3-Bromo-10-[3-(6-bromophenanthren-9-yl)propyl]phenanthrene | 862305-65-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 3-Bromo-10-[3-(6-bromophenanthren-9-yl)propyl]phenanthrene
• 英文别名: 3-bromo-10-[3-(6-bromophenanthren-9-yl)propyl]phenanthrene
• CAS: 862305-65-5
• 化学式: C₃₁H₂₂Br₂
• 分子量: 554.324
• InChiKey: UBIXDRIDWDJLHU-UHFFFAOYSA-N

物化性质

• 沸点：
  691.5±35.0 °C(Predicted)
• 密度：
  1.505±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  11.1
• 重原子数：
  33
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3-Bromo-10-[3-(6-bromophenanthren-9-yl)propyl]phenanthrene 在 sodium tetrahydroborate 、 正丁基锂 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 生成 {10-[3-(6-Hydroxymethyl-phenanthren-9-yl)-propyl]-phenanthren-3-yl}-methanol
  参考文献：
  名称：

  Synthesis and Fluorescence Spectra of Oxa[3.n]phenanthrenophanes

  摘要：

  Novel photostable oxa[3.n](3,9)- and (3.3](3,10)phenanthrenophanes (n = 3, 4) bearing trimethylene-type linkage(s) were successfully synthesized by the intramolecular acid-catalyzed etherification of the corresponding precursor diols. syn-Oxa[3.3](3,10)phenanthrenophane afforded the most red-shifted excimer fluorescence (lambda(max) = 432 nm) among the phenanthrenophanes so far prepared.

  DOI：

  10.1021/ol051047y
• 作为产物：
  描述：

  1-bromo-4-[6-(4-bromophenyl)-1,7-diphenylhepta-1,6-dien-2-yl]benzene 在 碘 、 methyloxirane 作用下， 以 甲苯 为溶剂， 以50%的产率得到3-Bromo-10-[3-(6-bromophenanthren-9-yl)propyl]phenanthrene
  参考文献：
  名称：

  Synthesis and Fluorescence Spectra of Oxa[3.n]phenanthrenophanes

  摘要：

  Novel photostable oxa[3.n](3,9)- and (3.3](3,10)phenanthrenophanes (n = 3, 4) bearing trimethylene-type linkage(s) were successfully synthesized by the intramolecular acid-catalyzed etherification of the corresponding precursor diols. syn-Oxa[3.3](3,10)phenanthrenophane afforded the most red-shifted excimer fluorescence (lambda(max) = 432 nm) among the phenanthrenophanes so far prepared.

  DOI：

  10.1021/ol051047y

文献信息

• Synthesis and Fluorescence Spectra of Oxa[3.<i>n</i>]phenanthrenophanes
  作者：Yosuke Nakamura、Takuzo Yamazaki、Jun Nishimura

  DOI：10.1021/ol051047y

  日期：2005.7.1

  Novel photostable oxa[3.n](3,9)- and (3.3](3,10)phenanthrenophanes (n = 3, 4) bearing trimethylene-type linkage(s) were successfully synthesized by the intramolecular acid-catalyzed etherification of the corresponding precursor diols. syn-Oxa[3.3](3,10)phenanthrenophane afforded the most red-shifted excimer fluorescence (lambda(max) = 432 nm) among the phenanthrenophanes so far prepared.