7-ethenylhexahydro-2H-azepin-2-one | 253139-14-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酰胺类
• 英文名称: 7-ethenylhexahydro-2H-azepin-2-one
• 英文别名: epsilon-Vinylcaprolactam；7-ethenylazepan-2-one
• CAS: 253139-14-9
• 化学式: C₈H₁₃NO
• mdl: MFCD19226884
• 分子量: 139.197
• InChiKey: YRTUVZSVKOTZHX-UHFFFAOYSA-N

物化性质

• 沸点：
  280.0±29.0 °C(Predicted)
• 密度：
  1.011±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.625
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  7-ethenylhexahydro-2H-azepin-2-one 、 邻溴苯甲酸甲酯 以 palladium acetate, tri-o-tolylphosphine 、 乙腈 为溶剂， 生成 methyl 2-[2-(hexahydro-2-oxo-1H-azepin-3-yl)ethenyl]benzoate
  参考文献：
  名称：

  Cyclic amidino agents useful as nitric oxide synthase inhibitors

  摘要：

  当前的发明揭示了作为一氧化氮合酶抑制剂有用的胍基衍生物。

  公开号：

  US06011028A1
• 作为产物：
  描述：

  2-亚乙基环己酮 在 sodium hydroxide 、 苯磺酰氯 作用下， 以 丙酮 为溶剂， 生成 7-ethenylhexahydro-2H-azepin-2-one
  参考文献：
  名称：

  Cyclic amidino agents useful as nitric oxide synthase inhibitors

  摘要：

  当前的发明揭示了作为一氧化氮合酶抑制剂有用的胍基衍生物。

  公开号：

  US06011028A1

文献信息

• CYCLIC AMIDINO AGENTS USEFUL AS NITRIC OXIDE SYNTHASE INHIBITORS
  申请人：G.D. SEARLE & CO.

  公开号：EP0821674A1

  公开（公告）日：1998-02-04
• METHODS OF PREPARING NEW IDH1 INHIBITORS
  申请人：Les Laboratoires Servier SAS

  公开号：EP3447052B1

  公开（公告）日：2021-10-20
• ULTRAVIOLET CURABLE TYPE INK-JET INK COMPOSITION, RECORDING METHOD AND RECORDING APPARATUS USISNG SAME
  申请人：KAGOSE Taketoshi

  公开号：US20120113201A1

  公开（公告）日：2012-05-10

  Provided is a UV curable type ink-jet ink composition containing a monomer A which is expressed by the following general formula (I): CH 2 ═CR 1 —COOR 2 —O—CH═CH—R 3 (I) (in the formula, R 1 is a hydrogen atom or methyl radical, R 2 is a bivalent organic residue radical having a carbon number in a range of 2 to 20, and R 3 is a hydrogen atom or a univalent organic residue radical having a carbon number in a range of 1 to 11), a compound B containing five or more (meth)acryloyl radicals per molecule, and a monofunctional (meth)acrylate C having an aromatic ring skeleton, wherein the monofunctional (meth)acrylate C which is in a range of 5 to 35 wt % with respect to the total weight of the ink composition is contained.
• ULTRAVIOLET CURABLE TYPE INK-JET INK COMPOSITION, RECORDING METHOD AND RECORDING APPARATUS USING THE SAME
  申请人：Seiko Epson Corporation

  公开号：US20150240094A1

  公开（公告）日：2015-08-27

  Provided is a UV curable type ink-jet ink composition containing a monomer A which is expressed by the following general formula (I): CH 2 ═CR 1 —COOR 2 —O—CH═CH—R 3 (I) (in the formula, R 1 is a hydrogen atom or methyl radical, R 2 is a bivalent organic residue radical having a carbon number in a range of 2 to 20, and R 3 is a hydrogen atom or a univalent organic residue radical having a carbon number in a range of 1 to 11), a compound B containing five or more (meth)acryloyl radicals per molecule, and a monofunctional (meth)acrylate C having an aromatic ring skeleton, wherein the monofunctional (meth)acrylate C which is in a range of 5 to 35 wt % with respect to the total weight of the ink composition is contained.
• US5883251A
  申请人：——

  公开号：US5883251A

  公开（公告）日：1999-03-16