2-Hydroxy-2,4-dimethyl-pentansaeure-butylester | 10348-52-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-Hydroxy-2,4-dimethyl-pentansaeure-butylester
• 英文别名: Butyl 2-hydroxy-2,4-dimethylpentanoate；butyl 2-hydroxy-2,4-dimethylpentanoate
• CAS: 10348-52-4
• 化学式: C₁₁H₂₂O₃
• 分子量: 202.294
• InChiKey: BCQAZCYAYLOJCW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  丙酮酸丁酯 在 platinum(IV) oxide 氢气 、 四氯化锡 作用下， 以 乙醇 、 1,2-二氯乙烷 为溶剂， 生成 2-Hydroxy-2,4-dimethyl-pentansaeure-butylester
  参考文献：
  名称：

  Klimova,E.; Arbuzov,Yu., Doklady Chemistry, 1966, vol. 167, p. 419 - 421

  摘要：

  DOI：

文献信息

• Catalyst for polymerization and co-polymerization of ethylene
  申请人：——

  公开号：US20010031694A1

  公开（公告）日：2001-10-18

  The present invention relates to a catalyst for polymerization and co-polymerization of ethylene. More particularly, the present invention relates to a solid titanium catalyst containing magnesium, wherein said catalyst is produced by preparing a magnesium solution by contact-reacting a halogenated magnesium compound with alcohol; reacting said solution with an ester compound having at least one hydroxy group, or a phosphorous compound and a silicon compound having alkoxy groups; producing a solid component with an adjusted particle morphology by adding a mixture of a titanium compound and a silicon compound; reacting the same with an aluminum compound; and then reacting the same with a titanium compound, or a titanium compound and a vanadium compound. As a result, the catalyst of the present invention has high catalytic activity with excellent catalyst morphology.

  本发明涉及一种乙烯聚合和共聚合催化剂。更具体地说，本发明涉及一种含镁的固体钛催化剂，其中所述催化剂是通过以下方法制备的：将卤代镁化合物与醇接触反应制备镁溶液；将所述溶液与具有至少一个羟基的酯化合物或磷化合物和具有烷氧基的硅化合物反应；加入钛化合物和硅化合物的混合物，使其与铝化合物反应，然后与钛化合物或钛化合物和钒化合物反应，制得具有调整颗粒形态的固体组分。因此，本发明的催化剂具有很高的催化活性和优异的催化剂形态。
• Catalyst for producing an ultra high molecular weight polyethylene and method for producing an ultra high molecular weight polyethylene using the same
  申请人：——

  公开号：US20020045537A1

  公开（公告）日：2002-04-18

  The present invention provides a method for producing a catalyst for the production of an ultra high molecular weight polyethylene and also a method for preparation of an ultra high molecular weight polyethylene with the use of said catalyst. The catalyst of the present invention is prepared by a process comprising: (i) producing a magnesium compound solution by contact-reacting a magnesium compound and an aluminum or boron compound with alcohol; (ii) contact-reacting the said solution with an ester compound containing at least one hydroxy group and a silicon compound containing an alkoxy group; and (iii) producing a solid titanium catalyst by adding a mixture of a titanium compound and a silicon compound thereto. The catalyst prepared by the present invention has excellent catalytic activity, and it helps to produce an ultra-high molecular weight polyethylene with large bulk density and narrow particle distribution without too large and minute particles.

  本发明提供了一种用于生产超高分子量聚乙烯的催化剂的生产方法，以及一种使用所述催化剂制备超高分子量聚乙烯的方法。本发明催化剂的制备工艺包括：(i) 通过将镁化合物和铝或硼化合物与醇接触反应制得镁化合物溶液；(ii) 将上述溶液与含有至少一个羟基的酯化合物和含有一个烷氧基的硅化合物接触反应；(iii) 通过向其中加入钛化合物和硅化合物的混合物制得固体钛催化剂。本发明制备的催化剂具有优异的催化活性，有助于生产体积密度大、颗粒分布窄、没有过大和过细颗粒的超高分子量聚乙烯。
• Method for producing a catalyst for homo-or co-polymerization of ethylene
  申请人：——

  公开号：US20040053774A1

  公开（公告）日：2004-03-18

  The present invention provides a method for producing a new catalyst of high catalytic activity and superior catalyst morphology for homo- or co-polymerization of ethylene, or more particularly a method for producing a titanium solid complex catalyst supported on a carrier containing magnesium, wherein said catalyst of high polymerization activity is capable of producing polymers of high bulk density.

  本发明提供了一种用于乙烯均聚或共聚的高催化活性和优异催化剂形态的新型催化剂的生产方法，或者更具体地说是一种在含镁载体上支撑的钛固体复合催化剂的生产方法，其中所述高聚合活性催化剂能够生产高体积密度的聚合物。
• Method of producing a catalyst for ethylene homo-and co-polymerization
  申请人：Samsung General Chemicals Co., Ltd.

  公开号：US20040242409A1

  公开（公告）日：2004-12-02

  The present invention relates to a catalyst for homo-polymerization or co-polymerization of ethylene, or more particularly to a solid complex titanium catalyst for homo-polymerization or co-polymerization of ethylene. The catalyst may be produced by preparing a magnesium solution by contact-reacting a magnesium halide compound with an alcohol. Reacting the solution with an ester compound and a boron compound. Then reacting the solution with a mixture of a titanium compound and a silicon compound.

  本发明涉及一种乙烯均聚或共聚的催化剂，或更具体地说，涉及一种乙烯均聚或共聚的固体复合钛催化剂。该催化剂可通过卤化镁化合物与醇的接触反应制备镁溶液。将溶液与酯化合物和硼化合物反应。然后将溶液与钛化合物和硅化合物的混合物反应。
• Method of polymerization and copolymerization of ethylene
  申请人：Yang Chun-Byung

  公开号：US20060149007A1

  公开（公告）日：2006-07-06

  Disclosed is a method of polymerization and copolymerization of ethylene, which is carried out in the presence of (a) a solid titanium complex catalyst prepared by the steps of (i) preparing a magnesium solution by contacting halogenated magnesium compounds with alcohol, (ii) reacting the magnesium solution with ester compound having at least one hydroxyl group and silicon compound having alkoxy group, (iii) preparing a solid titanium catalyst component by reacting mixture of titanium compound and haloalkane compound; and (iv) producing solid titanium complex catalyst by reacting the solid titanium catalyst component with mixture of aluminum compound and haloalkane compound, or with haloalkane; and (b) organometallic compounds in Group II or III of the Periodic Table.

  本发明公开了一种乙烯的聚合和共聚方法，该方法是在(a)固体钛复合催化剂的存在下进行的，固体钛复合催化剂的制备步骤为：(i)通过将卤代镁化合物与醇接触制备镁溶液，(ii)使镁溶液与具有至少一个羟基的酯化合物和具有烷氧基的硅化合物反应，(iii)通过使钛化合物和卤代烷烃化合物的混合物反应制备固体钛催化剂组分，以及(iv)通过使固体钛催化剂组分与铝化合物和卤代烷烃化合物的混合物或卤代烷烃反应制备固体钛复合催化剂；以及(b)有机金属化合物；(iv) 将固体钛催化剂组分与铝化合物和卤代烷烃化合物的混合物或卤代烷烃进行反 应，制得固体钛复合催化剂；以及 (b) 元素周期表中第 II 或 III 族的有机金属化合物。