9-decyl-9H-carbazole-3-carbaldehyde | 1004765-56-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-decyl-9H-carbazole-3-carbaldehyde
• 英文别名: (3-formyl-9-carbazolyl)-decane；9-Decylcarbazole-3-carbaldehyde
• CAS: 1004765-56-3
• 化学式: C₂₃H₂₉NO
• 分子量: 335.489
• InChiKey: LLVVXYFABCZURM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  25
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  22
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4,4'-二甲基-2,2'-联吡啶 、 9-decyl-9H-carbazole-3-carbaldehyde 在 potassium tert-butylate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 12.0h， 以40%的产率得到4,4'-bis((E)-2-(9-decyl-9H-carbazol-3-yl)vinyl)-2,2-bipyridine
  参考文献：
  名称：

  CARBAZOLE END CAPPED BIPYRIDINE COMPOUNDS AND PROCESS FOR PREPARATION THEREOF

  摘要：

  本发明旨在提供用于固态照明的高固态发光荧光体的化学式1和2。化学式1和2在蓝色和绿色区域分别具有良好的固态发射。化学式1A和2A的锌配合物在固态中分别具有黄色和红色发射。本发明还提供了化学式1和2的高固态发射测定，通过在365纳米发射固态LED上涂覆颜色可调材料，将紫外光转换为可见光。本发明还提供了用于筛选具有不同对离子的金属盐的碳齿端封闭双吡啶。通过注意溶液中的荧光变化来监测各种金属盐的区分。具有不同对离子的锌盐在溶液中具有不同的发射颜色。本发明还开发了一种新的双光子活性荧光Zn2+特异性探针，用于检测细胞环境中的Zn2+。化学式3的测定用作HeLa细胞中Zn2+离子的双光子成像的荧光探针。化学式3的高双光子吸收截面和荧光量子产率使其成为通过双光子激发荧光成像检测细胞环境中Zn2+的有用探针。

  公开号：

  US20140023883A1

文献信息

• Organophotoreceptor with a charge transport material having two azine groups
  申请人：Jubran Nusrallah

  公开号：US20050069798A1

  公开（公告）日：2005-03-31

  Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where n is an integer between 2 and 6, inclusive; R 1 and R 2 are, independently, H, halogen, carboxyl, hydroxyl, thiol, cyano, nitro, aldehyde group, ketone group, an ether group, an ester group, a carbonyl group, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula —(CH 2 ) m —, branched or linear, where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups can be optionally replaced by O, S, C═O, O═S═O, urethane, urea, an ester group, a NR 3 group, a CHR 4 group, or a CR 5 R 6 group where R 3 , R 4 , R 5 , and R 6 are, independently, H, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; Y comprises a bond, C, N, O, S, a branched or linear —(CH 2 ) p — group where p is an integer between 0 and 10, an aromatic group, a cycloalkyl group, a heterocyclic group, or a NR 7 group where R 7 is hydrogen atom, an alkyl group, or aryl group, wherein Y has a structure selected to form n bonds with the corresponding X groups; and Z is a fluorenylidene group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.

  改进的器官光感受器包括电导基板和位于电导基板上的光电导元件，光电导元件包括：(a) 具有以下结构的电荷传输材料，其中n是2到6之间的整数，包括；R1和R2独立地为H、卤素、羧基、羟基、硫醇、氰基、硝基、醛基、酮基、醚基、酯基、羰基、烷基、烷基芳基、或芳基；X是具有以下结构的连接基团—(CH2)m—，分支或线性，其中m是0到20之间的整数，包括，其中一个或多个亚甲基基团可以选择性地被O、S、C═O、O═S═O、脲、脲、酯基、NR3基团、CHR4基团或CR5R6基团取代，其中R3、R4、R5和R6独立地为H、烷基、烷基芳基、杂环基团或芳基；Y包括键、C、N、O、S、分支或线性—(CH2)p—基团，其中p是0到10之间的整数，芳香基团、环烷基团、杂环基团或NR7基团，其中R7是氢原子、烷基或芳基，其中Y的结构被选择为与相应的X基团形成n个键；Z是芴亚甲基基团；和(b) 一个电荷生成化合物。描述了相应的静电复印设备和成像方法。
• [EN] CARBAZOLE END CAPPED BIPYRIDINE COMPOUNDS AND PROCESS FOR PREPARATION THEREOF<br/>[FR] COMPOSÉS DE BIPYRIDINE COIFFÉE EN EXTRÉMITÉ PAR DU CARBAZOLE ET LEUR PROCÉDÉ DE PRÉPARATION
  申请人：COUNCIL SCIENT IND RES

  公开号：WO2012110945A1

  公开（公告）日：2012-08-23

  The present invention is to provide highly solid state emissive fluorophores of the formula 1 and 2 useful for the solid state lighting. The formula 1 and 2 have good solid state emission in blue and green region respectively. The zinc complexes of formula 1A and 2A have yellow and red emission respectively in solid state. The present invention also provide high solid state emissive assay of formula 1 and 2 to convert UV light into visible light by coating the color tunable materials on the 365- nm emitting solid state LED. The present invention further provides carbazole end- capped bipyridine for screening of metal salts with different counterions in solutions. The discrimination of the various metal salts can be monitored by noting the fluorescence change in solution. The zinc salts with different counterions have different emission color in solution. The present invention also develop a new two photon active fluorescent Zn2+ specific probe for detecting Zn2+ in cellular environments. Assay with formula 3 is used as a fluorescent probe for two photon imaging of Zn2+ ions in HeLa cells. The high two photon absorption cross section and fluorescence quantum yield of formula 3 made it as a useful probe for detecting Zn2+ in cellular environment by two photon excited fluorescence imaging.

  本发明提供了用于固态照明的高固态发光荧光体的化学式1和2，化学式1和2分别在蓝色和绿色区域具有良好的固态发射。化学式1A和2A的锌配合物在固态中分别具有黄色和红色发射。本发明还提供了化学式1和2的高固态发射测定，通过在365纳米发射固态LED上涂覆色可调材料将紫外光转换为可见光。本发明还提供了用于筛选不同配离子金属盐的碳酰基端-端联吡啶。通过观察溶液中的荧光变化，可以监测各种金属盐的区分。不同配离子的锌盐在溶液中具有不同的发射颜色。本发明还开发了一种新的双光子活性荧光Zn2+特异性探针，用于检测细胞环境中的Zn2+。使用化学式3作为HeLa细胞中Zn2+离子的双光子成像的荧光探针。化学式3的高双光子吸收截面和荧光量子产率使其成为通过双光子激发荧光成像检测细胞环境中的Zn2+的有用探针。
• A fluorescent molecular probe for the identification of zinc and cadmium salts by excited state charge transfer modulation
  作者：Kizhmuri P. Divya、Sivaraman Savithri、Ayyappanpillai Ajayaghosh

  DOI：10.1039/c4cc00379a

  日期：——

  A fluorescent probe for the identification of a given metal salt is not known. Herein we present a new fluorescent probe 1 for the identification of different zinc and cadmium salts by exploiting the effect of the charge density of counteranions to perturb the excited state solvatochromic behavior of the probe.

  目前还没有一种荧光探针可用于识别特定的金属盐。在此，我们提出了一种新的荧光探针 1，利用反离子的电荷密度效应来扰动探针的激发态溶解变色行为，从而识别不同的锌盐和镉盐。
• Organophotoreceptor with a charge transport material having at least two azine groups
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP1519239A2

  公开（公告）日：2005-03-30

  The present invention provides organophotoreceptors comprising an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where n is an integer between 2 and 6, inclusive; R1 and R2 are, independently, H, halogen, carboxyl, hydroxyl, thiol, cyano, nitro, aldehyde group, ketone group, an ether group, an ester group, a carbonyl group, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula -(CH2)m-, branched or linear, where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups can be optionally replaced by O, S, C=O, O=S=O, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R5, and R6 are, independently, H, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; Y comprises a bond, C, N, O, S, a branched or linear -(CH2)p- group where p is an integer between 0 and 10, an aromatic group, a cycloalkyl group, a heterocyclic group, or a NR7 group where R7 is hydrogen atom, an alkyl group, or aryl group, wherein Y has a structure selected to form n bonds with the corresponding X groups; and Z is a fluorenylidene group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods (processes) are described, as are corresponding charge transport materials.

  本发明提供的有机光感受器包括导电基板和导电基板上的光电导元件，光电导元件包括 (a) 电荷传输材料，其式为 式中 n 是介于 2 和 6 之间的整数； R1 和 R2 分别为 H、卤素、羧基、羟基、硫醇、氰基、硝基、醛基、酮基、醚基、酯基、羰基、烷基、烷芳基或芳基； X 是具有式-(CH2)m-的连接基团，支链或线性，其中 m 是 0 至 20（包括 20）之间的整数，一个或多个亚甲基可选择被 O、S、C=O、O=S=O、氨基甲酸酯、脲、酯基、NR3 基团、CHR4 基团或 CR5R6 基团，其中 R3、R4、R5 和 R6 独立地为 H、烷基、烷芳基、杂环基团或芳基； Y 包括键、C、N、O、S、支链或线性-(CH2)p-基团（其中 p 为 0 至 10 之间的整数）、芳香基团、环烷基基团、杂环基团或 NR7 基团（其中 R7 为氢原子、烷基基团或芳基基团），其中 Y 的结构可与相应的 X 基团形成 n 个键；以及 Z 是亚芴基团；以及 (b) 产生电荷的化合物。 描述了相应的电致发光装置和成像方法（过程），以及相应的电荷传输材料。
• US6955869B2
  申请人：——

  公开号：US6955869B2

  公开（公告）日：2005-10-18