bis(o-bromophenyl)bis(p-methoxyphenyl)stannane | 710353-70-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: bis(o-bromophenyl)bis(p-methoxyphenyl)stannane
• 英文别名: Bis(2-bromophenyl)-bis(4-methoxyphenyl)stannane
• CAS: 710353-70-1
• 化学式: C₂₆H₂₂Br₂O₂Sn
• 分子量: 644.977
• InChiKey: GTRZRENTRORXRN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.61
• 重原子数：
  31
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bis(o-bromophenyl)bis(p-methoxyphenyl)stannane 在 t-BuLi 作用下， 以 四氢呋喃 、 二氯甲烷 、 正戊烷 为溶剂， 生成 9,9,10,10-tetraiodo-9,10-dihydro-9,10-distannaanthracene
  参考文献：
  名称：

  Synthesis, Structures and Reactions of Novel 9,10‐Dihydro‐9,10‐distannaanthracenes

  摘要：

  AbstractA method for the synthesis of 9,10‐dihydro‐9,10‐distannaanthracenes has been improved and applied to the synthesis of novel unsymmetrical 9,10‐dihydro‐9,10‐distannaanthracenes. The first 9,9,10,10‐tetrahalo‐9,10‐dihydro‐9,10‐distannaanthracenes were successfully synthesized by halogenation of 9,9,10,10‐tetrakis(p‐methoxyphenyl)‐9,10‐dihydro‐9,10‐distannaanthracene. The structures of the newly obtained 9,10‐dihydro‐9,10‐distannaanthracenes were determined by X‐ray analysis. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

  DOI：

  10.1002/ejic.200300382
• 作为产物：
  描述：

  dichloro[bis(p-methoxyphenyl)]stannane 、 1,2-二溴苯 在 BuLi 作用下， 以 四氢呋喃 、 乙醚 、 正己烷 为溶剂， 以48%的产率得到bis(o-bromophenyl)bis(p-methoxyphenyl)stannane
  参考文献：
  名称：

  Synthesis, Structures and Reactions of Novel 9,10‐Dihydro‐9,10‐distannaanthracenes

  摘要：

  AbstractA method for the synthesis of 9,10‐dihydro‐9,10‐distannaanthracenes has been improved and applied to the synthesis of novel unsymmetrical 9,10‐dihydro‐9,10‐distannaanthracenes. The first 9,9,10,10‐tetrahalo‐9,10‐dihydro‐9,10‐distannaanthracenes were successfully synthesized by halogenation of 9,9,10,10‐tetrakis(p‐methoxyphenyl)‐9,10‐dihydro‐9,10‐distannaanthracene. The structures of the newly obtained 9,10‐dihydro‐9,10‐distannaanthracenes were determined by X‐ray analysis. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

  DOI：

  10.1002/ejic.200300382

文献信息

• Synthesis, Structures and Reactions of Novel 9,10‐Dihydro‐9,10‐distannaanthracenes
  作者：Masaichi Saito、Natsumi Henzan、Minehiko Nitta、Michikazu Yoshioka

  DOI：10.1002/ejic.200300382

  日期：2004.2

  AbstractA method for the synthesis of 9,10‐dihydro‐9,10‐distannaanthracenes has been improved and applied to the synthesis of novel unsymmetrical 9,10‐dihydro‐9,10‐distannaanthracenes. The first 9,9,10,10‐tetrahalo‐9,10‐dihydro‐9,10‐distannaanthracenes were successfully synthesized by halogenation of 9,9,10,10‐tetrakis(p‐methoxyphenyl)‐9,10‐dihydro‐9,10‐distannaanthracene. The structures of the newly obtained 9,10‐dihydro‐9,10‐distannaanthracenes were determined by X‐ray analysis. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)