bicyclo(2.2.2)octa-2,5-diene-7,8-dione | 32273-62-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: bicyclo(2.2.2)octa-2,5-diene-7,8-dione
• 英文别名: Bicyclo<2.2.2>octa-5,7-diene-2,3-dione；Bicyclo<2.2.2>octa-2,5-dien-7,8-dion；Bicyclo<2.2.1>octadien-(2,5)-dion-(7,8)；Bicyclo[2.2.2]octa-5,7-diene-2,3-dione
• CAS: 32273-62-4
• 化学式: C₈H₆O₂
• 分子量: 134.134
• InChiKey: LYRFROXCEOSELJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bicyclo(2.2.2)octa-2,5-diene-7,8-dione 在 sodium hydroxide 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 2.0h， 生成 8-diazobicyclo(2.2.2)octa-2,5-dien-7-one
  参考文献：
  名称：

  1,2,4,6-Cycloheptatetraene: the key intermediate in arylcarbene interconversions and related C7H6 rearrangements

  摘要：

  DOI：

  10.1021/ja00242a034
• 作为产物：
  描述：

  (2S,6R)-2,6-Dichloro-3,5-dioxa-tricyclo[5.2.2.0^2,6]undeca-8,10-dien-4-one 在 水 作用下， 以 1,4-二氧六环 为溶剂， 生成 bicyclo(2.2.2)octa-2,5-diene-7,8-dione
  参考文献：
  名称：

  Scharf,H.-D.; Klar,R., Chemische Berichte, 1972, vol. 105, p. 575 - 587

  摘要：

  DOI：

文献信息

• NOVEL COMPOUND AND METHOD OF PRODUCING ORGANIC SEMICONDUCTOR DEVICE
  申请人：Masumoto Akane

  公开号：US20080171403A1

  公开（公告）日：2008-07-17

  A method of producing an organic semiconductor device is provided in which a layer composed of an organic semiconductor having excellent crystallinity and orientation in a low-temperature region can be formed, and the device can be produced in the air. The method includes forming a layer composed of an organic semiconductor precursor on a base body and irradiating the organic semiconductor precursor with light, wherein the organic semiconductor precursor is a porphyrin compound or an azaporphyrin compound having in its molecule at least one of the structure represented by the following general formula (1) or (2):

  提供一种生产有机半导体器件的方法，其中可以在低温区域形成具有优异结晶性和取向性的有机半导体层，并且可以在空气中生产该器件。该方法包括在基体上形成由有机半导体前体组成的层，并用光辐照有机半导体前体，其中有机半导体前体是具有下述一般式（1）或（2）所代表的结构之一的卟啉化合物或氮杂卟啉化合物：
• NOVEL ADDUCT COMPOUND, SOLUTION FOR FORMATION OF ORGANIC SEMICONDUCTOR FILM, METHOD FOR PRODUCING SAID SEMICONDUCTOR FILM AND METHOD FOR SYNTHESIZING SAID ADDUCT COMPOUND
  申请人：Teijin Limited

  公开号：EP2471796B1

  公开（公告）日：2019-10-30
• Maier, Guenther; Reisenauer, Hans Peter; Roether, Bernd, Liebigs Annalen, 1996, # 3, p. 303 - 306
  作者：Maier, Guenther、Reisenauer, Hans Peter、Roether, Bernd、Eckwert, Juergen

  DOI：——

  日期：——
• NOVEL ADDUCT COMPOUND, METHODS FOR PURIFICATION AND PREPARATION OF FUSED POLYCYCLIC AROMATIC COMPOUND, SOLUTION FOR FORMATION OF ORGANIC SEMICONDUCTOR FILM, AND NOVEL ALPHA-DIKETONE COMPOUND
  申请人：Ikeda Yoshinori

  公开号：US20120211731A1

  公开（公告）日：2012-08-23

  Provided are a novel adduct compound and a novel α-diketone compound, from which organic semiconductor layers consisting of a fused polycyclic aromatic compound can be formed by a solution method, said solution method being generally easier than a deposition method. Also provided are a method for the purification of the adduct compound, and a solution for the formation of organic semiconductor film, which contains the adduct compound. The adduct compound has a structure wherein a compound having a double bond is added in an eliminable state to a fused polycyclic aromatic compound of general formula (I): Ar 1 Ar 2 Ar 3 (I), while the α-diketone compound has a structure wherein a compound having a double bond is added in an eliminable state to a fused polycyclic aromatic compound. The fused polycyclic aromatic compound is dinaphthothienothiophene or the like, while the compound having a double bond is hexachlorocyclopentadiene or the like. In general formula (I), Ar 1 , Ar 2 and Ar 3 are each as defined in the description.
• US7928221B2
  申请人：——

  公开号：US7928221B2

  公开（公告）日：2011-04-19