2-<4-Formyl-penten-(3)-yl>-2-methyl-1,3-dioxolan | 21403-85-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-<4-Formyl-penten-(3)-yl>-2-methyl-1,3-dioxolan
• 英文别名: 2-methyl-5-(2-methyl-[1,3]dioxolan-2-yl)-pent-2-enal；2-Methyl-5-(2-methyl-1,3-dioxolan-2-yl)pent-2-enal；2-methyl-5-(2-methyl-1,3-dioxolan-2-yl)pent-2-enal
• CAS: 21403-85-0
• 化学式: C₁₀H₁₆O₃
• 分子量: 184.235
• InChiKey: HLNSCECLAIWTQU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-<4-Formyl-penten-(3)-yl>-2-methyl-1,3-dioxolan 在 三乙酰氧基硼氢化钠 作用下， 以 苯 为溶剂， 反应 3.0h， 以89.6%的产率得到2-methyl-5-(2-methyl-[1,3]dioxolan-2-yl)-pent-2-en-1-ol
  参考文献：
  名称：

  Exclusive 1,2-Reduction of Functionalised Conjugated Aldehydes with Sodium Triacetoxyborohydride

  摘要：

  Functionalised alpha,beta-unsaturated aldehydes were exclusively reduced to allylic alcohols with sodium-triacetoxyborohydride. Neither saturated alcohol nor saturated aldehydes are obtained. Conjugated ketones are not reduced.

  DOI：

  10.1080/00397910008087180

文献信息

• Exclusive 1,2-Reduction of Functionalised Conjugated Aldehydes with Sodium Triacetoxyborohydride
  作者：Jasvinder Singh、Munisha Sharma、Irvinder Kaur、Goverdhan L. Kad

  DOI：10.1080/00397910008087180

  日期：2000.4

  Functionalised alpha,beta-unsaturated aldehydes were exclusively reduced to allylic alcohols with sodium-triacetoxyborohydride. Neither saturated alcohol nor saturated aldehydes are obtained. Conjugated ketones are not reduced.