4-(2-phenyl-1,3-dioxolan-2-yl)-1-butanol | 17851-47-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 4-(2-phenyl-1,3-dioxolan-2-yl)-1-butanol
• 英文别名: 1,3-Dioxolane-2-butanol, 2-phenyl-；4-(2-phenyl-1,3-dioxolan-2-yl)butan-1-ol
• CAS: 17851-47-7
• 化学式: C₁₃H₁₈O₃
• 分子量: 222.284
• InChiKey: QNEACMJHCDEAGT-UHFFFAOYSA-N

物化性质

• 沸点：
  178-180 °C(Press: 10 Torr)
• 密度：
  1.103±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-(2-phenyl-1,3-dioxolan-2-yl)-1-butanol 在 重铬酸吡啶 作用下， 以 二氯甲烷 为溶剂， 生成 5,5-(ethylenedioxy)-5-phenylpentanal
  参考文献：
  名称：

  The First Tandem [2 + 2] Cycloaddition−Michael Reaction Using Ynolates:  Facile Construction of Substituted Carbocycles

  摘要：

  [GRAPHICS]A tandem [2 + 2] cycloaddition-Michael reaction using ynolate anions followed by decarboxylation produced polysubstituted five-, six-, and seven-membered cycloalkenes.

  DOI：

  10.1021/ol0159928
• 作为产物：
  描述：

  4-苯甲酰基丁酸甲酯 在 lithium aluminium tetrahydride 、 4-甲基苯磺酸吡啶 作用下， 以 乙醚 、 苯 为溶剂， 反应 4.0h， 生成 4-(2-phenyl-1,3-dioxolan-2-yl)-1-butanol
  参考文献：
  名称：

  Hassarajani, S. A.; Dhotare, B.; Chattopadhyay, A., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1998, vol. 37, # 1, p. 80 - 81

  摘要：

  DOI：

文献信息

• Ketones as precursors of active compounds
  申请人：——

  公开号：US20030129212A1

  公开（公告）日：2003-07-10

  A compound of formula 1 wherein Y represents a pyridyl group, or a phenyl group of formula 2 wherein R 3 represents a hydrogen atom, a CF 3 group or an alkoxy group, R 4 represents a hydrogen atom, an alkyl group, or a CF 3 group, R 5 represents a hydrogen atom, an alkyl group, a CF 3 group or an alkoxy group, and R 1 and R 2 are the substituents of a terminal alkene of formula 3 wherein R 1 represents an alkyl or alkylene group, a mono- or poly-cycloalkyl group, or a phenyl group that optionally includes one or several hetero-atoms of oxygen, nitrogen, phosphorous or sulfur; R 2 represents a hydrogen atom, an alkyl or alkylene group, a mono- or poly-cycloalkyl group, or a phenyl group that optionally includes one or several hetero-atoms of oxygen, nitrogen, phosphorous and sulfur. This compound is capable of releasing, upon an exposure to light, an active compound such as a perfume and can be advantageously used in the treatment of any surface in order to perfume it through the controlled release of a perfumed molecule.

  式1的化合物，其中Y代表吡啶基团，或者式2的苯基团，其中R3代表氢原子、CF3基团或烷氧基团，R4代表氢原子、烷基团或CF3基团，R5代表氢原子、烷基团、CF3基团或烷氧基团，R1和R2是式3的末端烯烃的取代基，其中R1代表烷基或烷基烃基、单环或多环脂环基，或者可能包含氧、氮、磷或硫等一种或多种杂原子的苯基团；R2代表氢原子、烷基或烷基烃基、单环或多环脂环基，或者可能包含氧、氮、磷和硫等一种或多种杂原子的苯基团。该化合物能够在光照作用下释放活性化合物，如香水，并可以优势地用于处理任何表面，通过控制释放香水分子来使其带有香气。
• Carbonyl participation in the solvolysis of ketone derivatives. The observation and isolation of intermediates
  作者：Harold R. Ward、P. Dwight Sherman

  DOI：10.1021/ja01016a039

  日期：1968.7
• UTILISATION OF KETONES AS PRECURSORS OF ACTIVE COMPOUNDS
  申请人：FIRMENICH SA

  公开号：EP1294671A2

  公开（公告）日：2003-03-26
• MODIFIED OLIGOESTERS AND MANUFACTURE METHODS OF THE OLIGOESTERS
  申请人：ANHÍDRIDOS Y DERIVADOS DE COLOMBIA S.A. ANDERCOL

  公开号：US20160168315A1

  公开（公告）日：2016-06-16

  The present invention relates to a modified oligoester including an oligoester ( 1 ) that in one of its ends has a group that reacts with alcohols or organic acids forming covalent bonds and in one or more of its other terminations has one or more cyclic acetal groups ( 2 ). In addition, relates to the processes for the production of such modified oligoester, as well as the use of the same in the manufacture of polyester resins, coating compositions, and composite, as well as the process for producing these resins. The scope of the present invention is related to the chemical sector, particularly in what refers to modified oligoesters with cyclic acetal groups.
• US6949680B2
  申请人：——

  公开号：US6949680B2

  公开（公告）日：2005-09-27