2-Hydroxy-3-(morpholin-4-yl)cyclohex-2-en-1-on | 40621-92-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-Hydroxy-3-(morpholin-4-yl)cyclohex-2-en-1-on
• 英文别名: 3-morpholin-4-yl-cyclohexane-1,2-dione；2-Hydroxy-3-morpholin-4-ylcyclohex-2-en-1-one
• CAS: 40621-92-9
• 化学式: C₁₀H₁₅NO₃
• 分子量: 197.234
• InChiKey: UMLWVOWQIHAPJW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  49.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-Hydroxy-3-(morpholin-4-yl)cyclohex-2-en-1-on 以 二氯甲烷 为溶剂， 生成 3-hydroxy-3-(1-methoxy-2,6-dioxocyclohexyl)spiro[5.5]undecan-2,4-dion
  参考文献：
  名称：

  Chemie freier cyclischer vicinaler Tricarbonyl-Verbindungen (‘1,2,3-Trione') Teil 2. Redox-Reaktionen von 1,2,3-Trionen mit En-1,2-diolen (‘Reduktonen'), 2-Alkoxy-en-1-olen, En-1,2-diaminen und verwandten Spezies Für Teil 1, s. [1].

  摘要：

  Chemistry of Free Cyclic Vicinal Tricarbonyl Compounds ('1,2,3-Triones'). Part 2. Redox Reactions of 1,2,3-Triones with Ene-1,2-diols ('Reductones'), 2-Alkoxy-en-1-ols, Ene-1,2-diamines, and Related SpeciesMidstanding carbonyl groups of cyclic 1,2,3-triones 4 possess outstanding electrophilic (elcctron-pair accepting) as well as oxidizing (one-electron accepting) properties. Their reactions with selected electron-rich C C bonds as efficient nucleophiles (AN reactions) and as efficient reducing agents (SET (single electron transfer) reactions) are studied. In a few cases, short-lived charge-transfer colors could be observed. Particularly, free didehydro-5,6-0-isopropyliden-L-ascorbic acid (4g), its 0,C-adduct 8g to 5,6-O-isopropylidene-(L)-ascorbic acid (1g), and - via an independent pathway - the ostensible C,C-dimer 10a of mono-dehydrodimedone reductone were prepared. Intermediate radical anions 4- can be considered to be ideal representatives of dicapto-dative radicals. Novel large-scale syntheses of 3,4-dihydroxyfuran-2(5H)-one (1e) and of its vicinal trione 4e are presented.

  DOI：

  10.1002/1522-2675(200205)85:5<1295::aid-hlca1295>3.0.co;2-k
• 作为产物：
  描述：

  3-morpholin-4-yl-cyclohex-2-enone 生成 2-Hydroxy-3-(morpholin-4-yl)cyclohex-2-en-1-on
  参考文献：
  名称：

  Chemie freier cyclischer vicinaler Tricarbonyl-Verbindungen (‘1,2,3-Trione') Teil 2. Redox-Reaktionen von 1,2,3-Trionen mit En-1,2-diolen (‘Reduktonen'), 2-Alkoxy-en-1-olen, En-1,2-diaminen und verwandten Spezies Für Teil 1, s. [1].

  摘要：

  Chemistry of Free Cyclic Vicinal Tricarbonyl Compounds ('1,2,3-Triones'). Part 2. Redox Reactions of 1,2,3-Triones with Ene-1,2-diols ('Reductones'), 2-Alkoxy-en-1-ols, Ene-1,2-diamines, and Related SpeciesMidstanding carbonyl groups of cyclic 1,2,3-triones 4 possess outstanding electrophilic (elcctron-pair accepting) as well as oxidizing (one-electron accepting) properties. Their reactions with selected electron-rich C C bonds as efficient nucleophiles (AN reactions) and as efficient reducing agents (SET (single electron transfer) reactions) are studied. In a few cases, short-lived charge-transfer colors could be observed. Particularly, free didehydro-5,6-0-isopropyliden-L-ascorbic acid (4g), its 0,C-adduct 8g to 5,6-O-isopropylidene-(L)-ascorbic acid (1g), and - via an independent pathway - the ostensible C,C-dimer 10a of mono-dehydrodimedone reductone were prepared. Intermediate radical anions 4- can be considered to be ideal representatives of dicapto-dative radicals. Novel large-scale syntheses of 3,4-dihydroxyfuran-2(5H)-one (1e) and of its vicinal trione 4e are presented.

  DOI：

  10.1002/1522-2675(200205)85:5<1295::aid-hlca1295>3.0.co;2-k

文献信息

• Amino hydroxy cyclo hexenones and their use as developing agents
  申请人：POLAROID CORPORATION

  公开号：EP0055900A1

  公开（公告）日：1982-07-14

  Novel amino hydroxy cyclohexenones have the formula wherein R1, R2, R3 and R4 each are alkyl, usually containing 1 to 20 carbon atoms. They are useful as photographic silver halide developing agents in photographic processes and may be present in photographic products including a silver halide layer and in photographic processing compositions including aqueous alkali.

  新型氨基羟基环己烯酮的化学式为 其中 R1、R2、R3 和 R4 各为烷基，通常含有 1 至 20 个碳原子。它们在照相过程中可用作照相卤化银显影剂，并可存在于包括卤化银层的照相产品和包括水碱的照相冲洗组合物中。
• Adler,M. et al., Chemische Berichte, 1979, vol. 112, p. 2324 - 2331
  作者：Adler,M. et al.

  DOI：——

  日期：——
• ALDER M.; SCHANK K.; SCHMIDT V., CHEM. BER., 1979, 112, NO 6, 2324-2331
  作者：ALDER M.、 SCHANK K.、 SCHMIDT V.

  DOI：——

  日期：——
• US4304934A
  申请人：——

  公开号：US4304934A

  公开（公告）日：1981-12-08
• US4371603A
  申请人：——

  公开号：US4371603A

  公开（公告）日：1983-02-01