1,1'-bicyclododecanol | 79101-60-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,1'-bicyclododecanol
• 英文别名: 1,1-bicyclododecanol；1-(1-Hydroxycyclododecyl)cyclododecan-1-ol
• CAS: 79101-60-3
• 化学式: C₂₄H₄₆O₂
• 分子量: 366.628
• InChiKey: DZODXXJZEWCMQY-UHFFFAOYSA-N

物化性质

• 熔点：
  156.5-157.5 °C(Solv: hexane (110-54-3))
• 沸点：
  486.9±18.0 °C(Predicted)
• 密度：
  0.939±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  26
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  环十二酮 在 甲醇 作用下， 反应 4.0h， 以84%的产率得到1,1'-bicyclododecanol
  参考文献：
  名称：

  Novel self-coupling reaction of cyclic ketones under a high-pressure mercury lamp

  摘要：

  A novel self-coupling reaction in alcohol or hexane-water of cycloalkanone (cycloheptanone, cyclooctanone, and cyclododecanone) with irradiation under a high-pressure mercury lamp yielded the corresponding pinacol-type compound in good yields. In the case of cyclohexanone, 2-methyl-, 2-phenyl-, 4-methylcyclohexanone, 5 alpha- and 5 beta-cholestan-3-one, the pinacol derivatives were not obtained and the dimethyl acetals were given. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)01357-x

文献信息

• Isolation of a diazoalkane intermediate in the photic Bamford-Stevens reaction
  作者：Alex Nickon、Pamela St. John Zurer

  DOI：10.1021/jo00336a012

  日期：1981.11
• NICKON, A.;ZURER, P. ST. J., J. ORG. CHEM., 1981, 46, N 23, 4685-4694
  作者：NICKON, A.、ZURER, P. ST. J.

  DOI：——

  日期：——
• Novel self-coupling reaction of cyclic ketones under a high-pressure mercury lamp
  作者：Shun-Jun Ji、Masatoshi Matsushita、T.Tomoyoshi Takahashi、C.Akira Horiuchi

  DOI：10.1016/s0040-4039(99)01357-x

  日期：1999.9

  A novel self-coupling reaction in alcohol or hexane-water of cycloalkanone (cycloheptanone, cyclooctanone, and cyclododecanone) with irradiation under a high-pressure mercury lamp yielded the corresponding pinacol-type compound in good yields. In the case of cyclohexanone, 2-methyl-, 2-phenyl-, 4-methylcyclohexanone, 5 alpha- and 5 beta-cholestan-3-one, the pinacol derivatives were not obtained and the dimethyl acetals were given. (C) 1999 Elsevier Science Ltd. All rights reserved.