di-tertiary butyl phenyl phosphite | 110107-26-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: di-tertiary butyl phenyl phosphite
• 英文别名: Ditert-butyl phenyl phosphite
• CAS: 110107-26-1
• 化学式: C₁₄H₂₃O₃P
• 分子量: 270.309
• InChiKey: OMXUTLPVJWERPA-UHFFFAOYSA-N

物化性质

• 沸点：
  280.7±13.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  di-tertiary butyl phenyl phosphite 在 双氧水 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 以2.51 g的产率得到di-t-butyl phenyl phosphate
  参考文献：
  名称：

  Phosphonate-free phosphorylation of alcohols using bis-(tert-butyl) phosphoramidite with imidazole·hydrochloride and imidazole as the activator

  摘要：

  A variety of commercially available alcohols were converted to their bis-(tert-butyl) protected monophosphate pro-drugs. The improved procedure uses the unique combination of imidazole center dot hydrochloride and imidazole as the activator to suppress the formation of undesired phosphonate by-product frequently encountered with the bis-(tert-butyl) phosphoramidite reagents. The new activation procedure eliminates the need to use excess reagents. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.05.020
• 作为产物：
  描述：

  N,N-二异丙基亚磷酰胺二叔丁酯 、 苯酚 在 咪唑 、 咪唑盐酸盐 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 1.0h， 生成 di-tertiary butyl phenyl phosphite
  参考文献：
  名称：

  Phosphonate-free phosphorylation of alcohols using bis-(tert-butyl) phosphoramidite with imidazole·hydrochloride and imidazole as the activator

  摘要：

  A variety of commercially available alcohols were converted to their bis-(tert-butyl) protected monophosphate pro-drugs. The improved procedure uses the unique combination of imidazole center dot hydrochloride and imidazole as the activator to suppress the formation of undesired phosphonate by-product frequently encountered with the bis-(tert-butyl) phosphoramidite reagents. The new activation procedure eliminates the need to use excess reagents. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.05.020

文献信息

• FRICTION-CONTROLLING COMPOUND, AND FRICTION-CONTROLLING COMPOSITION CONTAINING SAID FRICTION-CONTROLLING COMPOUND
  申请人：Adeka Corporation

  公开号：EP3722395A1

  公开（公告）日：2020-10-14

  A friction inhibiting compound of the present invention is a friction inhibiting compound including a copolymer (A) that includes a polymerizable monomer (a) and a polymerizable monomer (b) as constituent monomers, wherein the polymerizable monomer (a) includes a specific alkyl acrylate or alkyl methacrylate, the polymerizable monomer(b) is at least one selected from the group consisting of specific hydroxyalkyl acrylates and hydroxyalkyl methacrylates; specific alkyl acrylates and alkyl methacrylates; and aromatic vinyl monomers having 8 to 14 carbon atoms, and a composition ratio of the polymerizable monomer (a) and polymerizable monomer(b) in the copolymer (A), represented by (a):(b), is (10 to 45):(55 to 90) in a molar ratio (provided that a total molar ratio of (a) and (b) is 100), and the weight average molecular weight of the copolymer (A) is 1,000 to 500,000.

  本发明的一种摩擦抑制化合物是包括共聚物（A）的摩擦抑制化合物，共聚物（A）包括作为组成单体的可聚合单体（a）和可聚合单体（b），其中可聚合单体（a）包括特定的丙烯酸烷基酯或甲基丙烯酸烷基酯，可聚合单体（b）是至少选自特定的丙烯酸羟烷基酯和甲基丙烯酸羟烷基酯组成的组中的一种；可聚合单体(a)和可聚合单体(b)在共聚物(A)中的组成比例为(a)：(b) 的摩尔比为 (10 至 45)：(55 至 90)（前提是 (a) 和 (b) 的总摩尔比为 100），共聚物 (A) 的重量平均分子量为 1,000 至 500,000。
• Schwetlick, Klaus; Koenig, Thomas; Rueger, Claus, Zeitschrift fur Chemie, 1986, vol. 26, # 10, p. 360 - 366
  作者：Schwetlick, Klaus、Koenig, Thomas、Rueger, Claus、Pionteck, Juergen

  DOI：——

  日期：——
• SCHWETLICK, KLAUS;KONIG, THOMAS;RUGER, CLAUS;PIONTECK, JURGEN, Z. CHEM., 26,(1986) N 10, 360-366
  作者：SCHWETLICK, KLAUS、KONIG, THOMAS、RUGER, CLAUS、PIONTECK, JURGEN

  DOI：——

  日期：——
• Thermowelded artikels based on polyolefin fibres
  申请人：MONTELL NORTH AMERICA INC.

  公开号：EP0391438B1

  公开（公告）日：1998-02-18
• POLYETHERIMIDE COMPOSITION, METHOD, AND ARTICLE
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP1478694A1

  公开（公告）日：2004-11-24