2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoro-1-(4-methylphenyl)heptan-1-one | 749924-42-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoro-1-(4-methylphenyl)heptan-1-one
• CAS: 749924-42-3
• 化学式: C₁₄H₈F₁₂O
• 分子量: 420.198
• InChiKey: XLMFUUBQLZXETP-UHFFFAOYSA-N

物化性质

• 沸点：
  279.7±40.0 °C(Predicted)
• 密度：
  1.470±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  27
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  13

反应信息

• 作为反应物：
  描述：

  2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoro-1-(4-methylphenyl)heptan-1-one 在 吡啶 、 盐酸羟胺 作用下， 以 乙醇 为溶剂， 以41%的产率得到
  参考文献：
  名称：

  [EN] HALOGENATED OXIME DERIVATIVES AND THE USE THEREOF AS LATENT ACIDS
  [FR] DERIVES D'OXIME HALOGENEE ET UTILISATION DE CEUX-CI COMME ACIDES LATENTS

  摘要：

  公开号：

  WO2004074242A3
• 作为产物：
  描述：

  7H-十二氟庚酰氯 、 甲苯 在 4-二甲氨基吡啶 、 aluminum (III) chloride 作用下， 以 二氯甲烷 为溶剂， 生成 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoro-1-(4-methylphenyl)heptan-1-one
  参考文献：
  名称：

  [EN] HALOGENATED OXIME DERIVATIVES AND THE USE THEREOF AS LATENT ACIDS
  [FR] DERIVES D'OXIME HALOGENEE ET UTILISATION DE CEUX-CI COMME ACIDES LATENTS

  摘要：

  公开号：

  WO2004074242A3

文献信息

• CONJUGATED COMPOUND, NITROGENATED CONDENSED-RING COMPOUND, NITROGENATED CONDENSED-RING POLYMER, ORGANIC THIN FILM, AND ORGANIC THIN FILM ELEMENT
  申请人：Osaka University

  公开号：EP2223918A1

  公开（公告）日：2010-09-01

  According to the first invention group there are provided conjugated compounds having two or more groups represented by the following formula (I) or the following formula (II): wherein one of Ar and Ar' represents a C6 or greater divalent aromatic hydrocarbon group and the other represents a C4 or greater divalent heterocyclic group, wherein the groups each may have a substituent, with the proviso that the groups as a whole contain no fluorine atoms, R1 and R2 each independently represent a hydrogen atom, a halogen atom or a monovalent group, and Ar" represents a trivalent aromatic hydrocarbon or trivalent heterocyclic group; when the conjugated compound has two or more groups represented by formula (I), the portion excluding these groups contain no fluorine atoms. According to the second group of the present invention there are provided nitrogen-containing fused-ring compounds represented by the following formula (α-I): in formula (α-I), R21 and R22 each independently represent a hydrogen atom, a halogen atom or an optionally substituted monovalent group, and Z21 and Z22 , each independently represent any one of the groups represented by the following formulas (α-i)-(α-ix); wherein R23, R24, R25 and R26 each independently represent a hydrogen atom, a halogen atom or a monovalent group, and R23 and R24 may bond together to form a ring, the left side and the right side of the group represented by formula (α-viii) may be interchanged.

  根据第一发明组，提供了具有两个或两个以上由下式（I）或下式（II）代表的基团的共轭化合物： 其中Ar和Ar'中的一个代表C6或更高的二价芳香烃基团，另一个代表C4或更高的二价杂环基团，其中各基团可有一个取代基，但各基团整体上不含氟原子，R1和R2各自独立地代表氢原子、卤素原子或一价基团，Ar "代表三价芳香烃或三价杂环基团；当共轭化合物具有两个或两个以上由式（I）表示的基团时，不包括这些基团的部分不含有氟原子。 根据本发明的第二组，提供了由下式（α-I）代表的含氮熔环化合物： 式(α-I)中，R21 和 R22 各自独立地代表氢原子、卤素原子或任选取代的一价基团，Z21 和 Z22 ，各自独立地代表下列式(α-i)-(α-ix)所代表的基团中的任一个； 其中 R23、R24、R25 和 R26 各自独立地代表氢原子、卤素原子或单价基团，且 R23 和 R24 可键合在一起形成环，式 (α-viii) 所代表基团的左侧和右侧可互换。
• Nitrogen-containing fused-ring compound, polymer comprising a nitrogen-containing fused-ring repeating unit, organic thin film, and organic thin film element
  申请人：SUMITOMO CHEMICAL CO., LTD.

  公开号：EP2520572A1

  公开（公告）日：2012-11-07

  The present invention provides nitrogen-containing fused-ring compounds represented by the following formula (α-I): in formula (α-I), R21 and R22 each independently represent a hydrogen atom, a halogen atom or an optionally substituted monovalent group, and Z21 and Z22 each independently represent any one of the groups represented by the following formulas (α-i)-(α-ix); wherein R23, R24, R25 and R26 each independently represent a hydrogen atom, a halogen atom or a monovalent group, and R23 and R24 may bond together to form a ring, the left side and the right side of the group represented by formula (α-viii) may be interchanged.

  本发明提供了由下式（α-I）表示的含氮熔环化合物： 式(α-I)中，R21和R22各自独立地代表氢原子、卤素原子或任选取代的一价基团，Z21和Z22各自独立地代表下式(α-i)-(α-ix)所代表的基团中的任一个； 其中 R23、R24、R25 和 R26 各自独立地代表氢原子、卤素原子或单价基团，且 R23 和 R24 可键合在一起形成环，式 (α-viii) 所代表基团的左侧和右侧可互换。
• Halogenated oxime derivatives and the use therof as latent acids
  申请人：Yamato Hitoshi

  公开号：US20090042114A1

  公开（公告）日：2009-02-12

  Compounds of the formula I or II wherein R 1 is C 1 -C 10 haloalkylsulfonyl, halobenzenesulfonyl, C 2 -C 10 haloalkanoyl, halobenzoyl; R 2 is halogen or C 1 -C 10 haloalkyl; Ar 1 is phenyl, biphenylyl, fluorenyl, naphthyl, anthracyl, phenanthryl, or heteroaryl, all of which are optionally substituted; Ar′ 1 is for example phenylene, naphthylene, diphenylene, heteroarylene, oxydiphenylene, phenylene-D-D 1 -D-phenylene or —Ar″ 1 -A 1 -Y 1 -A 1 -Ar″ 1 —; wherein these radicals optionally are substituted; Ar″ 1 is phenylene, naphthylene, anthracylene, phenanthrylene, or heteroarylene, all optionally substituted; A 1 is for example a direct bond, —O—, —S—, or —NR 6 —; Y 1 inter alia is C 1 -C 18 alkylene; X is halogen; D is for example —O—, —S— or —NR 6 —; D 1 inter alia is C 1 -C 18 alkylene; are particularly suitable as photolatent acids in ArF resist technology.
• US8241822B2
  申请人：——

  公开号：US8241822B2

  公开（公告）日：2012-08-14
• US8378338B2
  申请人：——

  公开号：US8378338B2

  公开（公告）日：2013-02-19