2-phenylethyl β-D-galactofuranoside | 1327183-64-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-phenylethyl β-D-galactofuranoside
• 英文别名: (2S,3R,4R,5R)-2-[(1R)-1,2-dihydroxyethyl]-5-(2-phenylethoxy)oxolane-3,4-diol
• CAS: 1327183-64-1
• 化学式: C₁₄H₂₀O₆
• 分子量: 284.309
• InChiKey: USPGWXPMZDIEKE-XGFWRYKXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.1
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  99.4
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  D-吡喃葡萄糖 、 苯乙醇 在 iron(III) chloride 作用下， 60.0~70.0 ℃ 、1.0 MPa 条件下， 反应 1.08h， 生成 2-phenylethyl α-D-galactofuranoside 、 2-phenylethyl β-D-galactofuranoside 、 (2R,3R,4S,5R,6S)-2-(hydroxymethyl)-6-(2-phenylethoxy)oxane-3,4,5-triol 、 苯基乙基 beta-D-吡喃半乳糖苷
  参考文献：
  名称：

  Kinetic Products Under Thermal Conditions: Rapid Entry into α/β-D-Galactofuranosides Using Microwave Irradiation and Selective Lewis Acids

  摘要：

  A modified Fischer-Lubineau reaction, employing microwave irradiation and selected Lewis acids such as Mn(ClO4)(2), Mn(C2H3O2)(3), FeCl3, CoCl2, and AgF as independent additives, induces rapid entry into alpha/beta-D-galactofuranosides in very good yield and purity.

  DOI：

  10.1080/07328303.2011.585259

文献信息

• Kinetic Products Under Thermal Conditions: Rapid Entry into α/β-D-Galactofuranosides Using Microwave Irradiation and Selective Lewis Acids
  作者：Soumava Santra、Emily Jonas、Jean-Paul Bourgault、Tarick El-Baba、Peter R. Andreana

  DOI：10.1080/07328303.2011.585259

  日期：2011.1.1

  A modified Fischer-Lubineau reaction, employing microwave irradiation and selected Lewis acids such as Mn(ClO4)(2), Mn(C2H3O2)(3), FeCl3, CoCl2, and AgF as independent additives, induces rapid entry into alpha/beta-D-galactofuranosides in very good yield and purity.