perylene tetracarboxylic acid bis{di-(1,1,1,3,3,5,5-heptamethyl trisiloxanyl butyl)-methylimide} | 1395396-41-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: perylene tetracarboxylic acid bis{di-(1,1,1,3,3,5,5-heptamethyl trisiloxanyl butyl)-methylimide}
• 英文别名: N,N'-di(1,9-di(1,1,1-3,3-5,5-trisiloxanyl)nonane-5-yl)perylene-3,4:9,10-tetracarboxylic acid bisimide；PTCBI；7,18-Bis[1,9-bis[[dimethyl(trimethylsilyloxy)silyl]oxy-dimethylsilyl]nonan-5-yl]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone；7,18-bis[1,9-bis[[dimethyl(trimethylsilyloxy)silyl]oxy-dimethylsilyl]nonan-5-yl]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• CAS: 1395396-41-4
• 化学式: C₇₀H₁₂₆N₂O₁₂Si₁₂
• 分子量: 1524.8
• InChiKey: OTZJCQXXHYIEFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  21.45
• 重原子数：
  96
• 可旋转键数：
  38
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.66
• 拓扑面积：
  149
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  1,1,1,3,3,5,5-七甲基三硅氧烷 、 N,N'-di(1,8-nonadien-5-yl)-perylene-3,4,9,10-tetracarboxylic bisimide 在 铂(0)-1,3-二乙烯-1,1,3,3-四甲基二硅氧烷 作用下， 以 5,5-dimethyl-1,3-cyclohexadiene 、 甲苯 为溶剂， 生成 perylene tetracarboxylic acid bis{di-(1,1,1,3,3,5,5-heptamethyl trisiloxanyl butyl)-methylimide}
  参考文献：
  名称：

  A liquid-crystalline perylene tetracarboxylic bisimide derivative bearing trisiloxan-2-yl moieties: influence on mesomorphic properties and electron transport

  摘要：

  液晶苯并四酰亚胺衍生物的介质和电子输运性质进行了比较，其中包含线性二硅氧烷和三硅氧烷链，以及三硅氧烷-2-基团。

  DOI：

  10.1039/c5ra23119a

文献信息

• High electron mobility in a columnar phase of liquid-crystalline perylene tetracarboxylic bisimide bearing oligosiloxane chains
  作者：Masahiro Funahashi、Akinari Sonoda

  DOI：10.1039/c2jm35579e

  日期：——

  A liquid-crystalline (LC) semiconductor based on perylene tetracarboxylic bisimide (PTCBI) bearing four 1,1,1,3,3-pentamethyldisiloxane chains was synthesized. This LC PTCBI derivative exhibits ordered columnar phases and the low temperature columnar phase is retained below room temperature. The electron mobility in the ordered columnar phase of this compound at room temperature exceeds 0.1 cm2 V−1 s−1. Moreover, this compound is soluble in various organic solvents, except alcohols, and thin films in which the columnar aggregates are aligned parallel to the substrates are produced by spin-coating. In particular, LC thin films in which the columnar stacks are uniaxially oriented can be produced by a friction transfer method.

  我们合成了一种基于带有四条 1,1,1,3,3 五甲基二硅氧烷链的过四甲酰二亚胺（PTCBI）的液晶半导体。这种 LC PTCBI 衍生物显示出有序的柱状相，而且低温柱状相在室温以下仍保持不变。在室温下，该化合物有序柱状相中的电子迁移率超过 0.1 cm2 V-1 s-1。此外，这种化合物还可溶于除乙醇以外的各种有机溶剂中，并可通过旋涂法制备出柱状聚集体与基底平行排列的薄膜。特别是，柱状堆积物呈单轴定向的 LC 薄膜可通过摩擦转移法生产。
• Liquid–crystalline perylene tetracarboxylic acid bisimide bearing oligosiloxane chains with high electron mobility and solubility
  作者：Masahiro Funahashi、Akinari Sonoda

  DOI：10.1016/j.orgel.2012.05.027

  日期：2012.9

  Liquid-crystalline perylene tetracarboxylic acid bisimide derivatives 1 and 2 bearing 1,1,1,2,2,3,3-heptamethyltrisiloxane chains at the end of alkyl side-chains have been synthesized. Compound 1 having four trisiloxane chains exhibits a hexagonal columnar phase at room temperature. Time-of-flight measurement reveals that the electron mobility in the columnar phase of compound 1 exceeds 10 (3) cm(2) V (1) s (1) at room temperature. In contrast, compound 2 bearing two trisiloxane chains is not mesomorphic. These two compounds are soluble in various organic solvents except for alcohols and thin films can be produced by a spin-coating method. (C) 2012 Elsevier B. V. All rights reserved.
• PERYLENE TETRACARBOXYLIC ACID BISIMIDE DERIVATIVE, n-TYPE SEMICONDUCTOR, PROCESS FOR PRODUCING n-TYPE SEMICONDUCTOR, AND ELECTRONIC DEVICE
  申请人：National University Corporation Kagawa University

  公开号：EP2695885B1

  公开（公告）日：2017-02-22
• A liquid-crystalline perylene tetracarboxylic bisimide derivative bearing trisiloxan-2-yl moieties: influence on mesomorphic properties and electron transport
  作者：Masahiro Funahashi、Nozomi Takeuchi、Akinari Sonoda

  DOI：10.1039/c5ra23119a

  日期：——

  Mesomorphic and electron transport properties are compared for liquid-crystalline perylene tetracarboxylic bisimide derivatives bearing linear disiloxane and trisiloxane chains, as well as trisiloxan-2-yl groups.

  液晶苯并四酰亚胺衍生物的介质和电子输运性质进行了比较，其中包含线性二硅氧烷和三硅氧烷链，以及三硅氧烷-2-基团。