3,3,6,6,9,9-六甲基-1,2,4,5-四氧杂环壬烷 | 22397-33-7

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 中文名称: 3,3,6,6,9,9-六甲基-1,2,4,5-四氧杂环壬烷
• 英文名称: 10,11,12,13,14,15-hexamethyl-1,2,4,5-tetraoxanate
• 英文别名: 3,3,6,6,9,9-hexamethyl-1,2,4,5-tetraoxacyclononane；3,3,6,6,9,9-hexamethyl-[1,2,4,5]tetroxonane；3,3,6,6,9,9-Hexamethyl-[1,2,4,5]tetroxonan；3,3,6,6,9,9-Hexamethyl-1,2,4,5-tetroxonane；3,3,6,6,9,9-hexamethyl-1,2,4,5-tetraoxonane
• CAS: 22397-33-7
• 化学式: C₁₁H₂₂O₄
• 分子量: 218.293
• InChiKey: QRIQYQXNFSXNGR-UHFFFAOYSA-N

物化性质

• 沸点：
  206.2±20.0 °C(Predicted)
• 密度：
  0.913±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2914190090

反应信息

• 作为产物：
  描述：

  2,5-二甲基正己烷-2,5-二甲羟基过氧化物 在 copper(II) sulfate 、 丙酮 作用下， 生成 3,3,6,6,9,9-六甲基-1,2,4,5-四氧杂环壬烷
  参考文献：
  名称：

  Criegee; Schnorrenberg; Becke, Justus Liebigs Annalen der Chemie, 1949, vol. 565, p. 7,17

  摘要：

  DOI：

文献信息

• Hydroxylamine esters as polymerization initiators
  申请人：——

  公开号：US20030216494A1

  公开（公告）日：2003-11-20

  The invention relates to novel cyclic and open-chain hydroxylamine esters and polymerizable compositions comprising these hydroxylamine esters and an ethylenically unsaturated monomer or oligomer. The invention also relates to use as polymerization initiators and to the use of known hydroxylamine esters selected from the group consisting of HALS compounds and the novel hydroxylamine esters for the controlled degradation of polypropylene and for achieving a controlled increase in the molecular weight of polyethylene.

  该发明涉及新型环状和开链羟胺酯以及包括这些羟胺酯和乙烯基不饱和单体或寡聚物的可聚合组合物。该发明还涉及用作聚合引发剂以及用于控制聚丙烯降解和实现聚乙烯分子量控制增加的已知羟胺酯，所述羟胺酯来自HALS化合物和新颖羟胺酯的组合。
• Reactor for Preparing Organic Peroxides Via the Intermediate of a Solid Hydroperoxide
  申请人：Appel Hans

  公开号：US20090187048A1

  公开（公告）日：2009-07-23

  A reactor which comprises a vessel ( 1 ) with a vessel bottom ( 2 ), a stirrer ( 3 ) arranged in the vessel, an emergency discharge valve ( 4 ) arranged in the vessel bottom for emptying the reactor in less than 600 seconds and at least one filtration device ( 5 ) arranged in the vessel bottom is suitable for the safe preparation of organic peroxides. The process for preparing an organic peroxide comprises the steps of preparing a solid hydroperoxide in the form of a suspension in the reactor, filtering the suspension through the filtration device ( 5 ) arranged in the vessel bottom ( 2 ) while retaining the solid hydroperoxide in the reactor and reacting the hydroperoxide with an alkylating agent, an acylating agent or a carbonyl compound.

  一个包括容器（1）和容器底部（2）、安排在容器内的搅拌器（3）、安排在容器底部的紧急排放阀（4）以在不到600秒内排空反应器、以及至少一个安排在容器底部的过滤装置（5）的反应器适用于安全制备有机过氧化物。制备有机过氧化物的过程包括以下步骤：在反应器中制备悬浮态的固体过氧化氢，通过安排在容器底部的过滤装置（5）过滤悬浮液，同时保留反应器中的固体过氧化氢，并将过氧化氢与烷基化剂、酰化剂或羰基化合物反应。
• Method for Controlled Free Radical Polymerization or Copolymerization of Methacrylic and/or Methacrylate Monomers or Exclusively Methacrylic and/or Methacrylate Copolymers
  申请人：Couturier Jean-Luc

  公开号：US20080274074A1

  公开（公告）日：2008-11-06

  The invention relates to a method for the polymerization of one or more methacrylate and/or methacrylic monomers, for the synthesis of methacrylate or methacrylic polymers or of exclusively methacrylic and/or methacrylate copolymers, comprising a step of bringing said monomer(s) into contact with one at least of the compounds of formula (I) and (II) below: in which: R 1 and R 2 may represent a phenyl group, R 3 and R 4 may together form an ═N-phenyl group, Z represents a group of formula —CR 8 R 9 R 10 , in which R 8 and R 9 may represent methyl groups and R 10 may represent a —COO-phenyl group.

  本发明涉及一种合成甲基丙烯酸甲酯或甲基丙烯酸聚合物或仅为甲基丙烯酸和/或甲基丙烯酸酯共聚物的聚合物的聚合方法，包括将上述单体与以下式(I)和(II)化合物之一中的至少一种接触的步骤：式中：R1和R2可以表示苯基，R3和R4可以共同形成═N-苯基，Z表示式—CR8R9R10的基团，其中R8和R9可以表示甲基基团，而R10可以表示—COO-苯基基团。
• COSMETIC PREPARATIONS BASED ON MOLECULARLY IMPRINTED POLYMERS
  申请人：Wendel Volker

  公开号：US20100048737A1

  公开（公告）日：2010-02-25

  The present invention relates to cosmetic or dermatological formulations comprising at least one active compound, at least one polymer which is molecularly imprinted in the presence of this active compound and at least one fatty phase.

  本发明涉及至少包含一种活性化合物、至少一种在存在该活性化合物的情况下分子印迹的聚合物和至少一种脂肪相的化妆品或皮肤学配方。
• Process for the controlled increase in the molecular weight of polyethylenes
  申请人：Roth Michael

  公开号：US20060128903A1

  公开（公告）日：2006-06-15

  The invention relates to novel cyclic hydroxylamine esters and to the use of known hydroxylamine esters selected from the group consisting of HALS (sterically hindered amine) compounds and the novel hydroxylamine esters achieving a controlled increase in the molecular weight of polyethylene.

  本发明涉及新型环状羟胺酯以及选自包括HALS（立体位阻胺）化合物的已知羟胺酯和实现对聚乙烯分子量的控制增加的新型羟胺酯的使用。