methyl ethyl ketone peroxide | 2780-59-8

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: methyl ethyl ketone peroxide
• 英文别名: Butanone peroxide；3,6-diethyl-3,6-dimethyl-[1,2,4,5]tetroxane；ethyl methyl ketone peroxide cyclic dimer；dimeric cyclic MEKP；Ethyl-methylketon-peroxid；3,6-Diethyl-3,6-dimethyl-1,2,4,5-tetroxane；3,6-diethyl-3,6-dimethyl-1,2,4,5-tetraoxane
• CAS: 2780-59-8
• 化学式: C₈H₁₆O₄
• 分子量: 176.213
• InChiKey: DYDYIBSLXXUTQU-UHFFFAOYSA-N

物化性质

• 保留指数：
  1046.9;1057.8;1059.4;1063.3;1072.8;1080.8;1085.6

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2934999090

反应信息

• 作为产物：
  描述：

  丁酮 在 硝酸 双氧水 作用下， 以 异十二烷 、 水 、 溶剂黄146 为溶剂， 反应 1.0h， 生成 3,6,9-三乙基-3,6,9-三甲基-1,4,7-三过氧壬烷 、 methyl ethyl ketone peroxide
  参考文献：
  名称：

  [DE] VERFAHREN ZUR HERSTELLUNG VON LÖSUNGEN VON TRIMEREN KETON-PEROXIDEN
  [EN] METHOD FOR THE PRODUCTION OF TRIMERIC KETONE PEROXIDE SOLUTIONS
  [FR] PROCEDE DE PRODUCTION DE SOLUTIONS DE PEROXYDES DE CETONE TRIMERES

  摘要：

  使用硝酸作为催化剂，在适当的溶剂中，将环己酮和过氧化氢反应，制备三聚环己酮过氧化物。

  公开号：

  WO2004076405A1

文献信息

• [EN] CYCLIC KETONE PEROXIDE COMPOSITION<br/>[FR] COMPOSITION DE PEROXYDE DE CÉTONE CYCLIQUE
  申请人：AKZO NOBEL CHEMICALS INT BV

  公开号：WO2015135865A1

  公开（公告）日：2015-09-17

  A composition comprising at least two trimeric cyclic ketone peroxides: a trimeric cyclic methyl ethyl ketone peroxide (3MEK-cp) of formula (I) and at least one peroxide satisfying formula (II) wherein R1 through R3 are independently selected from alkyl and alkoxyalkyl groups, said groups having 2 to 5 carbon atoms, the total number of carbon plus oxygen atoms of R1+R2+R3 is in the range 7-15, and the molar ratio of 3MEK-cp to the total amount of peroxides satisfying formula (II) being in the range of from 10:90 to 80:20.

  一种组合物，包括至少两种三聚环状酮过氧化物：具有式（I）的三聚环状甲基乙基酮过氧化物（3MEK-cp）和至少一种符合式（II）的过氧化物，其中R1至R3分别选自烷基和烷氧基烷基基团，所述基团具有2至5个碳原子，R1+R2+R3的碳加氧原子的总数在7-15范围内，3MEK-cp与符合式（II）的过氧化物总量的摩尔比在10:90至80:20范围内。
• CONJUGATED DIENE POLYMER AND METHOD FOR PRODUCING SAME
  申请人：Bando Fumiaki

  公开号：US20140350201A1

  公开（公告）日：2014-11-27

  Conjugated diene polymer comprising at least a conjugated diene monomer unit, the conjugated diene polymer has a number-average molecular weight (Mn) in terms of polystyrene of 1,000 to 1,000,000, a ratio (Mw/Mn) of a weight-average molecular weight (Mw) to the number-average molecular weight (Mn) of lower than 2.0 and the polymer bears a halogen atom at a terminal of the polymer chain. Method for producing the conjugated diene polymer comprises subjecting a monomer containing at least a conjugated diene to living radical polymerization using a polymerization initiator comprising a halogenocyclopentadienyl triorganophosphine η 2 -olefin ruthenium complex represented by formula (6) (and an organic halide.

  共轭二烯聚合物包括至少一个共轭二烯单体单元，该共轭二烯聚合物的聚合度数平均分子量（Mn）以聚苯乙烯为单位为1,000至1,000,000，重均分子量（Mw）与数均分子量（Mn）之比小于2.0，并且该聚合物在聚合物链的末端带有卤素原子。制备该共轭二烯聚合物的方法包括使用聚合引发剂将至少含有一个共轭二烯的单体进行活性自由基聚合，所述聚合引发剂包括一个卤代环戊二烯基三有机膦η2-烯烃钌配合物，其化学式为（6）（和一个有机卤化物）。
• Composition forming artificial marble or granite
  申请人：Great Lakes Chemical (Europe) GmbH

  公开号：EP1149809A1

  公开（公告）日：2001-10-31

  Composition forming artificial marble or granite, comprising: (A) a liquid and polymerizable poly(allyl carbonate) of a polyol or a mixture of polyols, as organic ligand; and (B) a mineral filler of a carbonate nature in the case of marble, or of a silicate or silica nature in the case of granite; characterized in that the polymerization of the poly(allyl carbonate) (A) is carried out in the presence of a peroxide polymerization initiator belonging to the group of perketals (C).

  形成人造大理石或花岗岩的组合物，包括 (A) 作为有机配体的多元醇或多元醇混合物的液态可聚合聚（碳酸烯丙酯）；以及 (B) 一种矿物填料，大理石为碳酸盐性质，花岗岩为硅酸盐或二氧化硅性质； 其特征在于聚（碳酸烯丙酯）（A）的聚合是在过氧化物聚合引发剂（C）的存在下进行的。
• CURABLE RESIN COMPOSITION, MOLDED BODY USING THE SAME, PREPREG AND LAMINATE
  申请人：Zeon Corporation

  公开号：EP2256164A1

  公开（公告）日：2010-12-01

  There is provided a curable resin composition comprising a cycloolefin polymer and a cyclic peroxide which has a cyclic structure and a peroxy structure in the cyclic structure. There is also provided a laminate obtained by using a molded article which is obtained by forming the curable resin composition into a sheet shape or a prepreg which is obtained by impregnating the curable resin composition into a reinforcing fiber.

  本发明提供了一种可固化树脂组合物，它由环烯烃聚合物和环状过氧化物组成，环状过氧化物具有环状结构和环状结构中的过氧结构。本发明还提供了一种层压板，该层压板通过使用将可固化树脂组合物制成片状的模制件或将可固化树脂组合物浸渍到增强纤维中的预浸料获得。
• POLYMERIZABLE COMPOSITION, CROSS-LINKABLE MOLDED OBJECT, CROSSLINKED MOLDED OBJECT, AND CROSSLINKED MOLDED OBJECT COMPOSITE BODY
  申请人：Zeon Corporation

  公开号：EP2343340A1

  公开（公告）日：2011-07-13

  A polymerizable composition which contains a cycloolefin monomer, metathesis polymerization catalyst, cross-linking agent, and carbon fiber which is brought into contact in advance with a sizing agent which includes a compound having an unsaturated terminal group and a polar group, a cross-linkable shaped article obtained by porimerizing the polymerizable composition, a cross-linked shaped article obtained by cross-linking the cross-linkable shaped article, and a cross-linked shaped article composite which contains the cross-linked shaped article and other members.

  一种含有环烯烃单体、偏聚合催化剂、交联剂和碳纤维的可聚合组合物，该组合物预先与上浆剂接触，上浆剂包括具有不饱和末端基团和极性基团的化合物；一种通过使该可聚合组合物聚孔而得到的可交联异型制品；一种通过使该可交联异型制品交联而得到的交联异型制品；以及一种包含该交联异型制品和其他构件的交联异型制品复合材料。