4-(1-benzotriazolyl)-5-(2-naphthyloxy)phthalodinitrile | 697239-03-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-(1-benzotriazolyl)-5-(2-naphthyloxy)phthalodinitrile
• 英文别名: 4-(1-benzotriazolyl)-5-(2-naphthoxy)phthalodinitrile；4-(1-benzotriazolyl)-5-(2-naphthoxy)phthalonitrile；4-(1H-1,2,3-benzotriazol-1-yl)-5-(2-naphthyloxy)phthalonitrile；4-(benzotriazol-1-yl)-5-naphthalen-2-yloxybenzene-1,2-dicarbonitrile
• CAS: 697239-03-5
• 化学式: C₂₄H₁₃N₅O
• 分子量: 387.4
• InChiKey: XLTNAIOXUGRQAI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  30
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  87.5
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4-(1-benzotriazolyl)-5-(2-naphthyloxy)phthalodinitrile 在 尿素 作用下， 反应 2.0h， 生成
  参考文献：
  名称：

  Stability of benzotriazolyl-substituted phthalocyanines with respect to thermal oxidative decomposition

  摘要：

  The thermal oxidative decomposition of benzotriazolyl-substituted phthalocyanines and their copper complexes is investigated by means of thermogravimetric, elemental, and spectroscopic analysis. It is shown that the nature of peripheral substituents exerts the greatest effect on the thermal stability of the compounds.

  DOI：

  10.1134/s0036024413030345

文献信息

• Nucleophilic substitution in 4-bromo-5-nitrophthalodinitrile: X. Synthesis of 4-(1-benzotriazolyl)-5-(1(2)-naphthyloxy)-phthalodinitriles and related phthalocyanines
  作者：S. A. Znoiko、A. S. Kambolova、V. E. Maizlish、G. P. Shaposhnikov、I. G. Abramov、S. I. Filimonov

  DOI：10.1134/s107036320908026x

  日期：2009.8

  4-(1-Benzotriazolyl)-5-[1(2)-naphthyloxy]phthalodinitriles were obtained by nucleophilic substitution of bromine and nitro group in 4-bromo-5-nitrophthalodinitrile. These compounds were used for the synthesis of the corresponding octa-substituted phthalocyanines. Spectral data of the compounds obtained were examined.

  通过亲核取代4-溴-5-硝基邻苯二甲腈中的溴和硝基，得到4-（1-苯并三唑基）-5- [1（2）-萘氧基]邻苯二腈。这些化合物用于合成相应的八取代的酞菁。检查获得的化合物的光谱数据。
• Synthesis of lanthanide complexes of phthalocyanines containing both naphthoxy and benzotriazole fragments
  作者：S. A. Znoiko、O. N. Zubkova、A. V. Borisov、V. E. Maizlish、G. P. Shaposhnikov

  DOI：10.1134/s1070363215110225

  日期：2015.11

  Interaction of 4-(1-benzotriazolyl)-5-(2-naphthoxy)phthalonitrile with erbium or ytterbium chloride has afforded the lanthanide complexes of tetra-4-(1-benzotriazolyl)tetra-5-(2-naphthoxy)phthalocyanine. Fusion of erbium tetra-4-(1-benzotriazolyl)tetra-5-(2-naphthoxy)phthalocyaninate with phthalonitrile has yielded the corresponding sandwich-type heteroligand complex. The prepared compounds have been characterized by data of elemental analysis as well as IR and electronic spectroscopy; their thermal stability has been studied.
• Thermogravimetric and spectral studies of the reaction between benzotriazolyl derivatives of phthalodinitriles and copper(II) acetate
  作者：N. A. Pavlycheva、N. Sh. Lebedeva、A. I. V’yugin、V. E. Maizlish、G. P. Shaposhnikov、S. A. Znoiko、I. G. Abramov、M. B. Abramova

  DOI：10.1134/s0036024408110101

  日期：2008.11

  The interaction of benzotriazolyl derivatives of phthalodinitriles with copper(II) acetate was studied thermogravimetrically and spectroscopically. Electron acceptor properties of peripheral substituents had a predominant influence on the enthalpy parameter of formation of copper(II)phthalocyanines.
• Studying the Thermo-Oxidative Destruction of Phthalocyanines Combining Fragments of Naphtholes, 1-Benzotriazole, and Sulfo Groups
  作者：S. A. Znoiko、V. E. Maizlish、T. V. Kustova、N. Sh. Lebedeva

  DOI：10.1134/s0036024422040355

  日期：2022.4