3-(2-allyl-phenoxy)-propan-1-ol | 856814-97-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3-(2-allyl-phenoxy)-propan-1-ol
• 英文别名: 3-[2-(Prop-2-EN-1-YL)phenoxy]propan-1-OL；3-(2-prop-2-enylphenoxy)propan-1-ol
• CAS: 856814-97-6
• 化学式: C₁₂H₁₆O₂
• mdl: MFCD15205911
• 分子量: 192.258
• InChiKey: XWQHPJPIVSSATP-UHFFFAOYSA-N

物化性质

• 沸点：
  159-160 °C(Press: 10.5 Torr)
• 密度：
  1.020±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.333
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-(2-allyl-phenoxy)-propan-1-ol 在 吡啶 、 氯化亚砜 作用下， 生成 (2-allyl-phenyl)-(3-chloro-propyl)-ether
  参考文献：
  名称：

  Particulate air pollution and hospital admissions in Christchurch, New Zealand

  摘要：

  Aims: Winter air pollution in Christchurch is dominated by particulate matter from solid fuel domestic heating. The aim of the study was to explore the relationship between particulate air pollution and admissions to hospital with cardio-respiratory illnesses.Methods: Particulate air pollution statistics (PM10) were obtained from the Canterbury Regional Council monitoring station in the city. The New Zealand Health Information Service provided data on admissions to the Princess Margaret and Christchurch Hospitals for the period June 1988 through December 1998 for both adults and children with cardiac and respiratory disorders. The relationship between PM10 and admissions was explored using a time series analysis approach controlling for weather variables. Missing values were interpolated from carbon monoxide data for the same time period, as carbon monoxide and PM10 were highly correlated.Results: There was a significant association between PM10 levels and cardio-respiratory admissions. For all age groups combined there was a 3.37% increase in respiratory admissions for each interquartile rise in PM10 (interquartile value 14.8 mcg/m(3)). There was also a 1.26% rise in cardiac admissions for each interquartile rise in PM10. There was no relationship between PM10 and admissions for appendicitis, the control condition selected.Conclusions: In keeping with overseas studies, there is evidence in Christchurch of a relationship between ambient particulate levels and admissions with cardiac and respiratory illnesses. The size of the effect is consistent with overseas data, with the greatest impact for respiratory disorders.Implications: These results indicate that measures to control ambient particulate levels have the potential to reduce hospital admissions for cardio-respiratory illnesses.

  DOI：

  10.1111/j.1467-842x.2002.tb00266.x
• 作为产物：
  描述：

  2-烯丙基酚 在 bis(cyclopentadienyl)titanium (III) chloride sodium ethanolate 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 反应 1.0h， 生成 3-(2-allyl-phenoxy)-propan-1-ol
  参考文献：
  名称：

  二茂钛（III）介导的8-内自由基环化为八元环醚的合成

  摘要：

  已经描述了二茂钛（III）氯化物（Cp 2 TiCl）介导的向八元环醚的合成的8-内基自由基环化。由市售的二茂钛二氯化物（Cp 2 TiCl 2）和在THF中的活化锌粉原位制备氯化钛新茂（III）。

  DOI：

  10.1016/j.tetlet.2005.12.131

文献信息

• Titanocene(III) mediated radical cyclizations of epoxides for the synthesis of medium-sized cyclic ethers
  作者：Samir Kumar Mandal、Subhas Chandra Roy

  DOI：10.1016/j.tet.2007.08.072

  日期：2007.11

  Titanocene(III) chloride (Cp2TiCl) mediated 7-exo and 8-endo radical cyclizations of epoxides towards the synthesis of 7- and 8-membered cyclic ethers have been described. Titanocene(III) chloride was prepared in situ from commercially available titanocene dichloride (Cp2TiCl2) and activated zinc dust in THF.

  已经描述了二茂钛（III）氯化物（Cp 2 TiCl）介导的环氧化物对7-和8-元环醚的合成的7-外和8-内基自由基环化。由市售的二茂钛二氯化物（Cp 2 TiCl 2）和在THF中的活化锌粉原位制备氯化钛新茂（III）。
• Motor fuel additive composition and method for preparation thereof
  申请人：——

  公开号：US20020023383A1

  公开（公告）日：2002-02-28

  A motor fuel additive composition comprises a mixture of: (a) from about 5 to about 50 weight percent, based upon the total weight of the additive, of a detergent component selected from the group consisting of (i) a reaction product of a substituted hydrocarbon and an amino compound, and (ii) a polybutylamine or polyisobutylamine; and (b) a fuel conditioner component comprising (i) from about 2 to about 50 weight percent, based upon the total weight of the additive, of a polar oxygenated hydrocarbon compound and (ii) from about 2 to about 50 weight percent, based upon the total weight of the additive, of an oxygenated compatibilizing agent. The fuel conditioner component may additionally comprise a hydrophilic separant, an aromatic hydrocarbon, or mixtures thereof. Additionally, in some cases the hydrophilic separant may also act as the compatibilizing agent. The additive may also additionally comprise a carrier oil or fluidizer. The additive is prepared by mixing together the detergent and fuel conditioner components, and is advantageous in that the detergent and fuel conditioner components synergistically interact to reduce both fuel intake system deposit formation and combustion chamber deposit formation, thereby inhibiting engine ORI.

  一种汽车燃料添加剂组合物包括以下物质的混合物(a) 以添加剂总重量为基准，约 5%至约 50%的去污剂组分，该组分选自以下 组别：(i) 取代的碳氢化合物和氨基化合物的反应产物；(ii) 聚丁胺或 聚异丁胺；(b) 燃料调节剂组分，包括：(i) 极性含氧烃化合物，占添加剂总重量的约 2%至约 50%；(ii) 含氧相容剂，占添加剂总重量的约 2%至约 50%。燃料调节剂组分还可包括亲水分离剂、芳香烃或它们的混合物。此外，在某些情况下，亲水分离剂也可用作相容剂。添加剂还可额外包含一种载体油或流化剂。添加剂是通过将清洁剂和燃油改良剂成分混合在一起制备而成的，其优点在于清洁剂和燃油改良剂成分可协同作用，减少燃油进气系统沉积物的形成和燃烧室沉积物的形成，从而抑制发动机ORI。
• BIODIESEL MOTOR FULE ADDITIVE COMPOSITION
  申请人：Nelson L. Otis

  公开号：US20050268535A1

  公开（公告）日：2005-12-08

  Disclosed is a biodiesel fuel additive composition which accelerates combustion phenomenon, reduces ignition delay, and improves Cetane number, thereby lowering particulate emissions, and improving fuel economy in diesel engines.

  本发明公开了一种生物柴油燃料添加剂组合物，它能加速燃烧现象，减少点火延迟，提高十六烷值，从而降低微粒排放，改善柴油发动机的燃油经济性。
• EP0518966A4
  申请人：——

  公开号：EP0518966A4

  公开（公告）日：1993-03-10
• MOTOR FUEL ADDITIVE COMPOSITION AND METHOD FOR PREPARATION THEREOF
  申请人：POLAR MOLECULAR CORPORATION

  公开号：EP0518966B1

  公开（公告）日：1995-12-27