tert.-Butyl-methyl-phenyl-phosphin | 119859-34-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tert.-Butyl-methyl-phenyl-phosphin
• 英文别名: Methyl-(2-methylpropyl)-phenylphosphane
• CAS: 119859-34-6
• 化学式: C₁₁H₁₇P
• 分子量: 180.23
• InChiKey: IBCOCCUYWHQQQI-UHFFFAOYSA-N

物化性质

• 沸点：
  54-55 °C(Press: 0.1 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  叠氮基三甲基硅烷 、 tert.-Butyl-methyl-phenyl-phosphin 反应 1.0h， 以96%的产率得到methyl-(2-methylpropyl)-phenyl-trimethylsilylimino-λ5-phosphane
  参考文献：
  名称：

  Wolfsberger, Werner, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1988, vol. 43, # 3, p. 295 - 298

  摘要：

  DOI：
• 作为产物：
  描述：

  2-[2-methylpropyl(phenyl)phosphanyl]acetic acid 以 氘代甲苯 为溶剂， 生成 二氧化碳 、 tert.-Butyl-methyl-phenyl-phosphin
  参考文献：
  名称：

  Doorn, Johannes A. van; Meijboom, Nico, Journal of the Chemical Society. Perkin transactions II, 1989, p. 1309 - 1314

  摘要：

  DOI：
• 作为试剂：
  描述：

  苯甲醛 、 丙烯酸乙酯 在 tert.-Butyl-methyl-phenyl-phosphin 作用下， 以 neat (no solvent) 为溶剂， 反应 0.5h， 以80%的产率得到2-(羟基苯基甲基)丙烯酸乙酯
  参考文献：
  名称：

  An intramolecular Baylis-Hillman reaction

  摘要：

  By means of an intramolecular Baylis-Hillman reaction the cyclopentene derivative 1 has been formed from 2. Asymmetric induction is low (entry 12, table 1). In the sixmembered ring example 9 --> 10 the yield is only 17% - 23% (entries 1 and 2, table 2).

  DOI：

  10.1016/s0040-4039(00)91855-0

文献信息

• Horner, Leopold; Dickerhof, Karlheinz, Phosphorus and Sulfur and the Related Elements, 1983, vol. 15, p. 213 - 218
  作者：Horner, Leopold、Dickerhof, Karlheinz

  DOI：——

  日期：——
• WOLFSBERGER, WERNER, Z. NATURFORSCH., 43,(1988) N 3, 295-298
  作者：WOLFSBERGER, WERNER

  DOI：——

  日期：——
• Composition, retardation plate, and liquid-crystal display device
  申请人：Li Yi

  公开号：US20080090027A1

  公开（公告）日：2008-04-17

  A composition comprising at least one liquid-crystal compound and a polymer having at least one group of the following formula (A) as the constitutive unit thereof: wherein Mp represents a trivalent linking group; L represents a single bond, or a bivalent linking group; X represents a substituted or unsubstituted functional group having a cyclic structure.
• LASER OSCILLATION ELEMENT
  申请人：FUJIFILM Corporation

  公开号：US20220145183A1

  公开（公告）日：2022-05-12

  Provided is a laser oscillation element including a cholesteric liquid crystal layer, in which even in a case where the intensity of excitation light is weak, laser oscillation can be induced. The laser oscillation element includes a cholesteric liquid crystal layer obtained by cholesteric alignment of a liquid crystal compound, in which in a cross-section of the cholesteric liquid crystal layer observed with a scanning electron microscope, bright portions and dark portions derived from the cholesteric liquid crystalline phase are tilted with respect to a main surface of the cholesteric liquid crystal layer, the cholesteric liquid crystal layer includes a colorant that emits light by excitation, and a luminescence wavelength range of the colorant and a selective reflection wavelength range of the cholesteric liquid crystal layer at least partially overlap each other.
• US7989037B2
  申请人：——

  公开号：US7989037B2

  公开（公告）日：2011-08-02