1,2-bis-hydroxymethyl-decahydro-naphthalene | 105339-60-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,2-bis-hydroxymethyl-decahydro-naphthalene
• 英文别名: 1,2-Bis-hydroxymethyl-decahydro-naphthalin；[1-(Hydroxymethyl)-1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalen-2-yl]methanol
• CAS: 105339-60-4
• 化学式: C₁₂H₂₂O₂
• 分子量: 198.305
• InChiKey: SJRKQULCVXUEOB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,2-diethoxycarbonyl-3,4-dihydronaphthalene 在 lithium aluminium tetrahydride 、 kieselguhr 、 乙醚 、 乙醇 、 镍 作用下， 200.0 ℃ 、23.53 MPa 条件下， 生成 1,2-bis-hydroxymethyl-decahydro-naphthalene
  参考文献：
  名称：

  Cyclic Dienes. XXIV. 1,2-Dimethylenedecalin¹

  摘要：

  DOI：

  10.1021/ja01530a019

文献信息

• Compound having silsesquioxane skeleton and its polymer
  申请人：Inagaki Jyun-ichi

  公开号：US20050009982A1

  公开（公告）日：2005-01-13

  The present invention relates to a compound represented by Formula (1) and a polymer obtained using the compound: wherein R 1 is phenyl which may have substituents, Q 1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, and Q 2 is a group represented by Formula (2) wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, A 1 to A 4 are independently a single bond, 1,4-cyclohexylene, 1,4-cyclohexenylene, a condensed ring group having 6 to 10 carbon atoms which is a divalent group, or 1,4-phenylene, Z 0 to Z 3 are independently a single bond, —CH═CR—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms, and Z 4 is a single bond, —CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms. And Y 1 in Formula (1) is the group defined in Claim 1.

  本发明涉及一种由式（1）表示的化合物和使用该化合物获得的聚合物：其中R1是苯基，可能具有取代基；Q1是氢、卤素、具有1至10个碳原子的烷基、环丙基、环丁基、环戊基、环己基、环己烯基或苯基，其中可选的氢原子可被卤素或具有1至5个碳原子的烷基取代；Q2是由式（2）表示的基团，其中代码<表示与硅的连接点，l、m、n和p独立地为0、1、2或3，A1至A4独立地为单键、1,4-环己亚基、1,4-环己烯亚基、具有6至10个碳原子的缩合环基团，为二价基团，或1,4-苯亚基，Z0至Z3独立地为单键、—CH═CR—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基，Z4为单键、—CH═CH—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基。式（1）中的Y1是权利要求1中定义的基团。
• METHOD FOR PRODUCING DIOL HAVING CYCLIC ACETAL SKELETON
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：US20190055259A1

  公开（公告）日：2019-02-21

  The present invention provides a method for producing a diol having a cyclic acetal skeleton, in which the method include an acetalization reaction step of obtaining a diol having a cyclic acetal skeleton by subjecting raw material hydroxypivalaldehyde and at least pentaerythritol and/or trimethylolpropane to an acetalization reaction under an acid catalyst and the raw material hydroxypivalaldehyde can contain a prescribed amount of at least one impurity selected from the group consisting of formaldehyde, neopentyl glycol, an ester compound having a neopentyl glycol skeleton represented by formula (III), and isobutyraldehyde.

  本发明提供了一种制备具有环状缩醛骨架的二元醇的方法，其中该方法包括通过在酸催化剂下使原料羟基皮瓦醛和至少戊三醇和/或三羟甲基丙烷发生缩醛化反应的步骤来获得具有环状缩醛骨架的二元醇，且原料羟基皮瓦醛可以含有来自由甲醛、新戊二醇、由式（III）所表示的新戊二醇骨架的酯化合物和异丁醛所选群组中至少一种杂质的预定量。
• Verification of translation
  申请人：Inagaki Jyun-ichi

  公开号：US20070190344A1

  公开（公告）日：2007-08-16

  A compound represented by Formula (1) and a polymer obtained using the compound: wherein R 1 is phenyl which may have substituents, Q 1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, Q 2 is a group represented by Formula (2): wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, and A 1 to A 4 , Z 0 to Z 4 and Y 1 are defined in the specification.

  公式（1）所表示的化合物和使用该化合物制得的聚合物：其中R1是苯基，可以有取代基；Q1是氢、卤素、具有1至10个碳原子的烷基、环丙基、环丁基、环戊基、环己烯基或苯基，其中可选氢原子可以被卤素或具有1至5个碳原子的烷基所取代；Q2是由公式（2）表示的基团：其中代码<表示与硅的连接点，l、m、n和p独立地为0、1、2或3，A1至A4、Z0至Z4和Y1在规范中有定义。
• COMPOUND HAVING SILSESQUIOXANE SKELETON AND ITS POLYMER
  申请人：INAGAKI Jyun-ichi

  公开号：US20120178894A1

  公开（公告）日：2012-07-12

  The present invention relates to a compound represented by Formula (1) and a polymer obtained using the compound: wherein R 1 is phenyl which may have substituents, Q 1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, <—Z 0 A 1 -Z 1  l A 2 -Z 2  m A 3 -Z 3  n A 4  p -Z 4 —  (2) and Q 2 is a group represented by Formula (2): wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, A 1 to A 4 are independently a single bond, 1,4-cyclohexylene, 1,4-cyclohexenylene, a condensed ring group having 6 to 10 carbon atoms which is a divalent group, or 1,4-phenylene, Z 0 to Z 3 are independently a single bond, CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms, and Z 4 is a single bond, —CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms. And Y 1 in Formula (1) is the group defined in claim 1.

  本发明涉及一种由公式（1）表示的化合物以及使用该化合物获得的聚合物：其中R1是苯基，可以具有取代基，Q1是氢、卤素、1至10个碳原子的烷基、环丙基、环丁基、环戊基、环己烯基或苯基，其中可选的氢原子可以被卤素或1至5个碳原子的烷基所取代，<—Z0A1-Z1lA2-Z2mA3-Z3nA4p-Z4—（2）和Q2是由公式（2）表示的基团：其中代码<表示与硅的连接点，l、m、n和p独立地为0、1、2或3，A1至A4独立地为单键、1,4-环己基、1,4-环己烯基、具有6至10个碳原子的紧凑环基团，或1,4-苯基，Z0至Z3独立地为单键、CH═CH—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基，Z4为单键、—CH═CH—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基。公式（1）中的Y1是权利要求1中定义的基团。
• ADVANCED POLY EPOXY ESTER RESIN COMPOSITIONS
  申请人：Jin Xin

  公开号：US20130178591A1

  公开（公告）日：2013-07-11

  A poly epoxy ester resin composition of the following chemical structure: where n is a number from 2 to about 3000; each m independently has a value of 0 or 1; each R 0 is independently —H or —CH 3 ; each R 1 is independently —H or a C 1 to C 6 alkylene radical (saturated divalent aliphatic hydrocarbon radical), Ar is a divalent aryl group or heteroarylene group;_and X is cycloalkylene group, including substituted cycloalkylene group, where the substitute group include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substitute group, for example, a halogen, a nitro, a blocked isocyanate, or an alkyloxy group; the combination of cycloalkylene and alkylene groups and the combination of alkylene and cycloalkylene group with a bridging moiety in between.

  以下是化学结构式为的聚合物环氧酯树脂组成：其中n为2至约3000的数字；每个m独立地具有值为0或1；每个R0独立地为—H或—CH3；每个R1独立地为—H或C1到C6的烷基基团（饱和二价脂肪族碳氢基团），Ar为二价芳基基团或杂芳基基团；X为环烷基团，包括取代环烷基团，其中取代基团包括烷基、环烷基、芳基或芳基烷基团或其他取代基团，例如卤素、硝基、阻塞异氰酸酯或烷氧基团；环烷基和烷基团的组合以及烷基和环烷基团之间带有桥接基团。