4-(1-naphthoxy)phthalonitrile | 201480-82-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-(1-naphthoxy)phthalonitrile
• 英文别名: 4-(Naphthalen-1-yloxy)benzene-1,2-dicarbonitrile；4-naphthalen-1-yloxybenzene-1,2-dicarbonitrile
• CAS: 201480-82-2
• 化学式: C₁₈H₁₀N₂O
• 分子量: 270.29
• InChiKey: HUMVKJZWSRDQHZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  56.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-(1-naphthoxy)phthalonitrile 、 zinc diacetate 在 1,8-diazabicyclo-[5,4,0]-undecane 作用下， 以 further solvent(s) 为溶剂， 以21%的产率得到2,9,16,23-tetrakis(1-napthoxy)-phthalocyaninatozinc(II)
  参考文献：
  名称：

  带有四个萘氧基侧基取代基的无金属和金属酞菁的合成与表征

  摘要：

  摘要通过4-（1-萘氧基）邻苯二甲腈和4-（2-萘氧基）邻苯二甲腈的环四聚反应制备了具有四个萘氧基侧基的酞菁。这些新化合物的特征在于元素分析，1 H NMR，IR和UV-Vis光谱数据。电子光谱表现出强烈的萘身份的π→π*跃迁以及酞菁核的特征性Q和B谱带。

  DOI：

  10.1016/j.poly.2003.12.003

文献信息

• RESIN BLENDS CONTAINING A PHTHALONITRILE REACTIVE DILUENT AND A DIPHTHALONITRILE RESIN, PREPREGS, AND ARTICLES
  申请人：3M Innovative Properties Company

  公开号：EP3601215A1

  公开（公告）日：2020-02-05
• US5247060A
  申请人：——

  公开号：US5247060A

  公开（公告）日：1993-09-21
• [EN] RESIN BLENDS CONTAINING A PHTHALONITRILE REACTIVE DILUENT AND A DIPHTHALONITRILE RESIN, PREPREGS, AND ARTICLES<br/>[FR] MÉLANGES DE RÉSINES CONTENANT UN DILUANT RÉACTIF DE PHTALONITRILE ET UNE RÉSINE DE DIPHTALONITRILE, PRÉIMPRÉGNÉS ET ARTICLES
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2018175025A1

  公开（公告）日：2018-09-27

  The present disclosure provides a resin blend. The resin blend includes at least one diluent containing a single phthalonitrile functional group and at least one diphthalonitrile resin. Also provided are prepregs including the resin blend impregnated into continuous reinforcing fibers or a cloth. Similarly, the present disclosure provides a molding compound including chopped reinforcing fibers distributed in the resin blend. An article is also provided, which includes polymerization product of the resin blend. An alternative article includes a substrate and a layer of the resin blend disposed on the substrate. The diluent typically improves processability of the resin blend and lowers the softening temperature of the polymerization product of the resin blend.
• Synthesis and characterization of metal-free and metallo phthalocyanines with four pendant naphthoxy-substituents
  作者：H Yasemin Yenilmez、İbrahim Özçeşmeci、Ali İhsan Okur、Ahmet Gül

  DOI：10.1016/j.poly.2003.12.003

  日期：2004.3

  Abstract Phthalocyanines with four naphthoxy pendant groups on the periphery were prepared by cyclotetramerization of 4-(1-naphthoxy)phthalonitrile and 4-(2-naphthoxy)phthalonitrile. The new compounds were characterized by elemental analyses, 1 H NMR, IR and UV–Vis spectral data. The electronic spectra exhibit an intense π→π * transition of naphthyl identity together with characteristic Q and B bands

  摘要通过4-（1-萘氧基）邻苯二甲腈和4-（2-萘氧基）邻苯二甲腈的环四聚反应制备了具有四个萘氧基侧基的酞菁。这些新化合物的特征在于元素分析，1 H NMR，IR和UV-Vis光谱数据。电子光谱表现出强烈的萘身份的π→π*跃迁以及酞菁核的特征性Q和B谱带。