6,6-Bis-methoxymethyl-2,4-dimethyl-deca-2,3-dien-8-yne | 681272-68-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 6,6-Bis-methoxymethyl-2,4-dimethyl-deca-2,3-dien-8-yne
• 英文别名: 6,6-Bis(methoxymethyl)-2,4-dimethyldeca-2,3-dien-8-yne
• CAS: 681272-68-4
• 化学式: C₁₆H₂₆O₂
• 分子量: 250.381
• InChiKey: NNGSEMIPLXDOLE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  18
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  6,6-Bis-methoxymethyl-2,4-dimethyl-deca-2,3-dien-8-yne 在 platinum(II) chloride 作用下， 以 甲苯 为溶剂， 以84%的产率得到2-Isopropyl-5,5-bis-methoxymethyl-1-methyl-3-vinylidene-cyclohexene
  参考文献：
  名称：

  PtCl₂-Catalyzed Cycloisomerizations of Allenynes

  摘要：

  The PtCl2-catalyzed cycloisomerization of allenyne systems has been examined. This process is a highly versatile tool for obtaining products that cannot be attainable with other metals. Simple adjustment of the allene or alkyne substitution can direct the reactivity in a selective manner and give birth to important carbocyclic frameworks (hydrindenes, cyclic vinylallenes, and trienes).

  DOI：

  10.1021/ja031892g

文献信息

• PtCl₂-Catalyzed Cycloisomerizations of Allenynes
  作者：Nicolas Cadran、Kevin Cariou、Gwénaëlle Hervé、Corinne Aubert、Louis Fensterbank、Max Malacria、José Marco-Contelles

  DOI：10.1021/ja031892g

  日期：2004.3.1

  The PtCl2-catalyzed cycloisomerization of allenyne systems has been examined. This process is a highly versatile tool for obtaining products that cannot be attainable with other metals. Simple adjustment of the allene or alkyne substitution can direct the reactivity in a selective manner and give birth to important carbocyclic frameworks (hydrindenes, cyclic vinylallenes, and trienes).