8,8-Dimethyl-bicyclo[3.2.1]octan-3-one | 103274-02-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 8,8-Dimethyl-bicyclo[3.2.1]octan-3-one
• 英文别名: 8,8-Dimethylbicyclo[3.2.1]octan-3-one；8,8-dimethylbicyclo[3.2.1]octan-3-one
• CAS: 103274-02-8
• 化学式: C₁₀H₁₆O
• 分子量: 152.236
• InChiKey: CHFWTDDNWJXEQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N-[(8,8-dimethyl-3-bicyclo[3.2.1]octanylidene)amino]-4-methylbenzenesulfonamide 在 Cr-MCM-41 zeolite on silica gel 作用下， 反应 0.17h， 以72%的产率得到8,8-Dimethyl-bicyclo[3.2.1]octan-3-one
  参考文献：
  名称：

  A FACILE METHOD FOR THE CONVERSION OF OXIMES AND TOSYLHYDRAZONES TO CARBONYL COMPOUNDS WITH CR-MCM-41 ZEOLITE UNDER MICROWAVE IRRADIATION*

  摘要：

  Cr-MCM-41 zeolite supported on silica gel can be used as an effective and mild oxidizing agent for the direct conversion of oximes and tosylhydrazones to carbonyl compounds under microwave irradiation in good yield. The procedure is applicable to the variety of oximes and tosylhydrazones and the zeolite can be recycled.

  DOI：

  10.1081/scc-120005429

文献信息

• A FACILE METHOD FOR THE CONVERSION OF OXIMES AND TOSYLHYDRAZONES TO CARBONYL COMPOUNDS WITH CR-MCM-41 ZEOLITE UNDER MICROWAVE IRRADIATION*
  作者：Lingaiah Nagarapu、Narender Ravirala、Dattatray Akkewar

  DOI：10.1081/scc-120005429

  日期：2002.1.1

  Cr-MCM-41 zeolite supported on silica gel can be used as an effective and mild oxidizing agent for the direct conversion of oximes and tosylhydrazones to carbonyl compounds under microwave irradiation in good yield. The procedure is applicable to the variety of oximes and tosylhydrazones and the zeolite can be recycled.