3-fluorophenanthrene-9,10-dione | 723-88-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 3-fluorophenanthrene-9,10-dione
• 英文别名: 3-fluoro-9,10-phenanthrenequinone；3-Fluor-9,10-phenanthrenchinon
• CAS: 723-88-6
• 化学式: C₁₄H₇FO₂
• 分子量: 226.207
• InChiKey: SOVJULMFBMIJDR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-fluorophenanthrene-9,10-dione 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 9.5h， 生成 3-(18-Phenyl-9-oxa-18,27-diazaheptacyclo[18.7.0.02,10.03,8.011,19.012,17.021,26]heptacosa-1,3,5,7,10,12,14,16,19,21,23,25-dodecaen-27-yl)phenanthrene-9,10-dicarbonitrile
  参考文献：
  名称：

  WO2023/42814

  摘要：

  公开号：
• 作为产物：
  描述：

  3-氟菲 在 chromium(VI) oxide 作用下， 以 溶剂黄146 为溶剂， 生成 3-fluorophenanthrene-9,10-dione
  参考文献：
  名称：

  Photochemistry of Stilbenes. IV. The Preparation of Substituted Phenanthrenes^1a-c

  摘要：

  DOI：

  10.1021/jo01034a059

文献信息

• PHENANTHRENEQUINONE COMPOUND, ELECTRODE ACTIVE MATERIAL, AND POWER STORAGE DEVICE
  申请人：Ohtsuka Yu

  公开号：US20100047688A1

  公开（公告）日：2010-02-25

  Disclosed is a novel organic compound synthesized by oligomerizing or polymerizing a specific quinone compound having two quinone groups at the ortho position and having a property such that the electron transfer occurs associated with a reversible redox reaction, the organic compound being insoluble in an organic solvent and having a high energy density, and thus being useful as an electrode active material for a power storage device. Using this organic compound as an electrode active material can improve the energy density, reduce the weight and size, and improve the functionality of the power storage device.

  揭示了一种新型有机化合物，通过寡聚或聚合具有两个醌基团位于邻位的特定醌化合物合成，具有电子转移伴随可逆氧化还原反应发生的性质，该有机化合物在有机溶剂中不溶解且具有高能量密度，因此可用作储能装置的电极活性材料。将这种有机化合物用作电极活性材料可以提高能量密度，减轻重量和体积，并改善储能装置的功能性。
• Suzuki cross coupling followed by cross dehydrogenative coupling: An efficient one pot synthesis of Phenanthrenequinones and analogues
  作者：Pompy Sarkar、Atiur Ahmed、Jayanta K. Ray

  DOI：10.1016/j.tetlet.2020.151701

  日期：2020.3

  An efficient one pot protocol has been developed towards the synthesis of substituted phenanthrenequinone and analogous derivatives via Suzuki cross coupling followed by copper catalyzed cross dehydrogenative coupling.

  已经开发出一种有效的一锅法，用于通过铃木（Suzuki）交叉偶联然后铜催化的交叉脱氢偶联来合成取代的菲醌和类似衍生物。
• PHENANTHRENEQUINONE COMPOUND, ELECTRODE ACTIVE MATERIAL, AND ELECTRICAL STORAGE DEVICE
  申请人：Panasonic Corporation

  公开号：EP2128121A1

  公开（公告）日：2009-12-02

  Disclosed is a novel organic compound synthesized by oligomerizing or polymerizing a specific quinone compound having two quinone groups at the ortho position and having a property such that the electron transfer occurs associated with a reversible redox reaction, the organic compound being insoluble in an organic solvent and having a high energy density, and thus being useful as an electrode active material for a power storage device. Using this organic compound as an electrode active material can improve the energy density, reduce the weight and size, and improve the functionality of the power storage device.

  本发明公开了一种新型有机化合物，该化合物是通过低聚或聚合一种特定的醌化合物合成的，该醌化合物在正交位置上具有两个醌基团，并且具有与可逆氧化还原反应相关的电子转移特性，该有机化合物不溶于有机溶剂，具有较高的能量密度，因此可用作功率存储设备的电极活性材料。使用这种有机化合物作为电极活性材料可以提高能量密度，减轻重量和尺寸，并改善功率存储设备的功能。
• ELECTRODE ACTIVE MATERIAL COMPRISING A PHENANTHRENEQUINONE COMPOUND AND ELECTRICAL STORAGE DEVICE INCLUDING THE SAME
  申请人：Panasonic Corporation

  公开号：EP2128121B1

  公开（公告）日：2013-09-11
• US8338027B2
  申请人：——

  公开号：US8338027B2

  公开（公告）日：2012-12-25