11-azidoundecyltrimethallylsilane | 928139-84-8

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: 11-azidoundecyltrimethallylsilane
• 英文别名: 11-azidoundecyl-trimethallyl-silane；11-Azidoundecyl-trimethallyl-silane；11-azidoundecyl-tris(2-methylprop-2-enyl)silane
• CAS: 928139-84-8
• 化学式: C₂₃H₄₃N₃Si
• 分子量: 389.7
• InChiKey: OLHXIQHDTZBVRD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.98
• 重原子数：
  27
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.74
• 拓扑面积：
  14.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  11-azidoundecyltrimethallylsilane 在 水 、 三苯基膦 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以68%的产率得到11-aminoundecyltrimethallylsilane
  参考文献：
  名称：

  A one-step co-condensation method for the synthesis of well-defined functionalized mesoporous SBA-15 using trimethallylsilanes as organosilane sources

  摘要：

  使用功能化基团浸渍的三甲基烯基硅烷，通过一步共聚合方法合成了具有良好定义的介孔SBA-15。

  DOI：

  10.1039/c5cc07286g
• 作为产物：
  描述：

  11-氯十一烷基三氯硅烷 在 sodium azide 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 反应 5.0h， 生成 11-azidoundecyltrimethallylsilane
  参考文献：
  名称：

  A one-step co-condensation method for the synthesis of well-defined functionalized mesoporous SBA-15 using trimethallylsilanes as organosilane sources

  摘要：

  使用功能化基团浸渍的三甲基烯基硅烷，通过一步共聚合方法合成了具有良好定义的介孔SBA-15。

  DOI：

  10.1039/c5cc07286g

文献信息

• Surface Modified Inorganic Material and Producing Method Thereof
  申请人：Jun Chul-Ho

  公开号：US20090270590A1

  公开（公告）日：2009-10-29

  A surface-modified inorganic material and a preparation method thereof. A surface-modified inorganic material is provided which is obtained by allowing an organosilane compound having allyl or an allyl derivative to react with an inorganic material, particularly solid silica or ITO glass, in the presence of an acid and an organic solvent, to introduce an organic group into the inorganic material even at room temperature, as well as a preparation method thereof. The invention can effectively introduce the organic group into the inorganic material even at room temperature, and thus is very effective in introducing compounds having a thermally sensitive functional group, for example, natural compounds or proteins. It is possible to introduce various organic groups into an inorganic material and to separate and purify organic molecule-bonded organosilane compounds using a silica gel column to effectively bond them to inorganic materials. Accordingly, the invention is very useful in the chemical industry.

  一种表面改性的无机材料及其制备方法。提供了一种表面改性的无机材料，通过在酸和有机溶剂存在下，使具有烯丙基或烯丙基衍生物的有机硅烷化合物与无机材料，特别是固体二氧化硅或ITO玻璃反应，将有机基引入无机材料，即使在室温下也能实现，并提供了其制备方法。该发明可以有效地在室温下将有机基引入无机材料，因此在引入具有热敏感功能基团的化合物，例如天然化合物或蛋白质时非常有效。可以将各种有机基引入无机材料，并使用硅胶柱分离和纯化有机分子结合的有机硅烷化合物，有效地将它们与无机材料结合。因此，该发明在化工行业中非常有用。
• SURFACE MODIFIED INORGANIC MATERIAL AND PRODUCING METHOD THEREOF
  申请人：Jun Chul-Ho

  公开号：US20130060014A1

  公开（公告）日：2013-03-07

  A surface-modified inorganic material and a preparation method thereof. A surface-modified inorganic material is provided which is obtained by allowing an organosilane compound having allyl or an allyl derivative to react with an inorganic material, particularly solid silica or ITO glass, in the presence of an acid and an organic solvent, to introduce an organic group into the inorganic material even at room temperature, as well as a preparation method thereof. The invention can effectively introduce the organic group into the inorganic material even at room temperature, and thus is very effective in introducing compounds having a thermally sensitive functional group, for example, natural compounds or proteins. It is possible to introduce various organic groups into an inorganic material and to separate and purify organic molecule-bonded organosilane compounds using a silica gel column to effectively bond them to inorganic materials.

  提供了一种表面改性的无机材料及其制备方法。通过在酸和有机溶剂的存在下，使具有烯丙基或烯丙基衍生物的有机硅化合物与无机材料，特别是固体二氧化硅或ITO玻璃反应，即使在室温下也能将有机基团引入无机材料中，从而得到表面改性的无机材料及其制备方法。该发明能够有效地将有机基团引入无机材料中，即使在室温下也能实现，因此非常适合引入具有热敏功能基团的化合物，例如天然化合物或蛋白质。可以将各种有机基团引入无机材料中，并使用硅胶柱分离和纯化有机分子-键合的有机硅化合物，以有效地将它们键合到无机材料上。
• A one-step co-condensation method for the synthesis of well-defined functionalized mesoporous SBA-15 using trimethallylsilanes as organosilane sources
  作者：Ye Ri Han、Jung-Woo Park、Hanil Kim、Hyejeong Ji、Soo Hyun Lim、Chul-Ho Jun

  DOI：10.1039/c5cc07286g

  日期：——

  Well-defined functionalized mesoporous SBA-15s are synthesized by a one-step co-condensation method using functional group-impregnated trimethallylsilanes.

  使用功能化基团浸渍的三甲基烯基硅烷，通过一步共聚合方法合成了具有良好定义的介孔SBA-15。