文献信息

• METHOD AND SYSTEM FOR RAMAN SPECTROSCOPY WITH ARBITRARY SAMPLE CELL
  申请人：MURAKAMI Naoki

  公开号：US20080137081A1

  公开（公告）日：2008-06-12

  In a Raman spectroscopic system: a sample cell in which a sample is filled or through which the sample flows down, where the sample has fluidity and contains one or more materials being to be measured, and having an electrophoretic feature or being conditioned in advance so as to have an electrophoretic feature; a Raman scattering device which has a sample-contact surface, is arranged so that the sample is in contact with the sample-contact surface, and outputs Raman-scattered light when the sample-contact surface is illuminated with measurement light; an optical system which illuminates with the measurement light the sample in contact with the sample-contact surface; a voltage application unit which is provided with the sample cell and applies an electric voltage to the sample so as to bring the one or more materials close to the sample-contact surface by electrophoresis; and a detection unit which detects the Raman-scattered light.
• RAMAN SPECTRUM DETECTING METHOD AND RAMAN SPECTRUM DETECTING DEVICE
  申请人：Tomaru Yuichi

  公开号：US20090273780A1

  公开（公告）日：2009-11-05

  A Raman spectrum detecting method includes a liquid sample contacting step of placing a liquid sample containing a reference substance and a specimen in contact with a detection surface, the reference substance generating a known Raman spectrum having at least one peak therein that is different from peaks in a Raman spectrum generated by the specimen; a scattered light detecting step of irradiating the detection surface in contact with the liquid sample with an excitation light and detecting Raman scattered light occurring from the liquid sample; and a normalizing step of extracting a Raman spectrum signal of the reference substance and a Raman spectrum signal of the specimen from the signal detected in the scattered light detecting step and normalizing a signal intensity of the Raman spectrum signal of the specimen according to an intensity of the Raman spectrum signal of the reference substance.
• Dynamic covalent assembly and disassembly of nanoparticle aggregates
  作者：Stefan Borsley、Euan R. Kay

  DOI：10.1039/c6cc00135a

  日期：——

  A new type of dynamic covalent nanoparticle (NP) building block is reported, exhibiting rapid constitutional adaptation in a NP-bound monolayer of boronate esters, and formation of covalently linked NP assemblies, which despite being connected by covalent bonds, can be fully disassembled on application of a chemical stimulus.

  报道了一种新型的动态共价纳米粒子（NP）构建块，它在NP结合的硼酸酯单层中表现出快速的结构适应性，并形成共价连接的NP组装体，尽管它们通过共价键连接，但仍可在其上完全分解化学刺激的应用。

表征谱图