diethyl 4-methyl-1,3-cyclohexanedicarboxylate | 96259-66-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: diethyl 4-methyl-1,3-cyclohexanedicarboxylate
• 英文别名: Diethyl 4-methylcyclohexane-1,3-dicarboxylate
• CAS: 96259-66-4
• 化学式: C₁₃H₂₂O₄
• 分子量: 242.315
• InChiKey: KSQFHGPSTUQPGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4-甲基-异酞腈 在 Rh on carbon sodium hydroxide 、 硫酸 、 水 、 氢气 作用下， 以 甲醇 、 溶剂黄146 、 二乙二醇 为溶剂， 反应 32.0h， 生成 diethyl 4-methyl-1,3-cyclohexanedicarboxylate
  参考文献：
  名称：

  Substituent effects on hydrogenation of aromatic rings: hydrogenation vs. hydrogenolysis in cyclic analogs of benzyl ethers

  摘要：

  DOI：

  10.1021/jo00212a025

文献信息

• SOLID TITANIUM CATALYST COMPONENT, CATALYST FOR OLEFIN POLYMERIZATION, AND PROCESS FOR PRODUCING OLEFIN POLYMER
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1845113A1

  公开（公告）日：2007-10-17

  A solid titanium catalyst component (I) of the present invention is characterized in that it contains titanium, magnesium, halogen, and a cyclic ester compound (a) represented by the following formula (1) : wherein n is an integer of 5 to 10; R2 and R3 are each independently COOR1 or R, and at least one of R2 and R3 is COOR1; a single bond (excluding Ca-Ca bonds, and a Ca-Cb bond in the case where R3 is R) in the cyclic backbone may be replaced with a double bond; a plurality of R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms; and a plurality of R' s are each independently a hydrogen atom or a substituent, but at least one of R's is not a hydrogen atom. When using this solid titanium catalyst component (I), an olefin polymer having a broad molecular weight distribution can be produced.

  本发明的固体钛催化剂组分（I）的特征在于它含有钛、镁、卤素和由下式（1）表示的环酯化合物（a）： 其中 n 为 5 至 10 的整数； R2 和 R3 各自独立地为 COOR1 或 R，且 R2 和 R3 中至少有一个为 COOR1； 环状骨架中的单键（不包括 Ca-Ca 键，在 R3 为 R 的情况下为 Ca-Cb 键）可被双键取代； 多个 R1 分别独立地为具有 1 至 20 个碳原子的单价烃基；以及 多个 R'各自独立地为氢原子或取代基，但至少有一个 R'不是氢原子。使用这种固体钛催化剂组分 (I)，可以生产出具有宽分子量分布的烯烃聚合物。
• SOLID TITANIUM CATALYST INGREDIENT, CATALYST FOR OLEFIN POLYMERIZATION, AND METHOD OF POLYMERIZING OLEFIN
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2221320A1

  公开（公告）日：2010-08-25

  A solid titanium catalyst component (I) comprising titanium, magnesium, halogen, a specific cyclic ester compound (a) and a specific cyclic ester compound (b), an olefin polymerization catalyst containing this catalyst component (I), and an olefin polymerization process using this olefin polymerization catalyst are disclosed. According to the solid titanium catalyst component, the olefin polymerization catalyst and the process for preparing an olefin polymer of the invention, an olefin polymer having high stereoregularity and a wide molecular weight distribution can be prepared with high activity, preparation of an olefin polymer excellent not only in molding properties such as high-speed streatchability and high-speed moldability but also in rigidity becomes possible, and besides, production cost can be reduced.

  本发明公开了一种由钛、镁、卤素、特定环酯化合物（a）和特定环酯化合物（b）组成的固体钛催化剂组分（I）、一种含有该催化剂组分（I）的烯烃聚合催化剂以及一种使用该烯烃聚合催化剂的烯烃聚合工艺。根据本发明的固体钛催化剂组分、烯烃聚合催化剂和烯烃聚合物的制备工艺，可以制备出具有高立体规整度和宽分子量分布的高活性烯烃聚合物，不仅可以制备出具有优异成型性能（如高速吸附性和高速成型性）的烯烃聚合物，而且还可以制备出具有优异刚性的烯烃聚合物，此外，还可以降低生产成本。
• SOLID TITANIUM CATALYST COMPONENT FOR ETHYLENE POLYMERIZATION, ETHYLENE POLYMERIZATION CATALYST AND ETHYLENE POLYMERIZATION METHOD
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2264075A1

  公开（公告）日：2010-12-22

  Provided are a solid titanium catalyst component for ethylene polymerization which can polymerize ethylene at a high activity and which can provide an ethylene polymer having an excellent particle property, an ethylene polymerization catalyst and an ethylene polymerization method in which the catalyst is used. The solid titanium catalyst component (I) for ethylene polymerization according to the present invention is obtained by bringing a liquid magnesium compound (A) including a magnesium compound, an electron donor (a) having 1 to 5 carbon atoms and an electron donor (b) having 6 to 30 carbon atoms into contact with a liquid titanium compound (C) under the presence of an electron donor (B) and includes titanium, magnesium and a halogen. The ethylene polymerization catalyst of the present invention includes the component (I) and an organic metal compound catalyst component (II). Further, the ethylene polymerization method of the present invention is a method for polymerizing ethylene under the presence of the catalyst.

  本发明提供了一种乙烯聚合用固体钛催化剂组分、乙烯聚合催化剂和使用该催化剂的乙烯聚合方法，该乙烯聚合用固体钛催化剂组分能以高活性聚合乙烯，并能提供具有优异颗粒性能的乙烯聚合物。 根据本发明的乙烯聚合用固体钛催化剂组分（I）是在电子供体（B）存在的情况下，将包括镁化合物、具有 1 至 5 个碳原子的电子供体（a）和具有 6 至 30 个碳原子的电子供体（b）的液态镁化合物（A）与液态钛化合物（C）接触而得到的，液态钛化合物（C）包括钛、镁和卤素。本发明的乙烯聚合催化剂包括组分（I）和有机金属化合物催化剂组分（II）。此外，本发明的乙烯聚合方法是一种在催化剂存在下聚合乙烯的方法。
• PROPYLENE-BASED BLOCK COPOLYMER AND COMPOSITION CONTAINING SAID COPOLYMER, AND MOLDED BODY OBTAINED THEREFROM
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2330139A1

  公开（公告）日：2011-06-08

  To provide a propylene-based block copolymer which has high melt viscoelasticity, excellent balance between rigidity and impact resistance and goodmoldingprocessablility and is extremely excellent in its molded product appearance, a composition containing the copolymer and molded products obtained therefrom. The propylene-based block copolymer comprises 5 to 80% by weight of a room temperature n-decane-soluble portion (Dsol) and 20 to 95% by weight of a room temperature n-decane-insoluble portion (Dinsol), with the proviso that the total amount of the Dsol and the Dinsol is 100% by weight, and satisfies the following requirements [1] to [3] at the same time: [1] the molecular weight distribution (Mw/Mn) of the Dsol is not less than 7. 0 but not more than 30, [2] the molecular weight distribution (Mw/Mn) of the Dinsol is not less than 7.0 but not more than 30, and Mz/Mw thereof is not less than 6.0 but not more than 20, and [3] the pentad fraction (mmmm) of the Dinsol is not less than 93%.

  提供一种丙烯基嵌段共聚物，它具有较高的熔体粘弹性，在刚性和抗冲击性之间具有极佳的平衡，具有良好的模塑加工性，并且在模塑产品外观方面极为出色，还提供一种含有该共聚物的组合物以及由此获得的模塑产品。丙烯基嵌段共聚物包括 5%至 80%（按重量计）的室温正癸烷可溶部分（Dsol）和 20%至 95%（按重量计）的室温正癸烷不溶部分（Dinsol），但条件是 Dsol 和 Dinsol 的总量为 100%（按重量计），并同时满足以下要求[1]至[3]：[1] Dsol 的分子量分布（Mw/Mn）不小于 7.0 但不大于 30，[2] Dinsol 的分子量分布（Mw/Mn）不小于 7.0 但不大于 30，其 Mz/Mw 不小于 6.0 但不大于 20，[3] Dinsol 的 pentad 分数（mmm）不小于 93%。
• Non-phthalate catalyst system and its use in the polymerization of olefins
  申请人：BRASKEM AMERICA, INC.

  公开号：US10633464B2

  公开（公告）日：2020-04-28

  This invention relates to a non-phthalate catalyst system for olefin polymerization. The non-phthalate catalyst system comprises (a) a solid Ziegler-Natta catalyst composition comprising a transition metal, a Group 2 metal, and one or more halogens; and one or more internal electron donor compounds; and (b) one or more external electron donor compounds.

  本发明涉及一种用于烯烃聚合的非邻苯二甲酸酯催化剂体系。该非邻苯二甲酸酯催化剂体系包括：(a) 一种固体齐格勒-纳塔催化剂组合物，该组合物包括过渡金属、第 2 族金属和一种或多种卤素；以及一种或多种内部电子供体化合物；和 (b) 一种或多种外部电子供体化合物。