4-(4-[1,1'-biphenyl]-4-yl-1H-1,2,3-triazol-1-yl)-N,N-dihexylbenzenamine | 1254468-04-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(4-[1,1'-biphenyl]-4-yl-1H-1,2,3-triazol-1-yl)-N,N-dihexylbenzenamine
• 英文别名: N,N-dihexyl-4-[4-(4-phenylphenyl)triazol-1-yl]aniline
• CAS: 1254468-04-6
• 化学式: C₃₂H₄₀N₄
• 分子量: 480.696
• InChiKey: ACPKDKJZEGGDDH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.4
• 重原子数：
  36
• 可旋转键数：
  14
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  34
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-azido-N,N-dihexylbenzenamine 、 4-乙炔联苯 在 copper(l) iodide 、 N,N-二异丙基乙胺 作用下， 以 四氢呋喃 为溶剂， 以86%的产率得到4-(4-[1,1'-biphenyl]-4-yl-1H-1,2,3-triazol-1-yl)-N,N-dihexylbenzenamine
  参考文献：
  名称：

  基于三唑的推挽系统中的快速光处理

  摘要：

  Electron donor–acceptor compounds 1 (asymmetrical push–pull derivative) and 2 (symmetrical push–pull–push derivative) were studied in which one (push–pull) or two aniline units (push–pull–push) are connected to a biphenyl group via triazole linkers, made by “click” chemistry. Steady-state and time-resolved spectroscopies indicate that highly dipolar charge separated excited states are populated in

  DOI：

  10.1039/b921322h

文献信息

• Fast photo-processes in triazole-based push–pull systems
  作者：Peter D. Zoon、Ivo H. M. van Stokkum、Manuel Parent、Olivier Mongin、Mireille Blanchard-Desce、Albert M. Brouwer

  DOI：10.1039/b921322h

  日期：——

  Electron donor–acceptor compounds 1 (asymmetrical push–pull derivative) and 2 (symmetrical push–pull–push derivative) were studied in which one (push–pull) or two aniline units (push–pull–push) are connected to a biphenyl group via triazole linkers, made by “click” chemistry. Steady-state and time-resolved spectroscopies indicate that highly dipolar charge separated excited states are populated in

  Electron donor–acceptor compounds 1 (asymmetrical push–pull derivative) and 2 (symmetrical push–pull–push derivative) were studied in which one (push–pull) or two aniline units (push–pull–push) are connected to a biphenyl group via triazole linkers, made by “click” chemistry. Steady-state and time-resolved spectroscopies indicate that highly dipolar charge separated excited states are populated in