2-Oxetanone, 3-(chloromethyl)-3-methyl- | 13390-74-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: 2-Oxetanone, 3-(chloromethyl)-3-methyl-
• 英文别名: 3-(chloromethyl)-3-methyloxetan-2-one
• CAS: 13390-74-4
• 化学式: C₅H₇ClO₂
• 分子量: 134.56
• InChiKey: QQNJXKGKZPZIFW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Impact resistant polymeric compositions
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0211467A2

  公开（公告）日：1987-02-25

  Impact resistant polymeric composition comprising a polyamide or a polyester and a thermally stable modified selectively hydrogenated high 1,2-content block copolymer wherein at least one acid compound is grafted to the block copolymer at a secondary or tertiary carbon position.

  抗冲击聚合物组合物，包括聚酰胺或聚酯和热稳定改性选择性氢化高 1,2 含量嵌段共聚物，其中至少有一种酸化合物在二级或三级碳位置接枝到嵌段共聚物上。
• Synthesis of energetic polyester thermoplastic homopolymers and energetic thermoplastic elastomers formed therefrom
  申请人：Department of National Defence

  公开号：EP1229009A1

  公开（公告）日：2002-08-07

  Polymerization of α-bromomethyl-α-methyl-β-propiolactone (BMMPL) or α-chloromethyl-α-methyl-β-propiolactone (CMMPL) yielded thermoplastic homopolymers that upon azidation led to a novel energetic thermoplastic polyester: poly(α-azidomethyl-α-methyl-β-propiolactone) (PAMMPL). An energetic copolyether-ester thermoplastic elastomer was prepared by using glycidyl azide polymer, a dihydroxyl terminated energetic polymer, as a macroinitiator for the polymerization of BMMPL or CMMPL. The azidation of the resulting copolyether-ester yielded an energetic thermoplastic elastomer that melted at between 80°C and 85°C. Polymerization of α-dibromomethyl-β-propiolactone (DBMPL) resulted in a polymer which upon azidation yielded a new energetic polymer that can be used as a binder or into an energetic thermoplastic elastomer synthesis.

  α-溴甲基-α-甲基-β-丙内酯（BMMPL）或α-氯甲基-α-甲基-β-丙内酯（CMMPL）聚合生成热塑性均聚物，叠氮化后可生成新型高能热塑性聚酯：聚（α-叠氮甲基-α-甲基-β-丙内酯）（PAMMPL）。使用缩水甘油叠氮聚合物（一种二羟基封端的高能聚合物）作为 BMMPL 或 CMMPL 聚合的大引发剂，制备了一种高能共聚醚酯热塑性弹性体。对所得到的共聚醚酯进行叠氮化处理后，可得到一种高能热塑性弹性体，其熔化温度在 80°C 至 85°C 之间。α-dibromomethyl-β-propiolactone (DBMPL) 的聚合产生了一种聚合物，叠氮化后产生了一种新的高能聚合物，可用作粘合剂或合成高能热塑性弹性体。
• SYNTHESIS OF ENERGETIC POLYESTER THERMOPLASTIC HOMOPOLYMERS AND ENERGETIC THERMOPLASTIC ELASTOMERS FORMED THEREFROM
  申请人：——

  公开号：US20020103307A1

  公开（公告）日：2002-08-01

  Polymerization of &agr;-bromomethyl-&agr;-methyl-&bgr;-propiolactone (BMMPL) or &agr;-chloromethyl-&agr;-methyl-&bgr;-propiolactone (CMMPL) yielded thermoplastic homopolymers that upon azidation led to a novel energetic thermoplastic polyester: poly(&agr;-azidomethyl-&agr;-methyl-&bgr;-propiolactone) (PAMMPL). An energetic copolyether-ester thermoplastic elastomer was prepared by using glycidyl azide polymer, a dihydroxyl terminated energetic polymer, as a macroinitiator for the polymerization of BMMPL or CMMPL. The azidation of the resulting copolyether-ester yielded an energetic thermoplastic elastomer that melted at between 80° C. and 85° C. Polymerization of &agr;-dibromomethyl-&bgr;-propiolactone (DBMPL) resulted in a polymer which upon azidation yielded a new energetic polymer that can be used as a binder or into an energetic thermoplastic elastomer synthesis.

  &agr;-溴甲基-&agr;-甲基-&bgr;-丙内酯（BMMPL）或&agr;-氯甲基-&agr;-甲基-&bgr;-丙内酯（CMMPL）聚合生成热塑性均聚物，叠氮化后可生成新型高能热塑性聚酯：聚（&agr;-叠氮甲基-&agr;-甲基-&bgr;-丙内酯）（PAMMPL）。使用缩水甘油叠氮聚合物（一种二羟基封端的高能聚合物）作为 BMMPL 或 CMMPL 聚合的大引发剂，制备了一种高能共聚醚酯热塑性弹性体。叠氮化后的共聚醚酯可生成一种高能热塑性弹性体，其熔融温度在 80°C 至 85°C 之间。
• Thermoplastic moulding composition
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0079632B1

  公开（公告）日：1986-11-26
• Modified block copolymers, impact resistant compositions containing the copolymers and a process for producing the copolymers
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0215501B1

  公开（公告）日：1991-09-25