甲基5-十四碳炔酸酯 | 39077-29-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 甲基5-十四碳炔酸酯
• 英文名称: Methyl tetradec-5-ynoate
• CAS: 39077-29-7
• 化学式: C₁₅H₂₆O₂
• 分子量: 238.37
• InChiKey: LZGVSHAOWJOSKI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  17
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  甲基5-十四碳炔酸酯 在 Lindlar's catalyst 作用下， 生成 methyl(Z)-5-tetra-decanoate
  参考文献：
  名称：

  2-(E)-nonen-1-ol: Male attractant for chafersAnomala vitis Fabr. andA. dubia Scop. (Coleoptera: Scarabaeidae)

  摘要：

  Traps baited with 2-(E)-nonen-1-ol alone or in combination with other compounds caught large numbers of males of both the vine chafer, Anomala vitis Fabr. and the margined vine chafer, A. dubia Scop. (Coleoptera: Scarabaeidae), vineyard and orchard pests. In a dosage test, the largest numbers were caught by traps baited with 10 mg of 2-(E)-nonen-1-ol, which was the highest dosage tested. This is the first report on male attractants for chafer species occurring in Europe.

  DOI：

  10.1007/bf02036185
• 作为产物：
  描述：

  tetradec-5-yn-4-olide 在 铜 、 锌 氯化亚砜 、 溶剂黄146 作用下， 反应 11.5h， 生成 甲基5-十四碳炔酸酯
  参考文献：
  名称：

  Low-molecular-mass bioregulators. II. Synthesis of methyl (�)-tetradeca-2E,4,5-trienoate ? The sex pheromone ofAcanthoscelides obtectus

  摘要：

  DOI：

  10.1007/bf00605208

文献信息

• Bohlmann,F. et al., Chemische Berichte, 1969, vol. 102, p. 3283 - 3292
  作者：Bohlmann,F. et al.

  DOI：——

  日期：——
• MELIKYAN, G. G.;MKRTCHYAN, V. M.;ATANESYAN, K. A.;AZARYAN, G. X.;BADANYAN+, BIOORGAN. XIMIYA, 16,(1990) N, S. 1000-1001
  作者：MELIKYAN, G. G.、MKRTCHYAN, V. M.、ATANESYAN, K. A.、AZARYAN, G. X.、BADANYAN+

  DOI：——

  日期：——
• Low-molecular-mass bioregulators. II. Synthesis of methyl (�)-tetradeca-2E,4,5-trienoate ? The sex pheromone ofAcanthoscelides obtectus
  作者：G. G. Melikyan、V. M. Mkrtchyan、K. A. Atanesyan、G. Kh. Azaryan、Sh. O. Badanyan

  DOI：10.1007/bf00605208

  日期：——
• 2-(E)-nonen-1-ol: Male attractant for chafersAnomala vitis Fabr. andA. dubia Scop. (Coleoptera: Scarabaeidae)
  作者：Miklós Tóth、Walter Soares Leal、István Szarukán、Mátyás Lesznyák、Gábor Szöcs

  DOI：10.1007/bf02036185

  日期：1994.10

  Traps baited with 2-(E)-nonen-1-ol alone or in combination with other compounds caught large numbers of males of both the vine chafer, Anomala vitis Fabr. and the margined vine chafer, A. dubia Scop. (Coleoptera: Scarabaeidae), vineyard and orchard pests. In a dosage test, the largest numbers were caught by traps baited with 10 mg of 2-(E)-nonen-1-ol, which was the highest dosage tested. This is the first report on male attractants for chafer species occurring in Europe.