5,11-dimethylindolo<3,2-b>-carbazole | 56525-80-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 5,11-dimethylindolo<3,2-b>-carbazole
• 英文别名: 5,11-Dimethylindolo<3,2-b>carbazole；N,N'-dimethylindolo<3,2-b>carbazole；5N,11N-dimethylindolo[3,2-b]carbazole；5,11-dimethylindolo[3,2-b]carbazole；5,11-dimethyl-5,11-dihydro-indolo[3,2-b]carbazole；N,N'-Dimethyl-5,11-dihydroindolo<3,2-b>carbazol；Indolo(3,2-b)carbazole, 5,11-dihydro-5,11-dimethyl-
• CAS: 56525-80-5
• 化学式: C₂₀H₁₆N₂
• 分子量: 284.36
• InChiKey: SOLMYUFYEJBNPZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  22
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  9-甲基咔唑-3-胺 在 氢氧化钾 、 air 、 铜 、 sodium cyanoborohydride 、 potassium carbonate 作用下， 以 吡啶 、 乙醚 、 溶剂黄146 、 乙腈 为溶剂， 反应 43.0h， 生成 5,11-dimethylindolo<3,2-b>-carbazole
  参考文献：
  名称：

  An Expedient Synthesis of 5,11-Dimethylindolo[3,2-b]-carbazole, A Potent Ligand for the Receptor for TCDD

  摘要：

  A new and efficient synthesis has been developed for the title indolocarbazole which has been indicated by a recent computer-aided study to be a potent ligand for the receptor for the naturally occurring carcinogen, TCDD.

  DOI：

  10.1080/00397919608004606

文献信息

• PYRIDYL CARBENE PHOSPHORESCENT EMITTERS
  申请人：Wu Yonggang

  公开号：US20120228583A1

  公开（公告）日：2012-09-13

  Organometallic compounds comprising an imidazole carbene ligand having a N-containing ring fused to the imidazole ring are provided. In particular, the N-containing ring fused to the imidazole ring may contain one nitrogen atom or more than one nitrogen atom. These compounds may demonstrate high photoluminescent (PL) efficiency, Gaussian emission spectra, and/or short excited state lifetimes. These materials may be especially useful as blue phosphorescent emitters.

  提供了包含咪唑卡宾配体的有机金属化合物，其中该配体具有与咪唑环融合的含氮环。具体来说，与咪唑环融合的含氮环可能包含一个或多个氮原子。这些化合物可能表现出高光致发光（PL）效率、高斯发射光谱和/或短激发态寿命。这些材料可能特别适用作为蓝色磷光发射体。
• GERMANIUM-CONTAINING RED EMITTER MATERIALS FOR ORGANIC LIGHT EMITTING DIODE
  申请人：Ma Bin

  公开号：US20120217868A1

  公开（公告）日：2012-08-30

  Organometallic compounds comprising a germanium-containing substituent are provided. The compounds may be used in organic light emitting devices to provide improved device efficiency, line shape and lifetime. In particular, the compounds comprise a phenylquinoline or phenylisoquinoline ligand having a germanium-containing substituent on the quinoline or isoquinoline portion of the ligand. These compounds may be advantageously used as red emitters in the emissive layer of organic light emitting devices.

  提供了含有锗取代基的有机金属化合物。这些化合物可用于有机发光器件，以提高器件效率、线形和寿命。具体来说，这些化合物包括在配体的喹啉或异喹啉部分上具有含锗取代基的苯基喹啉或苯基异喹啉配体。这些化合物可优势地用作有机发光器件发射层中的红色发射体。
• [EN] ELECTROCHEMICAL ENERGY STORAGE DEVICES<br/>[FR] DISPOSITIFS ÉLECTROCHIMIQUES DE STOCKAGE D'ÉNERGIE
  申请人：GENTEX CORP

  公开号：WO2015183821A1

  公开（公告）日：2015-12-03

  An energy storage device includes a cathodic material in an activated state; and an anodic material in an activated state; wherein: the cathodic material is a viologen covalently attached to, or confined within, a first polymer matrix, the first polymer matrix is configured to prevent or minimize substantial diffusion of the cathodic material in the activated state; and the anodic material is a phenazine, a phenothiazine, a triphenodithiazine, a carbazole, a indolocarbazole, a biscarbazole, or a ferrocene covalently attached to, or confined within, a second polymer matrix, the second polymer matrix is configured to prevent or minimize substantial diffusion of the anodic material in the activated state.

  一种储能装置包括处于激活状态的阴极材料；以及处于激活状态的阳极材料；其中：阴极材料是共价连接到第一聚合物基体内或被限制在其中的一种紫罗兰类物质，第一聚合物基体被配置为防止或最小化阴极材料在激活状态下的大量扩散；阳极材料是苯并噻吩、苯并噻唑、三苯并二噻吩、咔唑、吲哚咔唑、双咔唑或二茂铁等共价连接到第二聚合物基体内或被限制在其中的一种物质，第二聚合物基体被配置为防止或最小化阳极材料在激活状态下的大量扩散。
• Composition of matter for use in organic light-emitting diodes
  申请人：Kyulux North America, Inc.

  公开号：US10892425B1

  公开（公告）日：2021-01-12

  The present disclosure relates to compounds of formula (I) or formula (II) as compounds capable of emitting delayed fluorescence and uses of these compounds in organic light-emitting diodes.

  本公开涉及公式(I)或公式(II)的化合物，这些化合物能够发出延迟荧光，并且在有机发光二极管中使用这些化合物。
• [EN] NOVEL SPIROBENZOSUBERANE COMPOUNDS FOR USE IN ORGANIC ELECTRONIC DEVICES<br/>[FR] NOUVEAUX COMPOSÉS DE SPIROBENZOSUBERANE DESTINÉS À ÊTRE UTILISÉS DANS DES DISPOSITIFS ÉLECTRONIQUES ORGANIQUES
  申请人：SOLVAY

  公开号：WO2016102414A1

  公开（公告）日：2016-06-30

  Compounds of formula (1) wherein U, V, W and X, which may be the same or different at each occurrence, represent a substituent group selected from (2), (3), (4) wherein Z is N or P, Y is CR5R6, NR7, SiR8R9, PR10, P(=O)R11 or BR12.

  式（1）中的化合物，其中U、V、W和X分别代表从（2）、（3）、（4）中选择的取代基团，其中Z为N或P，Y为CR5R6、NR7、SiR8R9、PR10、P(=O)R11或BR12。